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Dibenzyl sulphide

Dibenzyl sulphide Suppliers list
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CAS:538-74-9
Purity:98%(Min,HPLC) Package:100g;1kg;5kg,10kg,25kg,50kg
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CAS:538-74-9
Purity:99% Package:5KG;1KG Remarks:C14H14S
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Products Intro: Product Name:Dibenzyl sulphide
CAS:538-74-9
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Dibenzyl sulphide Basic information
Product Name:Dibenzyl sulphide
Synonyms:BENZYLSULFID;BENZYL SULFIDE;DIBENZYL SULFIDE;DIBENZYL SULPHIDE;Benzene, 1,1'-[thiobis(methylene)]bis-;Benzyl sulfide, 98% 100GR;Dibenzyl sulfid;BENZYLSULPHIDE
CAS:538-74-9
MF:C14H14S
MW:214.33
EINECS:208-703-6
Product Categories:sulfide Flavor
Mol File:538-74-9.mol
Dibenzyl sulphide Structure
Dibenzyl sulphide Chemical Properties
Melting point 44-47 °C (lit.)
Boiling point 131 °C / 2mmHg
density 1.0880
refractive index 1.6170 (estimate)
Fp >110°C
storage temp. 0-10°C
form Crystals
color White
Water Solubility <0.1 g/100 mL at 21 ºC
Merck 14,1145
BRN 1911157
Stability:Stable. Combustible. Incompatible with strong oxidizing agents.
LogP3.169 (est)
CAS DataBase Reference538-74-9(CAS DataBase Reference)
NIST Chemistry ReferenceBenzene, 1,1'-[thiobis(methylene)]bis-(538-74-9)
EPA Substance Registry SystemDibenzyl sulfide (538-74-9)
Safety Information
Safety Statements 22-24/25
RIDADR UN 3335
WGK Germany 2
RTECS DC0512500
13
TSCA Yes
HS Code 29309090
Hazardous Substances Data538-74-9(Hazardous Substances Data)
ToxicityLD50 orl-rat: >2 g/kg ATDAEI 15(Suppl 1),S89,1996
MSDS Information
ProviderLanguage
Benzyl sulfide English
SigmaAldrich English
ACROS English
ALFA English
Dibenzyl sulphide Usage And Synthesis
Chemical Propertiesbeige crystals or powder with an unpleasant smell
UsesOrganic synthesis.
Synthesis Reference(s)Canadian Journal of Chemistry, 53, p. 1480, 1975 DOI: 10.1139/v75-205
Tetrahedron Letters, 27, p. 1073, 1986 DOI: 10.1016/S0040-4039(86)80051-X
General DescriptionColorless plates or pale beige crystalline solid with a crippling stench .
Air & Water ReactionsInsoluble in water.
Reactivity ProfileOrganosulfides, such as Dibenzyl sulphide, are incompatible with acids, diazo and azo compounds, halocarbons, isocyanates, aldehydes, alkali metals, nitrides, hydrides, and other strong reducing agents. Reactions with these materials generate heat and in many cases hydrogen gas. Many of these compounds may liberate hydrogen sulfide upon decomposition or reaction with an acid.
Fire HazardDibenzyl sulphide is combustible.
Safety ProfileModerately toxic by ingestion.When heated to decomposition it emits toxic vapors ofSOx.
Purification MethodsCrystallise the sulfide from EtOH/water (10:1), or repeatedly from Et2O. It has also been purified by chromatography on Al2O3 (pentane as eluent), then recrystallised from EtOH [Kice & Bowers J Am Chem Soc 84 2390 1962]. Dry it in a vacuum at 30o over P2O5, fused under nitrogen and re-dried. [Beilstein 6 IV 2649.]
Dibenzyl sulphide Preparation Products And Raw materials
Preparation ProductsDIBENZYL SULFOXIDE
Tag:Dibenzyl sulphide(538-74-9) Related Product Information
Borane-methyl sulfide complex Benzyl alcohol Benzyl chloromethyl ether Hydrogen Sulfide Sodium sulfide Diphenyl sulfide CARBONYL SULFIDE POLY(1,4-PHENYLENE SULFIDE) Dimethyl sulfide Benzyl BIS(3,5-DI-T-BUTYL-4-HYDROXYBENZYL) SULFIDE N,N-Dibenzylhydroxylamine 2,11-DITHIA[3.3]PARACYCLOPHANE 4,6-DIPHENYLTHIENO[3,4-D]-1,3-DIOXOL-2-ONE 5,5-DIOXIDE 2,5-DIPHENYL-4-HYDROXY-3-OXO-2,3-DIHYDROTHIOPHENE 1,1-DIOXIDE DIBENZYL SULFONE 1,3-DIPHENYLBENZO[C]THIOPHENE SODIUM SULPHIDE