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ChemicalBook > Product Catalog >Chemical Reagents >Organic reagents >Phosphine ligand >(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE

(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE

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(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE Suppliers list
Company Name: Shanghai Arbor Chemical Co., Ltd.
Tel: 021-60451682
Email: act@arborchemical.com
Products Intro: Product Name:(R)-SIPHOS
CAS:443965-14-8
Purity:97% Package:10G 100G 1KG 25KG
Company Name: Dayang Chem (Hangzhou) Co.,Ltd.
Tel: 571-88938639 +8617705817739
Email: info@dycnchem.com
Products Intro: Product Name:N-Dimethyl-[(R)-1,1′-spirobiindane-7,7′-diyl]phosphoramidite((R)-SIPHOS)
CAS:443965-14-8
Purity:0.95&0.99 Package:0.1KG;1KG;1000KG Remarks:High quality
Company Name: Zhuoer Chemical Co., Ltd
Tel: 02120970332; +8613524231522
Email: sales@zhuoerchem.com
Products Intro: Product Name:(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE
Purity:0.99 Package:25KG;5KG;1KG
Company Name: CR Corporation Lomited
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Email: fred.wen@crcorporation.cn
Products Intro: Product Name:(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE
CAS:443965-14-8
Company Name: Labnetwork lnc.
Tel: +86-27-50766799 +8618062016861
Email: contact@labnetwork.com
Products Intro: Product Name:(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE
CAS:443965-14-8
Purity:95% Package:100g; 1kg Remarks:LN02178856
(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE Basic information
Reaction
Product Name:(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE
Synonyms:N-DIMETHYL-[(S)-1,1'-SPIROBIINDANE-7,7'-DIYL]PHOSPHORAMIDITE;N-DIMETHYL-[(R)-1,1'-SPIROBIINDANE-7,7'-DIYL]PHOSPHORAMIDITE;(R)-SIPHOS;(S)-SIPHOS;(11AS)-(-)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE;(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE;(11aR)-(+)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-dimethylamine,min.98%(R)-SIPHOS;N-DIMETHYL-[(R)-1,1-SPIROBIINDANE-7,7-DIYL]PHOSPHORAMIDITE, (R)-SIPHOS
CAS:443965-14-8
MF:C19H20NO2P
MW:325.34
EINECS:
Product Categories:Chiral Phosphine;Chiral Spiro Ligand;CPN
Mol File:443965-14-8.mol
(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE Structure
(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE Chemical Properties
Melting point 95-96°C
Boiling point 429.6±55.0 °C(Predicted)
alpha +505° (c 0.5, CH2Cl2)
form solid
pka2.19±0.20(Predicted)
color white
optical activity[α]22/D +480°, c = 1 in chloroform
Sensitive moisture sensitive
Safety Information
WGK Germany 3
HS Code 29299090
MSDS Information
(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE Usage And Synthesis
Reaction
  1. Chiral ligands for the rhodium-catalyzed asymmetric hydrogenation of α-dehydroamino esters.
  2. Chiral ligands for the rhodium-catalyzed asymmetric hydrogenation of itaconic acid derivatives.
  3. Chiral ligands for rhodium-catalyzed asymmetric hydrogenation of β-dehydroaminoesters.
  4. Chiral ligands for rhodium-catalyzed asymmetric hydrogenation of enamides.
  5. Chiral ligands for rhodium-catalyzed asymmetric Pauson-Khand reaction.
  6. Chiral ligands for palladium-catalyzed asymmetric umpolung allylation of aldehydes.
Reactions of 443965-14-8_1
Reactions of 443965-14-8_2
Chemical PropertiesWhite power
Tag:(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE(443965-14-8) Related Product Information
Indene Dimethylamine (11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE