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| | TROPONE Basic information |
| Product Name: | TROPONE | | Synonyms: | TROPONE;2,4,6-Cyclo-heptatriene-1-one;2,4,6-Cycloheptatriene-1-one;Cycloheptatrienone;Tropon;2,4,6-CYCLOHEPTATRIENONE;LABOTEST-BB LT00233179;Tropone,97% | | CAS: | 539-80-0 | | MF: | C7H6O | | MW: | 106.12 | | EINECS: | 208-725-6 | | Product Categories: | | | Mol File: | 539-80-0.mol |  |
| | TROPONE Chemical Properties |
| Melting point | -7°C | | Boiling point | 113 °C/15 mmHg (lit.) | | density | 1.094 g/mL at 25 °C (lit.) | | refractive index | n20/D 1.615(lit.) | | Fp | >110°C | | storage temp. | -20°C | | color | very deep brown | | BRN | 1902335 |
| | TROPONE Usage And Synthesis |
| Uses | Tropone has been used in synthesis of:
- bicyclic δ-lactones via heterocyclic carbine-catalyzed [8+3] annulation pathway
- 6,7-benzobicyclo [3.2.2] nona-3,6,8-trien-2-one via thermal addition to bezyne
| | Synthesis Reference(s) | Journal of the American Chemical Society, 78, p. 5442, 1956 DOI: 10.1021/ja01601a077
The Journal of Organic Chemistry, 29, p. 960, 1964
Organic Syntheses, Coll. Vol. 9, p. 396, 1998 | | General Description | Metal-catalyzed [6+3] cycloaddition of tropone with azomethine ylides has been reported. |
| | TROPONE Preparation Products And Raw materials |
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