(2R,3R,5R,11S)-3,11-Methanoaspidofractinin-22-one

(2R,3R,5R,11S)-3,11-Methanoaspidofractinin-22-one Basic information
Product Name:(2R,3R,5R,11S)-3,11-Methanoaspidofractinin-22-one
Synonyms:(2R,3R,5R,11S)-3,11-Methanoaspidofractinin-22-one;Kopsan-22-one;Kopsanone;6H,13aH-3a,5a-Ethano-5,11-methano-1H-indolizino[8,1-cd]carbazol-14-one, 2,3,4,5,11,12-hexahydro-, (3aR,5R,5aR,10bR,11R,13aS)-
CAS:6662-83-5
MF:C20H22N2O
MW:306.4
EINECS:
Product Categories:
Mol File:6662-83-5.mol
(2R,3R,5R,11S)-3,11-Methanoaspidofractinin-22-one Structure
(2R,3R,5R,11S)-3,11-Methanoaspidofractinin-22-one Chemical Properties
Melting point 284-5°C
Safety Information
MSDS Information
(2R,3R,5R,11S)-3,11-Methanoaspidofractinin-22-one Usage And Synthesis
DescriptionThis alkaloid from Vinca erecta Rgl. et Schmalh does not appear to be identical with that isolated from Aspidosperma duckei Hub. and A. macrocarpa Mart. This base is reported to have a specific rotation of [C\' 1 D + 98.6° (c 0.18, CHCI3). The structure has been assigned on the basis of chemical and spectroscopic evidence.
ReferencesRakhimov et al., Khim. Prir. Soedin., 6, 713 (1970)
(2R,3R,5R,11S)-3,11-Methanoaspidofractinin-22-one Preparation Products And Raw materials
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