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| | 2-(Dicyclohexylphosphino)biphenyl Basic information | | Reaction |
| | 2-(Dicyclohexylphosphino)biphenyl Chemical Properties |
| Melting point | 102-106 °C(lit.) | | Boiling point | 499.5±24.0 °C(Predicted) | | storage temp. | under inert gas (nitrogen or Argon) at 2-8°C | | solubility | soluble in Toluene | | form | crystal | | color | white | | Sensitive | Air Sensitive | | BRN | 8440533 | | CAS DataBase Reference | 247940-06-3(CAS DataBase Reference) |
| | 2-(Dicyclohexylphosphino)biphenyl Usage And Synthesis |
| Reaction |
- Ligand used in the palladium-catalyzed synthesis of aromatic amines from aryl chlorides, bromides and triflates.
- Ligand employed in Suzuki coupling reactions involving aryl chlorides, bromides and triflates.
- Useful ligand for the Pd-catalyzed oxidation of alcohols in the presence of chlorobenzenes.
- Useful ligand for the Pd-catalyzed amination with ammonia equivalents.
- Ligand for the gold(I)-catalyzed intramolecular [4+2] cycloadditions involving 1,3-enynes and arylalkynes with alkenes.
- Ligand used in the palladium-catalyzed borylation of aryl bromdies.
- Ligand used in the palladium-catalyzed siliylation of aryl chlorides.
| | Chemical Properties | white to light yellow crystal powde | | Uses | suzuki reaction | | Uses | Ligand employed in an extremely general method for the Pd-catalyzed synthesis of aromaticamines using aryl chlorides, bromides and triflates. | | Uses | 2-(Dicyclohexylphosphino)biphenyl is used as a catalyst for Suzuki coupling reactions. | | General Description | CyJohnPhos [(2-Biphenyl)dicyclohexylphosphine] is an air-stable, bulky and electron-rich monodentate biarylphosphine ligand developed by the Buchwald group to enhance the reactivity of palladium catalysis during cross-coupling reactions. |
| | 2-(Dicyclohexylphosphino)biphenyl Preparation Products And Raw materials |
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