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Methyl-5-norbornene-2,3-dicarboxylic anhydride

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CAS:25134-21-8
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CAS:25134-21-8
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CAS:25134-21-8
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CAS:25134-21-8
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Products Intro: Product Name:Methyl-5-norbornene-2,3-dicarboxylic anhydride
CAS:25134-21-8
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Methyl-5-norbornene-2,3-dicarboxylic anhydride manufacturers

  • Nadic Anhydride (NA)
  •   Nadic Anhydride   (NA) pictures
  • $0.00 / 5KG
  • 2023-11-13
  • CAS:25134-21-8
  • Min. Order: 1KG
  • Purity: ≥98.0
  • Supply Ability: 71000
Methyl-5-norbornene-2,3-dicarboxylic anhydride Basic information
Product Name:Methyl-5-norbornene-2,3-dicarboxylic anhydride
Synonyms:NADIC METHYL ANHYDRIDE;NADIC(R) METHYL ANHYDRIDE;NADIC(TM) METHYL ANHYDRIDE;NMA;MNA;3-dione,3a,4,7,7a-tetrahydromethyl-7-methanoisobenzofuran-1;4,7-Methanoisobenzofuran-1,3-dione, 3a,4,7,7a-tetrahydromethyl-, (3aalpha,4alpha,7alpha,7aalpha)-;4,7-methanoisobenzofuran-1,3-dione,3a,4,7,7a-tetrahydromethyl-,(3aalpha,4al
CAS:25134-21-8
MF:C10H10O3
MW:178.18
EINECS:246-644-8
Product Categories:Organics;Norbornene Derivatives
Mol File:25134-21-8.mol
Methyl-5-norbornene-2,3-dicarboxylic anhydride Structure
Methyl-5-norbornene-2,3-dicarboxylic anhydride Chemical Properties
Boiling point 140°C (10 mmHg)
density 1.232 g/mL at 25 °C(lit.)
vapor density 6.1 (20 °C, vs air)
vapor pressure 5 mm Hg ( 120 °C)
refractive index n20/D 1.506(lit.)
Fp >230 °F
storage temp. room temp
solubility Miscible with acetone, benzene, naphtha and xylene.
form Oily Liquid
pka4.42[at 20 ℃]
color Clear light yellow
Water Solubility REACTS
Sensitive Moisture Sensitive
BRN 162395
LogP-4.01 at 20℃
CAS DataBase Reference25134-21-8(CAS DataBase Reference)
NIST Chemistry Reference4,7-Methanoisobenzofuran-1,3-dione, 3a,4,7,7a-tetrahydromethyl-(25134-21-8)
EPA Substance Registry System4,7-Methanoisobenzofuran-1,3-dione, 3a,4,7,7a-tetrahydromethyl-, (3aR,4S,7R,7aS)-rel- (25134-21-8)
Safety Information
Hazard Codes Xn,C
Risk Statements 22-36/37/38-42-34
Safety Statements 39-45-36/37/39-26
RIDADR UN 3265 8/PG 2
WGK Germany 3
RTECS RB9100000
TSCA Yes
HazardClass 6.1
PackingGroup III
HS Code 29172000
Hazardous Substances Data25134-21-8(Hazardous Substances Data)
ToxicityLD50 oral in rat: 914mg/kg
MSDS Information
ProviderLanguage
Methyl-5-norbornene-2,3-dicarboxylic anhydride English
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Methyl-5-norbornene-2,3-dicarboxylic anhydride Usage And Synthesis
Chemical Propertiesclear light yellow oily liquid
UsesMethyl-5-norbornene-2,3-dicarboxylic anhydride is used as a curing agent in epoxy resins and in the preparation of vertically aligned and penetrated carbon nanotube/polymer film. It serves as an intermediate in polyesters, alkyd resins and plasticizers. It is also used in electrical laminating and filament-winding. Further, it is used in the preparation of methyl nadimides endcapped resins based on tris(3-aminophenyl)phosphine oxide. It is utilized in the flame retarding treatment.
General Descriptionadditional information see 45359 Epoxy Embedding Medium kit
Flammability and ExplosibilityNon flammable
Purification MethodsPurify the anhydride by thin layer chromatography on Al2O3 (previously boiled in EtOAc) and eluted with hexane/*C6H6 (1:2) then recrystallise it from *C6H6/hexane. The free acid has m 118.5-119.5o. [Miranov et al. Tetrahedron 19 1939 1963, Beilstein 17/11 V 199.]
Methyl-5-norbornene-2,3-dicarboxylic anhydride Preparation Products And Raw materials
Raw materialsDiethyl ether-->Benzene-->Hexane-->Lithium Aluminum Hydride-->p-Toluenesulfonic acid-->CIS-BUTENEDIOIC ANHYDRIDE-->Dicyclopentadiene-->METHYLCYCLOPENTADIENE DIMER-->2-METHYL-2-CYCLOPENTEN-1-ONE
Tag:Methyl-5-norbornene-2,3-dicarboxylic anhydride(25134-21-8) Related Product Information
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