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Zirconyl chloride octahydrate

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Products Intro: Product Name: Zirconyl chloride octahydrate
CAS:13520-92-8
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CAS:13520-92-8
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CAS:13520-92-8
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CAS:13520-92-8
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Products Intro: Product Name:Zirconyl chloride octahydrate
CAS:13520-92-8
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Zirconyl chloride octahydrate Basic information
Synthesis
Product Name:Zirconyl chloride octahydrate
Synonyms:zirconyl(di)chloride;ZIRCONYL CHLORIDE TECHNICAL;Zirconyl chloride oc;Zirconyl chloride octahydrate, 98+% 100GR;Zirconyl chloride octahydrate, 98+% 5GR;Zirconyl Chloride, Octahydrate, Reagent, ACS;Zirconium(IV) oxychloride octahydrate puriss. p.a., >=99.5%;Zirconium(IV) oxychloride octahydrate Vetec(TM) reagent grade, 98%
CAS:13520-92-8
MF:Cl2H2O2Zr
MW:196.14
EINECS:603-909-6
Product Categories:13520-92-8
Mol File:13520-92-8.mol
Zirconyl chloride octahydrate Structure
Zirconyl chloride octahydrate Chemical Properties
Melting point 400°C (dec.)
Boiling point 210°C
density 1.91
storage temp. Store at +15°C to +25°C.
solubility H2O: soluble
form Crystalline Powder
Specific Gravity1.91
color White to light yellow
PH1 (50g/l, H2O, 20℃)
OdorOdorless
Water Solubility SOLUBLE
Sensitive Hygroscopic
Merck 14,10184
Exposure limitsACGIH: TWA 5 mg/m3; STEL 10 mg/m3
NIOSH: IDLH 25 mg/m3; TWA 5 mg/m3; STEL 10 mg/m3
Stability:Stable, but may be moisture sensitive. Incompatible with strong oxidizing agents.
CAS DataBase Reference13520-92-8(CAS DataBase Reference)
Safety Information
Hazard Codes C
Risk Statements 34-22-37
Safety Statements 26-36/37/39-45-27
RIDADR UN 3264 8/PG 3
WGK Germany 1
RTECS ZH7250000
TSCA Yes
HS Code 2827 49 90
HazardClass 8
PackingGroup III
ToxicityLD50 orally in Rabbit: 3500 mg/kg
MSDS Information
ProviderLanguage
Zirconyl chloride octahydrate English
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Zirconyl chloride octahydrate Usage And Synthesis
SynthesisZircon is melted with caustic soda, rinsed, desiliconized, and then reacted with sulfuric acid, and then ammonia water is added to obtain zirconium hydroxide precipitate. Finished zirconium oxychloride.
Chemical Propertiessolid
UsesZirconium dichloride oxide is utilized as a precursor to prepare other zirconium compounds. It is employed in acid dyes, pigment toners and antiperspirants. It finds application as a rubber additive and a fiber treatment agent. It is also used in paint drying, refractories, ceramics and glaze.
General DescriptionThis product is used as a potential green catalyst.
Purification MethodsRecrystallise the chloride several times from water [Ferragina et al. J Chem Soc, Dalton Trans 265 1986]. Recrystallisation from 8M HCl gives the octahydrate as white needles on concentrating. It is also formed by hydrolysing ZrCl4 with water. After one recrystallisation from H2O, 99+% grade zirconyl chloride had Ag, Al, As, Cd, Cu, Hf, Mg, Na, Sc and V at 20, 1.8, 0.6, 0.6, 0.4, 8.4, 0.4, 2.4, 80 and 3 ppm, respectively. (See above.) METAL-ORGANIC COMPOUNDS This section contains metal-organic compounds as well as ammonium and metal salts of organic acids. (For Introduction see p 445.)
Tag:Zirconyl chloride octahydrate(13520-92-8) Related Product Information
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