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Ethyl 3-methyl-3-phenylglycidate

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Products Intro: Product Name:Ethyl 3-methyl-3-phenylglycidate
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Products Intro: Product Name:Ethyl 3-Methyl-3-Phenylglycidate
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Products Intro: CAS:77-83-8
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Products Intro: Product Name:Ethyl 3-methyl-3-phenylglycidate
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Ethyl 3-methyl-3-phenylglycidate Basic information
Product Name:Ethyl 3-methyl-3-phenylglycidate
Synonyms:ethylbeta-methylphenylglycidate;ethylesterof2,3-epoxy-3-phenylbutanoicacid;Fraeseol;Hydrocinnamic acid, alpha,beta-epoxy-beta-methyl-, ethyl ester;hydrocinnamicacid,α,β-epoxy-β-methyl-,ethylester;methyl-3phenyl-3glycidated’ethyle;Oxiranecarboxylic acid, 3-methyl-3-phenyl-, ethyl ester;Oxiranecarboxylicacid,3-methyl-3-phenyl-,ethylester
Product Categories:
Mol File:77-83-8.mol
Ethyl 3-methyl-3-phenylglycidate Structure
Ethyl 3-methyl-3-phenylglycidate Chemical Properties
Boiling point 272-275 °C(lit.)
density 1.087 g/mL at 25 °C(lit.)
refractive index n20/D 1.505(lit.)
Fp >230 °F
storage temp. Store below +30°C.
BRN 12299
CAS DataBase Reference77-83-8(CAS DataBase Reference)
NIST Chemistry ReferenceGlycidic acid, 3-methyl-3-phenyl, ethyl ester(77-83-8)
EPA Substance Registry SystemOxiranecarboxylic acid, 3-methyl-3-phenyl-, ethyl ester(77-83-8)
Safety Information
Hazard Codes Xi
Risk Statements 10-36/37/38
Safety Statements 16-26-36/37/39
RIDADR UN 1993 3/PG 3
WGK Germany 2
RTECS MW5250000
HS Code 29189090
Hazardous Substances Data77-83-8(Hazardous Substances Data)
ToxicityLD50 orally in Rabbit: 5470 mg/kg
MSDS Information
3-Methyl-3-phenyl glycidic acid ethyl ester English
ACROS English
SigmaAldrich English
ALFA English
Ethyl 3-methyl-3-phenylglycidate Usage And Synthesis
Chemical Propertiesclear yellow liquid
UsesPerfumery, flavors.
UsesEthyl 3-methyl-3-phenylglycidate is a synthetic flavoring agent that is a glycidic acid ester. It is a colorless to pale yellow liquid with a strong fruit odor suggestive of strawberries. It is unstable to alkali and moderately stable to weak organic acids. It should be stored in glass, tin, or aluminum containers. It is soluble in fixed oils and in propylene glycol. It is used in flavors for strawberry note and has application in candy, beverages, and ice cream at 6–20 ppm. It is also termed aldehyde c-16.
General DescriptionClear, colorless to yellowish liquid with a strawberry-like odor.
Air & Water ReactionsInsoluble in water.
Reactivity ProfileEsters, such as Ethyl 3-methyl-3-phenylglycidate, react with acids to liberate heat along with alcohols and acids. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Heat is also generated by the interaction of esters with caustic solutions. Flammable hydrogen is generated by mixing esters with alkali metals and hydrides.
Fire HazardEthyl 3-methyl-3-phenylglycidate is probably combustible.
Safety ProfileMddly toxic by ingestion. Mutation data reported. Combustible liquid. When heated to decomposition it emits acrid smoke and irritating fumes. See also ALDEHYDES.
Ethyl 3-methyl-3-phenylglycidate Preparation Products And Raw materials
Raw materialsXylene-->Sodium ethoxide-->Ethyl chloroacetate-->Acetophenone-->Sodium amide-->Propiophenone
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