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| | Bis(triphenylphosphine)nickel(II)chloride Basic information | | Reaction |
| | Bis(triphenylphosphine)nickel(II)chloride Chemical Properties |
| | Bis(triphenylphosphine)nickel(II)chloride Usage And Synthesis |
| Reaction |
- Catalyst for hydrosilylation of styrene with diphenysilane
- Catalyst for carboxylation of various aryl chlorides and other derivatives
- Catalyst for C–P cross-coupling reactions of diphenylphosphine oxide with aryl chloride
- Catalyst for N?Heterocyclic carbene-assisted cross-coupling reactions of diarylborinic acids with aryl chlorides,tosylates, and sulfamates.
- Catalyst for Negishi biaryl ketone synthesis by cross-coupling of amides with aryl zinc halides via carbon-nitrogen bond cleavage.
| | Chemical Properties | dark green to dark grey crystals or powder | | Uses | Coordination compund. | | Uses | Dichlorobis(triphenylphosphine)nickel(II) is used as a catalyst for cross-coupling of Grignard reagents, hydrosilylations, hydrogenation and polymerization. | | Uses | suzuki reaction | | Purification Methods | Wash it with glacial AcOH and dry it in a vacuum over H2SO4 and KOH until AcOH is removed. [Venanzi J Chem Soc 719 1958, Kocienski et al. J Org Chem 54 1215 1989, Beilstein 16 IV 953.] |
| | Bis(triphenylphosphine)nickel(II)chloride Preparation Products And Raw materials |
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