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(+)-N-BENZYL-N-METHYL-DINAPHTHO[2,1-D:1',2']DIOXAPHOSPHEPIN-4-AMINE, (11BS)

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(+)-N-BENZYL-N-METHYL-DINAPHTHO[2,1-D:1',2']DIOXAPHOSPHEPIN-4-AMINE, (11BS) Suppliers list
Company Name: CR Corporation Lomited
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Email: fred.wen@crcorporation.cn
Products Intro: Product Name:(+)-N-BENZYL-N-METHYL-DINAPHTHO[2,1-D:1',2']DIOXAPHOSPHEPIN-4-AMINE, (11BS)
CAS:490023-37-5
Company Name: Shaoxin Catsyn Co., Ltd.
Tel: +undefined-0575-82040869 +86-0575-82040869;
Email: sales@catsyn.com
Products Intro: Product Name:(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a;3,4-a']dinaphthalen-4-yl)benzyl(methyl)amine
CAS:490023-37-5
Purity:98% Min. Package:1G;1KG;100KG Remarks:SC11360
Company Name: Aladdin Scientific
Tel: +1-833-552-7181
Email: sales@aladdinsci.com
Products Intro: Product Name:(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a;3,4-a']dinaphthalen-4-yl)benzyl(methyl)amine
CAS:490023-37-5
Purity:99% Package:$181.9/100mg;$411.9/250mg;$727.9/500mg;$1311.9/1g;Bulk package Remarks:99%
Company Name: Amadis Chemical Company Limited
Tel: 571-89925085
Email: sales@amadischem.com
Products Intro: Product Name:N-Benzyl-N-methyldinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine
CAS:490023-37-5
Purity:0.97 Package:mgs,gs,kgs Remarks:A871851
Company Name: ABCR GmbH & CO. KG
Tel: 49 721 95061 0
Email: info@abcr.de
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(+)-N-BENZYL-N-METHYL-DINAPHTHO[2,1-D:1',2']DIOXAPHOSPHEPIN-4-AMINE, (11BS) Basic information
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Product Name:(+)-N-BENZYL-N-METHYL-DINAPHTHO[2,1-D:1',2']DIOXAPHOSPHEPIN-4-AMINE, (11BS)
Synonyms:(S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BENZYL(METHYL)AMINE;(S)-(+)-BENZYL(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)METHYLAMINE;(+)-N-BENZYL-N-METHYL-DINAPHTHO[2,1-D:1',2']DIOXAPHOSPHEPIN-4-AMINE, (11BS);3,4-a']dinaphthalen-4-yl)benzyl(methyl)amine, 99%;(S)-(+)-Benzyl(3,5-dioxa-4-phospha-cyclohepta[2,1-a;(S)-(+)-BENZYL(3,5-DIOXA-4-PHOSPHA-CYCL&;3,4-a']dinaphthalen-4-yl)benzyl(methyl)amine,99%;3,4-a′]dinaphthalen-4-yl)MethylaMine
CAS:490023-37-5
MF:C28H22NO2P
MW:435.45
EINECS:
Product Categories:Chiral Phosphine;CPN
Mol File:490023-37-5.mol
(+)-N-BENZYL-N-METHYL-DINAPHTHO[2,1-D:1',2']DIOXAPHOSPHEPIN-4-AMINE, (11BS) Structure
(+)-N-BENZYL-N-METHYL-DINAPHTHO[2,1-D:1',2']DIOXAPHOSPHEPIN-4-AMINE, (11BS) Chemical Properties
Melting point 155-159 °C
Boiling point 635.4±48.0 °C(Predicted)
alpha +356° (c 0.32, CHCl3)
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
pka0.08±0.20(Predicted)
form Powder
color white
Sensitive moisture sensitive
Safety Information
Risk Statements 36/37/38
Safety Statements 26-36/37/39
WGK Germany 3
MSDS Information
ProviderLanguage
SigmaAldrich English
(+)-N-BENZYL-N-METHYL-DINAPHTHO[2,1-D:1',2']DIOXAPHOSPHEPIN-4-AMINE, (11BS) Usage And Synthesis
Reaction
  1. The ligand has been used in Ir-catalyzed asymmetric hydrogenation of substituted benzophenone N-H imines.
  2. The ligand has been used in the rhodium-catalyzed enantioselective hydrogenation of (E)-N-acylated dehydro-β-aminoacid esters.
Reactions of 490023-37-5
UsesDSM MonoPhos Family of Highly Efficient Privileged Ligands
(+)-N-BENZYL-N-METHYL-DINAPHTHO[2,1-D:1',2']DIOXAPHOSPHEPIN-4-AMINE, (11BS) Preparation Products And Raw materials
Tag:(+)-N-BENZYL-N-METHYL-DINAPHTHO[2,1-D:1',2']DIOXAPHOSPHEPIN-4-AMINE, (11BS)(490023-37-5) Related Product Information
Benzophenone (+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR) (S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1R)-1-PHENYLETHYL]AMINE,DICHLOROMETHANE ADDUCT (R)-MONOPHOS (+)-N,N-BIS[(1R)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR) (+)-N-BENZYL-N-METHYL-DINAPHTHO[2,1-D:1',2']DIOXAPHOSPHEPIN-4-AMINE, (11BS)