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| | Dimethyl sulfoxide-d6 Basic information |
| Product Name: | Dimethyl sulfoxide-d6 | | Synonyms: | Methyl sulfoxide-d6, with 1% TMS, in 0.75 ml ampoules, 99.9 atom% D, for NMR;Methyl sulfoxide-d6, packaged in 0.75 ml ampoules, 100.0 atom % D, for NMR;Methyl sulfoxide-d6, packaged in 0.50 ml ampoules, 100.0 atom % D, for NMR;DeuterodiMethyl sulfoxide-d6;DiMethylsulfoxide deuterated;Dimethylsulphoxide-D6 >99.8 Atom % D 0.03% TMS;Dimethyl sulfoxide-d6, deuteration degree min. 99,5%, NMR spectroscopy grade, Spectrosol;Dimethyl sulfoxide-d6, deuteration degree min. 99,8%, NMR spectroscopy grade, Spectrosol | | CAS: | 2206-27-1 | | MF: | C2D6OS | | MW: | 84.17 | | EINECS: | 218-617-0 | | Product Categories: | Analytical Chemistry;Deuterated Compounds for NMR;NMR Spectrometry;Dimethyl sulfoxide-d6;Aldrich High Purity NMR Solvents for Routine NMR;High Throughput NMR;Labware;NMR;NMR Solvents;NMR Solvents and Reagents;Routine NMR;Solvent by Application;Solvents;Solvents for High Throughput NMR;Spectroscopy Solvents (IR;Stable Isotopes;Tubes and Accessories;UV/Vis);Alphabetical Listings;D;Aldrich 100% NMR Solvents for High Resolution;Dimethyl Sulfoxide (DMSO);High Resolution NMR;Solvent by Type;250g RMB 2600 | | Mol File: | 2206-27-1.mol |  |
| | Dimethyl sulfoxide-d6 Chemical Properties |
| Melting point | 20.2 °C | | Boiling point | 55 °C5 mm Hg(lit.) | | density | 1.190 g/mL at 25 °C(lit.) | | vapor pressure | 0.42 mm Hg ( 20 °C) | | refractive index | n20/D 1.476(lit.) | | Fp | 185 °F | | storage temp. | no restrictions. | | solubility | Minimum isotopic purity 99.96% | | form | Liquid | | color | Colorless | | Specific Gravity | 1.190 | | explosive limit | 1.8-63%(V) | | Water Solubility | Miscible with water and with almost all organic solvents such as alcohols, esters, ketones, chlorinated solvents and aromatic hydrocarbons. | | Sensitive | Hygroscopic | | BRN | 1237248 | | Stability: | Stable. Combustible. Moisture sensitive. Incompatible with acid chlorides, strong acids, phosphorus halides, strong oxidizing agents, strong reducing agents. Reacts violently with a wide range of materials - consult a full MSDS sheet before starting use. | | LogP | -0.69 at 20℃ and pH7 | | CAS DataBase Reference | 2206-27-1(CAS DataBase Reference) |
| Hazard Codes | Xi | | Risk Statements | 36/37/38 | | Safety Statements | 26-36-23 | | RIDADR | NA 1993 / PGIII | | WGK Germany | 3 | | RTECS | PV6210000 | | Autoignition Temperature | 573 °F | | HS Code | 2845 90 10 | | Toxicity | LD50 orally in Rabbit: 14500 mg/kg LD50 dermal Rat 40000 mg/kg |
| | Dimethyl sulfoxide-d6 Usage And Synthesis |
| Chemical Properties | Dimethyl sulfoxide-d6 is a sulfur-containing compound with the molecular formula (CD3)2SO. It is a colorless, odorless, transparent liquid at room temperature, with a freezing point of 18.45°C and a boiling point of 189°C. It has a slightly bitter taste and is highly soluble in water, alcohol, ether, and ester, exhibiting strong hygroscopic properties. DMSO remains stable below 140°C but decomposes into trace amounts of aldehydes, sulfides, and mercaptans when heated for extended periods at its boiling point. Decomposition accelerates under acidic conditions but can be inhibited in alkaline environments. Therefore, DMSO refining is typically performed via vacuum distillation, with the pH maintained around 8, or by adding sodium oxalate as a stabilizer. | | Uses | DMSO-d6 is a solvent of choice in NMR spectroscopy, owing to its unique characteristics of dissolving both nonpolar and polar compounds, miscibility with almost all organic solvents and permitting high temperature dynamic NMR studies. | | Uses | Dimethyl sulfoxide-d6 may be used as an NMR solvent for 1H and 13C NMR experiments. | | Uses | (Dimethyl Sulfoxide-d6) DMSO is a very common aprotic solvent that is used in a variety of organic chemical reactions and spectroscopic analyses. | | Definition | ChEBI: Dimethyl sulfoxide-d6 is a deuterated compound, a sulfoxide and a volatile organic compound. | | General Description | Dimethyl sulfoxide-d6 (DMSO-d6) is a deuterated solvent. It is 100% isotopically enriched NMR (Nuclear Magnetic Resonance) solvent. It is widely employed in high resolution NMR studies due to its high chemical and isotopic purity. On photoirradiation in the range of 193 and 222nm, it undergoes decomposition to afford CD3 radicals. Quantum yields of CD3 have been evaluated by infrared diode laser absorption spectroscopy. 100% DMSO-d6 has been used as solvent in the long-range COSY (Correlation Spectroscopy) experiment. |
| | Dimethyl sulfoxide-d6 Preparation Products And Raw materials |
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