(R)-(-)-1-[(R)-2-(2'-Diphenylphosphinophenyl)ferrocenyl]ethyldicyclohexylphosphine

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CAS:565184-29-4
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CAS:565184-29-4
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CAS:565184-29-4
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(R)-(-)-1-[(R)-2-(2'-Diphenylphosphinophenyl)ferrocenyl]ethyldicyclohexylphosphine Basic information
Product Name:(R)-(-)-1-[(R)-2-(2'-Diphenylphosphinophenyl)ferrocenyl]ethyldicyclohexylphosphine
Synonyms:(1S)-1-[(1R)-1-(Dicyclohexylphosphino)ethyl]-2-[2-(diphenylphosphino)phenyl]ferrocene;(R)-1-[(R)-1- (Dicyclohexylphosphino)ethyl]- 2-[2- (diphenylphosphino)phenyl]ferro cene;(R)-(-)-1-[(R)-2-(2'-Diphenylphosphinophenyl)ferrocenyl]ethyldicyclohexylphosphine, Walphos SL-W003-1;Ferrocene,1-[(1R)-1-(dicyclohexylphosphino)ethyl]-2-[2-(diphenylphosphino)phenyl]-, (1S)-;(R)-(-)-1-[(R)-2-(2'-Diphenylphosphinophenyl)ferrocenyl]ethyldicyclohexylphosphine;(R)-(-)-1-[(R)-2-(2''-Diphenylphosphinophenyl)ferrocenyl]ethyldicyclohexylphosphine
CAS:565184-29-4
MF:C42H48FeP210*
MW:670.623042
EINECS:
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Mol File:565184-29-4.mol
(R)-(-)-1-[(R)-2-(2'-Diphenylphosphinophenyl)ferrocenyl]ethyldicyclohexylphosphine Structure
(R)-(-)-1-[(R)-2-(2'-Diphenylphosphinophenyl)ferrocenyl]ethyldicyclohexylphosphine Chemical Properties
Melting point 87-96 °C
alpha -8° ±2° (c 0.5, CHCl3)
form Powder
color orange
Safety Information
MSDS Information
(R)-(-)-1-[(R)-2-(2'-Diphenylphosphinophenyl)ferrocenyl]ethyldicyclohexylphosphine Usage And Synthesis
Uses(1S)-1-[(1R)-1-(Dicyclohexylphosphino)ethyl]-2-[2-(diphenylphosphino)phenyl]ferrocene is used in preparation of chiral Piperidines via asymmetric Hydrogenation of Dehydropiperidines using metal chiral Phosphine catalyst complexes.
Reactions1. Enantioselective synthesis of chiral fluoropiperidine via asymmetric hydrogenation of a vinyl fluoride.
2. Palladium/ClickFerrophos – Catalyzed asymmetric domino allylstannylation-Heck reaction of o-formylaryl triflate.
3. Catalytic asymmetric alkylation of acylsilanes.
Reactions of 565184-29-4
(R)-(-)-1-[(R)-2-(2'-Diphenylphosphinophenyl)ferrocenyl]ethyldicyclohexylphosphine Preparation Products And Raw materials
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