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Di-tert-butyl peroxide

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Company Name: Henan DaKen Chemical CO.,LTD.
Tel: +86-371-55531817
Email: info@dakenchem.com
Products Intro: Product Name:Di-tert-butyl peroxide
CAS:110-05-4
Purity:99% Package:100g,500g,1kg,5kg,10kg
Company Name: Henan Tianfu Chemical Co.,Ltd.
Tel: 0371-55170693
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Products Intro: CAS:110-05-4
Purity:99% Package:500G;1KG;5KG;25KG
Company Name: Mainchem Co., Ltd.
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Products Intro: Product Name:Di-tert-butyl peroxide
CAS:110-05-4
Company Name: Hangzhou FandaChem Co.,Ltd.
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Products Intro: Product Name:Di-tert-butyl peroxide
CAS:110-05-4
Purity:as in COA Package:as customers' requirements
Company Name: Chemson Industrial (Shanghai) Co., Ltd.
Tel: 86-21-65208861-ext8007
Email: sales1@chemson.com.cn
Products Intro: Product Name:Di-tert-butyl peroxide
CAS:110-05-4
Purity:99.50% Package:25kg

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Di-tert-butyl peroxide Basic information
Product Name:Di-tert-butyl peroxide
Synonyms:DIBUTYLPEROXIDE;DI-TERT-BUTYL PEROXIDE;DI-T-BUTYL PEROXIDE;DI-TERTIARY-BUTYL PEROXIDE;DTBP;BIS(1,1-DIMETHYLETHYL)PEROXIDE;Di-#ntert.-butyl peroxide;tert-Butyl peroxide (Luperox(R) DI)
CAS:110-05-4
MF:C8H18O2
MW:146.23
EINECS:203-733-6
Product Categories:Organics;Organic Peroxide;Oxidation;Synthetic Organic Chemistry
Mol File:110-05-4.mol
Di-tert-butyl peroxide Structure
Di-tert-butyl peroxide Chemical Properties
Melting point -30 °C
Boiling point 109-110 °C(lit.)
density 0.796 g/mL at 25 °C(lit.)
vapor pressure 40 mm Hg ( 20 °C)
refractive index n20/D 1.3891(lit.)
Fp 34 °F
storage temp. 2-8°C
solubility 0.063g/l
form Liquid
color Clear
Water Solubility immiscible
Merck 14,3461
BRN 1735581
Stability:May decompose explosively if heated, subjected to shock, or treated with reducing agents. Highly flammable. Refrigerate.
CAS DataBase Reference110-05-4(CAS DataBase Reference)
NIST Chemistry ReferenceDi-tert-butyl peroxide(110-05-4)
EPA Substance Registry SystemPeroxide, bis(1,1-dimethylethyl)(110-05-4)
Safety Information
Hazard Codes O,F,Xn
Risk Statements 7-11-68-52/53-2017/7/11
Safety Statements 14-16-3/7-36/37/39-14A-61-23
RIDADR UN 3107 5.2
WGK Germany 1
RTECS ER2450000
Autoignition Temperature182 °C
HS Code 2909 60 00
HazardClass 5.2
PackingGroup II
Hazardous Substances Data110-05-4(Hazardous Substances Data)
ToxicityLD50 orally in Rabbit: > 25000 mg/kg
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
Di-tert-butyl peroxide Usage And Synthesis
Chemical Propertiescolourless liquid
UsesAs polymerization catalyst.
General DescriptionClear colorless liquid.
Reactivity ProfileThe explosive instability of the lower dialkyl peroxides (e.g., dimethyl peroxide) and 1,1-bis-peroxides decreases rapidly with increasing chain length and degree of branching, the di-tert-alkyl derivatives being amongst the most stable class of peroxides. Though many 1,1-bis-peroxides have been reported, few have been purified because of the higher explosion hazards compared with the monofunctional peroxides. Di-tert-butyl peroxide is unlikely that this derivative would be particularly unstable compared to other peroxides in it's class, Bretherick 1979v.
Purification MethodsWash the peroxide with aqueous AgNO3 to remove olefinic impurities, water and dry (MgSO4). Free it from tert-butyl hydroperoxide by passage through an alumina column [Jackson et al. J Am Chem Soc 107 208 1985], and if necessary two high vacuum distillations from room temperature to a liquid-air trap [Offenbach & Tobolsky J Am Chem Soc 79 278 1957]. [Beilstein 1 IV 1619.] The necessary protection from EXPLOSION should be used.
Di-tert-butyl peroxide Preparation Products And Raw materials
Raw materialsHydrogen peroxide-->tert-Butanol-->tert-Butyl hydroperoxide
Preparation Products(4-METHOXY-PYRIDIN-2-YL)-METHANOL-->4-METHOXYPICOLINALDEHYDE
Tag:Di-tert-butyl peroxide(110-05-4) Related Product Information
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