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Bis(triphenylphosphine)nickel(II)chloride

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Products Intro: Product Name:Bis(triphenylphosphine)nickel(II)chloride
CAS:14264-16-5
Purity:99% Package:1KG;10.00;USD
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Products Intro: Product Name:Bis(triphenylphosphine)nickel(II)chloride
CAS:14264-16-5
Purity:99% Package:25KG
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Products Intro: Product Name:Bis(triphenylphosphine)nickel(II)chloride
CAS:14264-16-5
Purity:98%(Min,HPLC) Package:100g;1kg;5kg,10kg,25kg,50kg
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Products Intro: Product Name:Bis(triphenylphosphine)nickel(II)chloride
CAS:14264-16-5
Purity:0.99 Package:100g ;1KG ;5KG Remarks:Catalysts
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Products Intro: Product Name:Bis(triphenylphosphine)nickel(II)chloride
CAS:14264-16-5
Purity:99% Package:25KG;5KG;1KG

Bis(triphenylphosphine)nickel(II)chloride manufacturers
Bis(triphenylphosphine)nickel(II)chloride Basic information
Reaction
Product Name:Bis(triphenylphosphine)nickel(II)chloride
Synonyms:Dichlorobis(triphenyIphosphine)-nickel;tributyl-phosphin compd. with nickelchloride;Nickel(II) chloride bis(triphenylphosphine);Dichlorobis(triphenylphosphine)nickel(II), Nickel(II)bis(triphenylphosphine) dichloride;Phosphine, tributyl-, compound with nickel chloride (2:1);Dichlorobis(triphenylphosphine)nickel(Ⅱ);Dichlorobis(triphenylphosphine)nickel(II), 98+%;Dichlorobis(triphehylphosphine)nickel(II) ,98%
CAS:14264-16-5
MF:C36H30Cl2NiP2
MW:654.17
EINECS:238-154-8
Product Categories:Metal Compounds;Catalysts for Organic Synthesis;Classes of Metal Compounds;Homogeneous Catalysts;Metal Complexes;Ni (Nickel) Compounds;Synthetic Organic Chemistry;Transition Metal Compounds;metal-phosphine complexes;Aromatics;Phosphorylating and Phosphitylating Agents;Pyridines;Ni
Mol File:14264-16-5.mol
Bis(triphenylphosphine)nickel(II)chloride Structure
Bis(triphenylphosphine)nickel(II)chloride Chemical Properties
Melting point 250 °C (dec.)(lit.)
storage temp. Inert atmosphere,Room Temperature
solubility DMSO (Slightly), Methanol (Slightly)
form Crystals or Powder
color Dark green to dark gray
Water Solubility insoluble
Sensitive Hygroscopic
Exposure limitsNIOSH: IDLH 10 mg/m3; TWA 0.015 mg/m3
CAS DataBase Reference14264-16-5(CAS DataBase Reference)
NIST Chemistry Referencedichlorobis(triphenylphosphine)nickel(14264-16-5)
EPA Substance Registry SystemNickel, dichlorobis(triphenylphosphine)- (14264-16-5)
Safety Information
Hazard Codes T
Risk Statements 45-43-52/53-34-20/21/22
Safety Statements 53-36/37-45-60-36/37/39-26
RIDADR 3260
WGK Germany 3
RTECS QR6170000
F 21
TSCA Yes
HazardClass 6.1(b)
PackingGroup III
HS Code 29310095
MSDS Information
ProviderLanguage
Dichlorobis(triphenylphosphine)nickel(II) English
SigmaAldrich English
ACROS English
ALFA English
Bis(triphenylphosphine)nickel(II)chloride Usage And Synthesis
Reaction
  1. Catalyst for hydrosilylation of styrene with diphenysilane
  2. Catalyst for carboxylation of various aryl chlorides and other derivatives
  3. Catalyst for C–P cross-coupling reactions of diphenylphosphine oxide with aryl chloride
  4. Catalyst for N?Heterocyclic carbene-assisted cross-coupling reactions of diarylborinic acids with aryl chlorides,tosylates, and sulfamates.
  5. Catalyst for Negishi biaryl ketone synthesis by cross-coupling of amides with aryl zinc halides via carbon-nitrogen bond cleavage.
Reactions of 14264-16-5
Chemical Propertiesdark green to dark grey crystals or powder
UsesDichlorobis(triphenylphosphine)nickel(II) is used as a catalyst for cross-coupling of Grignard reagents, hydrosilylations, hydrogenation and polymerization.
Usessuzuki reaction
UsesCoordination compund.
reaction suitabilitycore: nickel
reagent type: catalyst
Purification MethodsWash it with glacial AcOH and dry it in a vacuum over H2SO4 and KOH until AcOH is removed. [Venanzi J Chem Soc 719 1958, Kocienski et al. J Org Chem 54 1215 1989, Beilstein 16 IV 953.]
Bis(triphenylphosphine)nickel(II)chloride Preparation Products And Raw materials
Raw materialsEthanol-->Dichloromethane-->Triphenylphosphine-->Nickel(II) chloride hexahydrate
Preparation Products6,6'-Dimethyl-2,2'-dipyridyl-->3-PHENYLPIPERIDINE
Tag:Bis(triphenylphosphine)nickel(II)chloride(14264-16-5) Related Product Information
Potassium chloride Ammonium chloride Calcium chloride Triphenylphosphine Bis(triphenylphosphine)palladium(II) chloride Choline chloride Polyvinyl chloride Nickel oxide Tris(triphenylphosphine)rhodiu Nickel chloride Sodium chloride Thionyl chloride (OXYDI-2,1-PHENYLENE)BIS(DIPHENYLPHOSPHINE) BIS(TRIPHENYLPHOSPHINE)DICARBONYLNICKEL Bis-(triphenylphosphino)-cuprous borohydride BIS(TRIPHENYLPHOSPHINE)COBALT (II) CHLORIDE Nickel(II) chloride hexahydrate Bis(tricyclohexylphosphine)nickel(II) chloride, 99%
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