ChemicalBook > Product Catalog >Chemical Reagents >Organic reagents >Silane >Triethylsilane

Triethylsilane

Triethylsilane Suppliers list
Company Name: Capot Chemical Co.,Ltd.
Tel: +86 (0)571-855 867 18
Email: sales@capotchem.com
Products Intro: Product Name:Triethylsilane
CAS:617-86-7
Purity:98%(Min,GC) Package:100g;1kg;5kg,10kg,25kg,50kg
Company Name: Henan DaKen Chemical CO.,LTD.
Tel: +86-371-55531817
Email: info@dakenchem.com
Products Intro: Product Name:TRIETHYLSILANE
CAS:617-86-7
Purity:99.00% Package:100g,500g,1KG,10KG,100KG Remarks:Low M.W.Organic Silanes Professor
Company Name: Henan Tianfu Chemical Co.,Ltd.
Tel: 0371-55170693
Email: info@tianfuchem.com
Products Intro: Product Name:TRIETHYLSILANE
CAS:617-86-7
Purity:99% Package:500G;1KG;5KG;25KG
Company Name: Mainchem Co., Ltd.
Tel: +86-0592-6210733
Email: sales@mainchem.com
Products Intro: Product Name:Triethylsilane
CAS:617-86-7
Company Name: Zjartschem
Tel: +86-571-8723 8903 jocelynpan@zjarts.com
Email: jocelynpan@zjarts.com
Products Intro: Product Name:Triethylsilane
CAS:617-86-7
Purity:98% Package:500g;1kg;5kg;10kg;100kg;1000kg... Remarks:Brand:Zjartschem | Cat.No.:ZCF06141

Lastest Price from Triethylsilane manufacturers

  • Triethylsilane
  • US $1.00 / KG
  • 2018-08-13
  • CAS:617-86-7
  • Min. Order: 1G
  • Purity: 99%
  • Supply Ability: 100kg
Triethylsilane Basic information
Referrence Referrence
Product Name:Triethylsilane
Synonyms:Triethylsilyl;Triethylsilane,99%;Silane, triethyl-;Triethylsilane, 98.5+%;Triethylsilicon;Triethylsilane,Triethylsilyl hydride;Triethylsilane ,97%;Triethylsilane, 99% 100GR
CAS:617-86-7
MF:C6H16Si
MW:116.28
EINECS:210-535-3
Product Categories:Other Reagents;Reduction;Si (Classes of Silicon Compounds);Si-H Compounds;Silicon Compounds (for Synthesis);Synthetic Organic Chemistry;Alkyl Silanes;Hydrogensilanes Hydrogensiloxanes;Reducing Agents;Chemistry;Silanes;Synthetic Reagents;organosilicon compound;Organics
Mol File:617-86-7.mol
Triethylsilane Structure
Triethylsilane Chemical Properties
Melting point -157°C
Boiling point 107-108 °C(lit.)
density 0.728 g/mL at 25 °C(lit.)
refractive index n20/D 1.412(lit.)
Fp 25 °F
storage temp. 2-8°C
form liquid
color colorless
Water Solubility Miscible with water.
Sensitive Moisture Sensitive
BRN 1098278
Stability:Stable, but moisture sensitive. Highly flammable. Generates highly flammable gas (hydrogen) in contact with water, acids and bases.
CAS DataBase Reference617-86-7(CAS DataBase Reference)
NIST Chemistry ReferenceSilane, triethyl-(617-86-7)
EPA Substance Registry SystemSilane, triethyl-(617-86-7)
Safety Information
Hazard Codes F,Xi
Risk Statements 11-36/37/38-52/53
Safety Statements 9-16-29-33-37/39-26-61
RIDADR UN 1993 3/PG 2
WGK Germany 1
10-21
TSCA Yes
HazardClass 3
PackingGroup II
HS Code 29310095
MSDS Information
ProviderLanguage
Triethylsilane English
SigmaAldrich English
ACROS English
ALFA English
Triethylsilane Usage And Synthesis
ReferrenceTriethylsilane is a useful versatile reductant since it has a active hydride. It can be used for mediated the palladium-catalyzed dehalogenation reaction of alkyl or aryl halides, the reduction of primary, secondary, and tertiary chlorides, bromides, and iodides catalyzed by iridium, as well as efficient reduction of multiple bonds, azides, imines, and nitro groups, as well as benzyl group and allyl group deprotection. It is also specifically for the hydrosilation of olefins to give alkyl silanes. It is also the catalyst for synthesis of a spiro-oxindole blocker of Nav1.7 for the treatment of pain, redox initiated cationic polymerization and Beckmann rearrangement of cyclododecanone oxime as well as regioselective reductive coupling of enones and allenes.
Referrence
  1. R. Boukherroub,†,‡, C. Chatgilialoglu,,§ and, and G. Manuel†. "PdCl2-Catalyzed Reduction of Organic Halides by Triethylsilane." Organometallics 15.5(1996):1508-1510.
  2. Jian Yang and, and M. Brookhart. "Iridium-Catalyzed Reduction of Alkyl Halides by Triethylsilane." Journal of the American Chemical Society 129.42(2007):12656-7.
  3. And, Pijus K. Mandal, and J. S. Mcmurray. "Pd−C-Induced Catalytic Transfer Hydrogenation with Triethylsilane." Journal of Organic Chemistry 72.17(2007):6599-6601.
  4. Chen, Bang Chi, et al. "Novel triethylsilane mediated reductive N -alkylation of amines: improved synthesis of 1-(4-imidazolyl)methyl-4-sulfonylbenzodiazepines, new farnesyltransferase inhibitors." Tetrahedron Letters 42.7(2001):1245-1246.
Chemical PropertiesClear liquid
UsesTriethylsilane is a trialkylsilicon hydride used in the synthesis of alkylsilanes via hydrosilation of olefins. Triethylsilane is also used as an effective reducing agent.
Purification MethodsReflux triethylsilane over molecular sieves, then distil it. It is passed through neutral alumina before use [Randolph & Wrighton J Am Chem Soc 108 3366 1986]. [Beilstein 4 IV 3895.]
Triethylsilane Preparation Products And Raw materials
Preparation Products4-BENZYLPIPERIDINE-->6,7-DIMETHOXY-3-METHYL-1,2,3,4-TETRAHYDROISOQUINOLINE HYDROCHLORIDE
Tag:Triethylsilane(617-86-7) Related Product Information
tert-Butyldimethylsilyl chloride tert-Butylchlorodiphenylsilane TRIISOBUTYLCHLOROSILANE Chlorotriethylsilane Triethylsilyl trifluoromethanesulfonate Tributylchlorosilane CHLOROTRIBENZYLSILANE TRIBENZYLSILANE TRIETHYLBROMOSILANE Triethylsilane Chlorotrimethylsilane Iodotrimethylsilane Sodium hydride Triethoxysilane Triethylaluminum Triethoxyisobutylsilane Ethyltriethoxysilane TRIMETHYLSILANE