|
|
| | Lithium dihydrogen phosphate Basic information |
| | Lithium dihydrogen phosphate Chemical Properties |
| Melting point | >100°C | | density | 2.5 g/mL at 25 °C(lit.) | | storage temp. | Inert atmosphere,Room Temperature | | form | Powder | | Specific Gravity | 2.461 | | color | white | | Water Solubility | Slightly soluble in water. | | Stability: | Stable. Incompatible with strong oxidizing agents. | | Major Application | battery precursors
catalysts
material synthesis precursor | | InChI | InChI=1S/Li.H3O4P.H/c;1-5(2,3)4;/h;(H3,1,2,3,4); | | InChIKey | AZOORWHXDYIBGH-UHFFFAOYSA-N | | SMILES | P(O)(O)(O)=O.[LiH] | | CAS DataBase Reference | 13453-80-0(CAS DataBase Reference) | | EPA Substance Registry System | Phosphoric acid, monolithium salt (13453-80-0) |
| Hazard Codes | Xn | | Risk Statements | 22-36/37/38 | | Safety Statements | 26-36 | | WGK Germany | 3 | | RTECS | TC6593950 | | TSCA | TSCA listed | | HS Code | 28352990 | | Storage Class | 11 - Combustible Solids | | Toxicity | mouse,LD50,oral,910mg/kg (910mg/kg),"Aktual'nye Problemy Gigieny Truda. Current Problems of Labor Hygiene," Tarasenko, N.Y., ed. Moscow, Pervyi Moskovskii Meditsinskii Inst., 1978Vol. -, Pg. 28, 1978. |
| | Lithium dihydrogen phosphate Usage And Synthesis |
| Description | Lithium dihydrogen phosphate, also known as LDP, is a White crystalline powder with the formula LiH2PO4. It is soluble in water. LiH2PO4 is usually prepared by a stoichiometric reaction of Li2СO3 and 85% orthophosphoric acid[1]. It is often used as a raw material for the preparation of cathode materials for lithium batteries or as phosphate in chemical reactions. | | Chemical Properties | White crystalline powder | | Uses | Precursor for LiMX2O7 (M = Fe, V; x =P, As) cathode materials.1 | | Uses | Lithium Dihydrogen Phosphate is used in preparation method of lithium hydroxide from lithium-containing low-magnesium brine in lithium phosphate manner. | | General Description | This product has been enhanced for energy efficiency. | | Solubility in water | At 0°C， the solubility of lithium dihydrogen phosphate in water is about 55.8wt % (126.2 g of LiH2PO4 /100 g of water)[1].
At 22°C, the solubility of lithium dihydrogen phosphate corresponds to ~ 153.8 g of LiH2PO4/100 g of water.
At 25°C, it doesn't dissolve in water[2]. | | References | [1] A.P. Voronov, G.N. Babenko, V.M. Puzikov, A.N. Iurchenko, Growth of LiH2PO4 single crystals from phosphate solutions, Journal of Crystal Growth, 2013, 374, 49–52.
[2] R. W. Berg, A. V. Nikiforov, N. J. Bjerrum, Vapor pressure and specific electrical conductivity in the H2O–LiH2PO4–LiPO3 system—a novel electrolyte for water electrolysis at elevated temperature.Ionics, 2021, 27, 703–719. |
| | Lithium dihydrogen phosphate Preparation Products And Raw materials |
|