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o-Anisaldehyde

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CAS:135-02-4
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  • o-Anisaldehyde
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  • 2025-12-08
  • CAS:135-02-4
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  • o-Anisaldehyde
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  • 2025-12-03
  • CAS:135-02-4
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  • Purity: 99%
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  • o-Anisaldehyde
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  • 2025-06-20
  • CAS:135-02-4
  • Min. Order: 1kg
  • Purity: 99.00%
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o-Anisaldehyde Basic information
Description References
Product Name:o-Anisaldehyde
Synonyms:o-Anisaldehyde:2-Methoxybenzaldehyde;o-Anisaldehyde, 98% 100GR;o-Anisaldehyde, 98% 5GR;2-Methoxybenzaldehyde Salicylaldehyde Methyl Ether;Adjacent Methoxy benzene forMaldehyde;o-Anisaldehyde 〔o-Methoxybenzaldehyde〕;2-methoxy-benzaldehyd;2-Methoxybenzenecarboxaldehyde
CAS:135-02-4
MF:C8H8O2
MW:136.15
EINECS:205-171-7
Product Categories:aldehyde;Fluorescent;Pyridines;Aromatic Aldehydes & Derivatives (substituted);Benzaldehyde
Mol File:135-02-4.mol
o-Anisaldehyde Structure
o-Anisaldehyde Chemical Properties
Melting point 34-40 °C(lit.)
Boiling point 238 °C(lit.)
density 1.127 g/mL at 25 °C(lit.)
FEMA 4077 | O-ANISALDEHYDE
refractive index 1.5608
Fp 244 °F
storage temp. 2-8°C
solubility Solubility Slightly soluble in water; soluble in ethanol
form Low Melting Crystalline Mass
Specific Gravity1.127
color Light yellow to pale brown
Odorat 10.00 % in propylene glycol. sweet powdery hawthorn guaiacol vanilla acetophenone almond
PH RangeNon1 uorescence (3.1) to green 1 uorescence (4.4)
Odor Typeanisic
biological sourcesynthetic
Water Solubility insoluble
Sensitive Air Sensitive
JECFA Number2062
BRN 606301
Major ApplicationBattery, hair dyes, bird repellents, cosmetics, antibacterial, antipyretic
LogP1.72
CAS DataBase Reference135-02-4(CAS DataBase Reference)
NIST Chemistry ReferenceBenzaldehyde, 2-methoxy-(135-02-4)
EPA Substance Registry SystemBenzaldehyde, 2-methoxy- (135-02-4)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38-36/38
Safety Statements 26-36-37/39
WGK Germany 2
RTECS BZ2610000
9-23
TSCA Yes
HS Code 29124900
ToxicityLD50 orally in Rabbit: 2500 mg/kg LD50 dermal Rabbit > 5000 mg/kg
MSDS Information
ProviderLanguage
2-Methoxybenzaldehyde English
SigmaAldrich English
ACROS English
ALFA English
o-Anisaldehyde Usage And Synthesis
DescriptionO-Anisaldehyde (also 2-methoxybenzaldehyde) is found in cassia oil, cinnamon bark, and cinnamon bark oil. It is a clear colorless liquid with a strong aroma.
O-Anisaldehyde is used as a flavor agent in foods including nonalcoholic/alcoholic beverages, baked goods, chewing gum, confections, frozen dairy, fruit ices, hard/soft candy, instant coffee, tea, Jams, jellies, and milk products. O-Anisaldehyde has been used to examine the acaricidal activity of Periploca sepium oil and its active component against Tyrophagus and to obtain good enantioselectivities using Cu(OAc)(2)-bis(oxazolines) via hydrogen bonding in asymmetric Henry reaction.
References[1] George A. Burdock (2016) Fenraoli’s Handbook of Flavor Ingredients, Sixth Edition.
[2] https://www.alfa.com/en/catalog/A10770/
Descriptiono-Methoxybenzaldehyde has a faint, sweet, floral odor. It blends well with cassia. It has a spice-like flavor, quite bitter above 30 - 40 ppm. May be prepared from salicylaldehyde and dimethyl sulfate in weak alkaline solution.
Chemical Propertieslight yellow to pale brown
Chemical PropertiesColorless to cream amber crystalline powder; sweet powdery hawthorn guaiacol vanilla acetophenone almond aroma.
OccurrenceReported found in Cassia oil, cinnamon bark, and Cinnamon bark oil (Cinnamomum zeylanicum Blume), Sri Lanka (0.09–0.15%)
Uses2-Methoxybenzaldehyde has been used to examine the acaricidal activity of Periploca sepium oil and its active component against Tyrophagus. It has also been used to obtain good enantioselectivities using Cu(OAc)(2)-bis(oxazolines) via hydrogen bonding in asymmetric Henry reaction.
Uses2-Methoxybenzaldehyde has been used to obtain good enantioselectivities using Cu(OAc)(2)-bis(oxazolines) via hydrogen bonding in asymmetric Henry reaction.
UsesIntermediate.
DefinitionChEBI: 2-Methoxybenzaldehyde is a carbonyl compound.
Aroma threshold valuesMedium strength odor; anisic type; recommend smelling in a 10.00% solution or less.
Taste threshold valuesSweet powdery guaiacol musty vanilla floral almond taste at 50 ppm in water.
Synthesis Reference(s)Journal of Heterocyclic Chemistry, 11, p. 943, 1974 DOI: 10.1002/jhet.5570110616
Tetrahedron Letters, 25, p. 1843, 1984 DOI: 10.1016/S0040-4039(01)90056-5
Biochem/physiol ActionsNaturally-occurring aromatic aldehyde with acaricidal activity. May condense with L-tryptophan in foods to form the corresponding phenolic tetrahydro-β-carboline-3-carboxylic acid which is a potent antioxidant.
Safety ProfileModerately toxic by ingestion. A skin irritant. Mutation data reported. Combustible liquid. When heated to decomposition it emits acrid smoke and irritating fumes.
Tag:o-Anisaldehyde(135-02-4) Related Product Information
4-Hydroxybenzaldehyde Benzaldehyde 2-Nitrobenzaldehyde Guaiacol Cuminaldehyde Veratraldehyde 2-Carboxybenzaldehyde 2-Formylbenzenesulfonic acid sodium salt 3,5-Dimethoxybenzaldehyde Anisole (Trifluoromethoxy)benzene 4-Dimethylaminobenzaldehyde 4-Methoxyphenol 2-BROMO-2'-METHOXYACETOPHENONE Salicylaldehyde o-Anisic acid 2-FLUOROCYCLOHEXANONE 2-Methoxycinnamic acid

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