- Vinylferrocene
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2025-12-24
- CAS:1271-51-8
- Min. Order: 1KG
- Purity: 99.0%
- Supply Ability: 10000KG
- Vinylferrocene
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- $1.00
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2019-07-06
- CAS:1271-51-8
- Min. Order: 1G
- Purity: 98%
- Supply Ability: 100kg
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| | Vinylferrocene Basic information |
| | Vinylferrocene Chemical Properties |
| Melting point | 51-53 °C (lit.) | | Boiling point | 80-85 °C/0.2 mmHg (lit.) | | Fp | 144 °F | | storage temp. | Sealed in dry,2-8°C | | form | crystal | | color | orange | | Water Solubility | Insoluble in water. | | Hydrolytic Sensitivity | 4: no reaction with water under neutral conditions | | Exposure limits | ACGIH: TWA 1 mg/m3
NIOSH: TWA 1 mg/m3 | | Stability: | Stable. Highly flammable. Incompatible with strong acids, strong oxidizing agents. | | InChI | InChI=1S/C7H7.C5H5.Fe/c1-2-7-5-3-4-6-7;1-2-4-5-3-1;/h2-6H,1H2;1-5H; | | InChIKey | LCPVTGDQYVLJHU-UHFFFAOYSA-N | | SMILES | [C]1(C=C)[CH][CH][CH][CH]1.[CH]1[CH][CH][CH][CH]1.[Fe] |^1:0,3,4,5,6,7,8,9,10,11| | | NIST Chemistry Reference | Vinylferrocene(1271-51-8) |
| Hazard Codes | F | | Risk Statements | 11-22 | | Safety Statements | 16-22-24/25-7/9-33 | | RIDADR | UN 1325 4.1/PG 2 | | WGK Germany | 3 | | F | 10 | | TSCA | No | | HazardClass | 4.1 | | PackingGroup | II | | HS Code | 29319090 | | Storage Class | 4.1B - Flammable solid hazardous materials | | Hazard Classifications | Flam. Sol. 1 |
| | Vinylferrocene Usage And Synthesis |
| Chemical Properties | crystalline solid | | Uses | Used in the synthesis of 2-aminomethylferrocenes from vinyl ferrocene and lithium amides. | | Definition | ChEBI: Ferrocene substituted on one of the cyclopentadienyl rings by a vinyl group. | | reaction suitability | core: iron
reagent type: catalyst | | Purification Methods | Dissolve vinylferrocene in Et2O, wash it with H2O and brine, dry (Na2SO4), and evaporate to a small volume. Purify it through an Al2O3 (Spence grade H) column by eluting the yellow band with pet ether (b 40-60o). The low melting orange crystals can be sublimed. The tetracyanoethylene adduct crystallises from *C6H6/pentane and has m 137-139o(dec). [Horspool & Sutherland Can J Chem 46 3453 1968, Berger et al. J Org Chem 39 377 1974, Rauch & Siegel J Organomet Chem 11 317 1968, Beilstein 16 III 1787.] |
| | Vinylferrocene Preparation Products And Raw materials |
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