ChemicalBook > Product Catalog >Inorganic chemistry >Inorganic salts >Metal halide and Halogen salt >Metal chlorides and salt >Zirconyl chloride octahydrate

Zirconyl chloride octahydrate

Zirconyl chloride octahydrate Suppliers list
Company Name: Hebei Chuanghai Biotechnology Co,.LTD
Tel: +86-13131129325
Email: sales1@chuanghaibio.com
Products Intro: Product Name:Zirconyl chloride octahydrate
CAS:13520-92-8
Purity:99% Package:1KG;1.60;USD|1KG;1.60;USD
Company Name: Henan Fengda Chemical Co., Ltd
Tel: +86-371-86557731 +86-13613820652
Email: info@fdachem.com
Products Intro: Product Name: Zirconyl chloride octahydrate
CAS:13520-92-8
Purity:99% Package:1kg;8USD|25kg;5USD|100kg;1USD
Company Name: Hebei Zhuanglai Chemical Trading Co.,Ltd
Tel: +8613343047651
Email: admin@zlchemi.com
Products Intro: Product Name:Zirconium Oxychloride Octahydrate
CAS:13520-92-8
Purity:99% Package:1kg;99USD|25kg;35USD
Company Name: Henan Tianfu Chemical Co.,Ltd.
Tel: +86-0371-55170693 +86-19937530512
Email: info@tianfuchem.com
Products Intro: Product Name:Zirconyl chloride octahydrate
CAS:13520-92-8
Purity:99% Package:25KG;5KG;1KG
Company Name: Shanxi Naipu Import and Export Co.,Ltd
Tel: +86-13734021967 +8613734021967
Email: kaia@neputrading.com
Products Intro: Product Name:Zirconium Oxychloride Octahydrate
CAS:13520-92-8
Purity:99 Package:1bag;100USD

Zirconyl chloride octahydrate manufacturers

Zirconyl chloride octahydrate Basic information
Synthesis
Product Name:Zirconyl chloride octahydrate
Synonyms:zirconyl(di)chloride;ZIRCONYL CHLORIDE TECHNICAL;Zirconyl chloride oc;Zirconyl chloride octahydrate, 98+% 100GR;Zirconyl chloride octahydrate, 98+% 5GR;Zirconyl Chloride, Octahydrate, Reagent, ACS;Zirconium(IV) oxychloride octahydrate puriss. p.a., >=99.5%;Zirconium(IV) oxychloride octahydrate Vetec(TM) reagent grade, 98%
CAS:13520-92-8
MF:Cl2H2O2Zr
MW:322.25
EINECS:603-909-6
Product Categories:13520-92-8
Mol File:13520-92-8.mol
Zirconyl chloride octahydrate Structure
Zirconyl chloride octahydrate Chemical Properties
Melting point 400°C (dec.)
Boiling point 210°C
density 1.91
storage temp. Store at +15°C to +25°C.
solubility H2O: soluble
form Crystalline Powder
Specific Gravity1.91
color White to light yellow
PH1 (50g/l, H2O, 20℃)
OdorOdorless
Water Solubility SOLUBLE
Sensitive Hygroscopic
Merck 14,10184
Exposure limitsACGIH: TWA 5 mg/m3; STEL 10 mg/m3
NIOSH: IDLH 25 mg/m3; TWA 5 mg/m3; STEL 10 mg/m3
Stability:Stable, but may be moisture sensitive. Incompatible with strong oxidizing agents.
CAS DataBase Reference13520-92-8(CAS DataBase Reference)
Safety Information
Hazard Codes C
Risk Statements 34-22-37
Safety Statements 26-36/37/39-45-27
RIDADR UN 3264 8/PG 3
WGK Germany 1
RTECS ZH7250000
TSCA Yes
HS Code 2827 49 90
HazardClass 8
PackingGroup III
ToxicityLD50 orally in Rabbit: 3500 mg/kg
MSDS Information
ProviderLanguage
Zirconyl chloride octahydrate English
SigmaAldrich English
ACROS English
ALFA English
Zirconyl chloride octahydrate Usage And Synthesis
SynthesisZircon is melted with caustic soda, rinsed, desiliconized, and then reacted with sulfuric acid, and then ammonia water is added to obtain zirconium hydroxide precipitate. Finished zirconium oxychloride.
Chemical PropertiesTetragonal prisms or needles. Deliquescent in moist air, evolves HCl and becomes dull in dry air. Soluble in H3O (slight hydrolysis) and alcohol. Lower hydrates are formed by heating a stream of HCl. It Liberates HCl on heating in air, and the solubility in water is gradually lost; it reverts to the oxide on calcination. Precipitation of an alcoholic solution with ether or acetone yields dizirconyl chloride Zr aO3Cl a -5HaO, which is sparingly soluble in water. The same compound deposits when a dilute aqueous solution of zirconyl chloride is allowed to stand for a month.
Chemical Propertiessolid
UsesZirconium dichloride oxide is utilized as a precursor to prepare other zirconium compounds. It is employed in acid dyes, pigment toners and antiperspirants. It finds application as a rubber additive and a fiber treatment agent. It is also used in paint drying, refractories, ceramics and glaze.
Production Methods Since zircon ZrSiO4, a mineral found in nature, is more difficult to work with, it is better to start from zirconia ZrO2 (baddeleyite), which is calcined, finely ground (the coarser particles are screened off with silk gauze) and converted to the sulfate by evaporation or treatment for several days with an excess of the warm cone. H2SO4. The solid residue, which consists of Zr(SO4)2 and unreacted ZrO2, is taken up in water (the solid is added in small portions to prevent solution heating). The sulfate dissolves slowly, and its solution may be aided by acidifying the water with some hydrochloric acid. The resultant milky suspension, which contains solid undissolved ZrO2 and SiO2 (or ZrSiO4), is allowed to stand for several hours and filtered. The weakly acidic sulfuric acid solution is precipitated with ammonia, and the hydroxide is filtered off. If the precipitate still exhibits a high Si content, it is dissolved in cone and hydrochloric acid and the solution is evaporated to dryness; this procedure is repeated several times. SiO2 and some basic zirconium chloride become the insoluble residue when redissolved in water. If no Si is evident in the hydroxide, the fresh gel is dissolved in cold hydrochloric acid, and the oxychloride is allowed to crystallize by adding cone, hydrochloric acid, or saturating it with HCl. The crystals are filtered and washed with 8N HCl.
General DescriptionThis product is used as a potential green catalyst.
Purification MethodsRecrystallise the chloride several times from water [Ferragina et al. J Chem Soc, Dalton Trans 265 1986]. Recrystallisation from 8M HCl gives the octahydrate as white needles on concentrating. It is also formed by hydrolysing ZrCl4 with water. After one recrystallisation from H2O, 99+% grade zirconyl chloride had Ag, Al, As, Cd, Cu, Hf, Mg, Na, Sc and V at 20, 1.8, 0.6, 0.6, 0.4, 8.4, 0.4, 2.4, 80 and 3 ppm, respectively. (See above.) METAL-ORGANIC COMPOUNDS This section contains metal-organic compounds as well as ammonium and metal salts of organic acids. (For Introduction see p 445.)
Tag:Zirconyl chloride octahydrate(13520-92-8) Related Product Information
Calcium chloride C. I. Pigment Blue 30 (77420) Bethanechol ZIRCONYL NITRATE HYDRATE Aluminum chlorohydrate Choline chloride Ammonium chloride Sulfuryl chloride Zirconium oxychloride Zirconium tetrachloride Copper oxychloride Sodium chloride Calcium phosphorylcholine chloride Thionyl chloride Potassium chloride Phenylphosphonic dichloride Polyvinyl chloride Zirconium dioxide Zirconium Chloride Octahydrate Zirconium Oxychloride Octahydrate