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2,4-Dichlorobenzyl chloride

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Products Intro: Product Name:2,4-Dichlorobenzyl chloride
CAS:94-99-5
Purity:99% Package:1KG;10.00;USD
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CAS:94-99-5
Purity:99.0% Package:1KG;|25KG
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CAS:94-99-5
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Products Intro: Product Name:2,4-Dichlorobenzyl chloride
CAS:94-99-5
Purity:98%(Min,GC) Package:100g;1kg;5kg,10kg,25kg,50kg
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Products Intro: Product Name:TIANFU-CHEM 2,4-Dichlorobenzyl chloride
CAS:94-99-5
Purity:99% Package:25KG;5KG;1KG

2,4-Dichlorobenzyl chloride manufacturers

2,4-Dichlorobenzyl chloride Basic information
Product Name:2,4-Dichlorobenzyl chloride
Synonyms:2,4-dichloro-1-(chloromethyl)-benzen;2,4-dichloro-1-chloromethyl-benzene;-2,4-Trichlorotoluene;benzene,2,4-dichloro-1-(chloromethyl)-;Toluene, alpha2,4-trichloro-;toluene,α,2,4-trichloro-;α,2,4-trichlorotoluene;ALPHA,2,4-TRICHLOROTOLUENE
CAS:94-99-5
MF:C7H5Cl3
MW:195.47
EINECS:202-381-0
Product Categories:Aromatics;Miscellaneous Reagents;Econazole Nitrate;Aromatic Halides (substituted)
Mol File:94-99-5.mol
2,4-Dichlorobenzyl chloride Structure
2,4-Dichlorobenzyl chloride Chemical Properties
Melting point -2.6 °C (lit.)
Boiling point 248 °C (lit.)
density 1.407 g/mL at 25 °C (lit.)
refractive index n20/D 1.576(lit.)
Fp >230 °F
storage temp. Inert atmosphere,2-8°C
solubility Chloroform (Slightly), Ethyl Acetate (Slightly)
form Oily Liquid
color Clear colorless to very light yellow
BRN 387220
InChIInChI=1S/C7H5Cl3/c8-4-5-1-2-6(9)3-7(5)10/h1-3H,4H2
InChIKeyIRSVDHPYXFLLDS-UHFFFAOYSA-N
SMILESC1(CCl)=CC=C(Cl)C=C1Cl
LogP4.08
CAS DataBase Reference94-99-5(CAS DataBase Reference)
NIST Chemistry ReferenceBenzene, 2,4-dichloro-1-(chloromethyl)-(94-99-5)
EPA Substance Registry SystemBenzene, 2,4-dichloro-1-(chloromethyl)- (94-99-5)
Safety Information
Hazard Codes C,N
Risk Statements 34-37-50/53-22
Safety Statements 26-36/37/39-45-61-60
RIDADR UN 3265 8/PG 2
WGK Germany 3
19
Hazard Note Corrosive
TSCA Yes
HazardClass 8
PackingGroup II
HS Code 29036990
MSDS Information
ProviderLanguage
2,4-Dichlorobenzoylchloride English
SigmaAldrich English
ACROS English
ALFA English
2,4-Dichlorobenzyl chloride Usage And Synthesis
Chemical Propertiesclear colorless to very light yellow oily liquid
Uses2,4-Dichlorobenzyl chloride was used as starting reagent for the synthesis of series of novel 1,2,4-triazolium derivatives.
Uses2,4-Dichlorobenzyl chloride is a reagent used in the addition of dichlorobenzene.
Synthesis
2,4-Dichlorobenzyl alcohol

1777-82-8

2,4-Dichlorobenzyl chloride

94-99-5

GENERAL STEPS: 2,4-dichlorobenzyl alcohol (17.7 g, 0.1 mol), dichloromethane (30 mL), and N,N-dimethylformamide (DMF, 1 mL) were added to a 100 mL round-bottomed flask, followed by the slow dropwise addition of phosphorus trichloride (4.68 g, 0.034 mol). The reaction mixture was heated to reflux temperature (60-80°C) and the reaction lasted for 2-3 hours. The progress of the reaction was monitored by thin layer chromatography (TLC) until the complete disappearance of the raw material. After completion of the reaction, 2,4-dichlorobenzyl chloride (17.99 g, 92% yield) was purified by distillation.

References[1] Patent: CN106117028, 2016, A. Location in patent: Paragraph 0053; 0054; 0055; 0056
Tag:2,4-Dichlorobenzyl chloride(94-99-5) Related Product Information
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