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Allyl chloride

Allyl chloride Suppliers list
Company Name: Henan Tianfu Chemical Co.,Ltd.
Tel: 0371-55170693
Products Intro: Product Name:1-Propene, 3-chloro-
Purity:99% Package:5KG;1KG
Company Name: Hefei TNJ Chemical Industry Co.,Ltd.
Tel: +86-0551-65418679
Products Intro: Product Name:Allyl chloride
Purity:- Package:1ASSAYS;1USD
Company Name: Hubei Jusheng Technology Co.,Ltd.
Tel: 86-18871470254
Products Intro: Product Name:Allyl chloride
Purity:99% Package:5KG;1KG
Company Name: Jinan Finer Chemical Co., Ltd
Tel: +86-531-88989536 +8615508631887
Products Intro: Product Name:Allyl chloride
Purity:99.5% Package:1KG;USD
Company Name: Hebei Guanlang Biotechnology Co., Ltd.
Tel: +8619930503282
Products Intro: Product Name:Allyl chloride
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Allyl chloride manufacturers

  • Allyl Chloride
  • $0.00 / KG
  • 2021-12-01
  • CAS:107-05-1
  • Min. Order: 1KG
  • Purity: 99%
  • Supply Ability: 10 ton
  • Allyl chloride
  • $1.00 / KG
  • 2021-08-25
  • CAS:107-05-1
  • Min. Order: 1KG
  • Purity: 99%
  • Supply Ability: 1000MT
  • Allyl chloride
  • $15.00-10.00 / KG
  • 2021-07-13
  • CAS:107-05-1
  • Min. Order: 1KG
  • Purity: 99%+ HPLC
  • Supply Ability: Monthly supply of 1 ton
Allyl chloride Basic information
Product Name:Allyl chloride
Synonyms:2-propenylchloride;3-chloro-1-propen;3-Chloro-1-propylene;3-Chloroprene;3-chloro-prop-1-ene;3-chloro-propen;3-chloropropene (allyl chloride);3-chloropropene(allylchloride)
Product Categories:API Intermediate;omega-Functional Alkanols, Carboxylic Acids, Amines & Halides;Pharmaceutical Intermediates;omega-Unsaturated Halides;Benzimidazoles
Mol File:107-05-1.mol
Allyl chloride Structure
Allyl chloride Chemical Properties
Melting point -136 °C
Boiling point 44-46 °C(lit.)
density 0.939 g/mL at 25 °C(lit.)
vapor density 2.6 (vs air)
vapor pressure 20.58 psi ( 55 °C)
refractive index n20/D 1.414(lit.)
Fp −20 °F
storage temp. Store at +2°C to +8°C.
solubility alcohol: miscible(lit.)
form Powder/Solid
color White
Specific Gravity0.939
Odorpungent odor
explosive limit3.3-11.2%(V)
Water Solubility 3.6 G/L (20 ºC)
FreezingPoint -134.5℃
Merck 14,289
BRN 635704
Henry's Law Constant2.69 at 25 °C (static headspace-GC, Welke et al., 1998)
Exposure limitsNIOSH REL: TWA 1 ppm (3 mg/m3), STEL 2 ppm (6 mg/m3), IDLH 250 ppm; OSHA PEL: TWA 1 ppm; ACGIH TLV: STEL 2 ppm.
Stability:Stability Stable, but reacts vigorously or violently with a wide variety of materials. Highly flammable. Incompatible with strong oxidizing agents, acids, amines, peroxides, chlorides of iron and aluminium, BF3, aromatic hydrocarbons, Lewis acids, metals, caustics, ammonia, ferric chloride, ethylene imine, ethylenediamine. Heat and light se
CAS DataBase Reference107-05-1(CAS DataBase Reference)
NIST Chemistry Reference1-Propene, 3-chloro-(107-05-1)
IARC3 (Vol. 36, Sup 7, 71, 125) In prep.
EPA Substance Registry SystemAllyl chloride (107-05-1)
Safety Information
Hazard Codes F,Xn,N,T
Risk Statements 45-46-11-20/21/22-36/37/38-48/20-50-68-40-39/23/24/25-23/24/25-48/23/24/25
Safety Statements 53-26-36/37-45-61-46-25-16-7
RIDADR UN 1100 3/PG 1
WGK Germany 2
RTECS UC7350000
Autoignition Temperature390 °C
Hazard Note Flammable
HS Code 2903 29 00
HazardClass 3
PackingGroup I
Hazardous Substances Data107-05-1(Hazardous Substances Data)
ToxicityLD50 orally in rats: 0.7 g/kg (Smyth, Carpenter)
MSDS Information
ACROS English
SigmaAldrich English
ALFA English
Allyl chloride Usage And Synthesis
Chemical Propertiescolourless, light yellow or amber liquid with an unpleasant smell
Chemical PropertiesAllyl chloride is a colorless liquid, insoluble in water but soluble in common organic solvents. Allyl chloride is prepared by the reaction of propylene with chlorine. It is a common alkylating agent relevant to the manufacture of pharmaceuticals and pesticides. It is also a component in some thermo-setting resins. Allyl chloride has been produced commercially since 1945 and is used almost exclusively as a chemical intermediate, principally in the production of epichlorohydrin or as a raw material for epichlorohydrin. It is also used as a chemical intermediate in the preparation of glycerin, glycerol chlorohydrins, glycidyl ethers, allylamines, and allyl ethers of trimethylpropane, sodium allyl sulfonate, a series of allyl amines and quaternary ammonium salts, allyl ethers, and a variety of alcohols, phenols, and polyols. It is also used in pharmaceuticals as a raw material for the production of allyl isothiocyanate (synthetic mustard oil), allyl substituted barbiturates (sedatives), and cyclopropane (anesthetic); in the manufacture of specialty resins for water treatment and to produce babiturate and hypnotic agents such as aprobarbital, butalbital, methohexital sodium, secobarbital, talbutal, and thiamyl sodium.
Chemical PropertiesAllyl chloride is a highly reactive and flammable, colorless, brown or purple liquid, with an unpleasant, pungent odor.
Physical propertiesColorless to light brown to reddish-brown liquid with a pungent, unpleasant, garlic-like odor. An experimentally determined odor threshold concentration of 470 ppbv was reported by Leonardos et al. (1969).
UsesAllyl chloride (3-chloropropene; 1-chloro-2-propene) is a chemical intermediate used in the synthesis of allyl compounds found in varnish, resins, polymers, pesticides, and pharmaceuticals (O’Neil, 2001).
UsesAllyl chloride is used in the synthesis of glycerol, allyl alcohol and epichlorohydrin.
UsesManufacture of epichlorohydrin, epoxy resin, glycerin pesticides, and sodium allyl sulfonate
Production MethodsAllyl chloride can be synthesized by reaction of allyl alcohol with HCl or by treatment of allyl formate with HCl in the presence of a catalyst (ZnCl2).
General DescriptionA clear colorless liquid with an unpleasant pungent odor. Flash point -20°F. Boiling point 113°F. Less dense than water (7.8 lb / gal) and insoluble in water. Hence floats on water. Vapor irritates skin, eyes and mucous membranes. Vapors are heavier than air. Long exposure to low concentrations or short exposure to high concentrations may have adverse health effects from inhalation or skin absorption.
Air & Water ReactionsHighly flammable. Insoluble in water.
Reactivity ProfileAllyl chloride presents a serious fire and explosion hazard when exposed to heat, flame or oxidizing agents. Polymerizes violently and exothermically with Lewis acids (aluminum chloride, boron trifluoride, sulfuric acid) or metals (aluminum, magnesium, zinc, or galvanized metal) [MCA SD-99, 1973]. Incompatible with acids (nitric acid, chlorosulfonic acid, oleum), with strong bases (sodium hydroxide, potassium hydroxide), with ethyleneimine and ethylenediamine [Lewis, 3rd ed., 1993, p. 36]. Attempts to alkylate benzene or toluene using Allyl chloride in the presence of ethylaluminum chlorides have led to explosions.
HazardSkin and eye irritant. Upper respiratory tract irritant, liver and kidney damage. Question- able carcinogen.
Health HazardCauses marked irritation of skin and may burn. Burns the eyes; effect may be delayed.
Health HazardAllyl chloride is toxic and flammable. Exposures to allyl chloride cause a cough, sore throat, headache, dizziness, weakness, respiratory distress, abdominal pain, burning sensation, vomiting, and loss of consciousness. After acute inhalation exposures to high levels of allyl chloride, workers developed irritation of the eyes and respiratory passages, loss of consciousness, and fatal injury. Prolonged and intense exposure produced conjunctivitis, reddening of eyelids, and corneal burn, damage to the CNS, causing motor and sensory neurotoxic damage, and the heart and respiratory system, causing the onset of pulmonary edema in humans. Laboratory rabbits exposed to allyl chloride through inhalation developed degenerative changes that included dilation of sinusoids and vacuolar degeneration in the liver, congestion or cloudy swelling and fatty degeneration of the epithelium of the renal convoluted tubules, and thickening of the alveolar septa in the lungs. The exposed cat exhibited only muscle weakness and unsteady gait toward the end of the exposure period.
Fire HazardSpecial Hazards of Combustion Products: Releases irritating hydrogen chloride gas on combustion
Safety ProfileSuspected carcinogen with experimental tumorigenic data. Poison by intraperitoneal and intravenous routes. Moderately toxic by ingestion, inhalation, and skin contact. Experimental teratogenic and reproductive effects. A skin and eye irritant. Human mutation data reported. Chronic exposure may cause liver and lildney damage. The vapors of allyl chloride are quite irritating to the eyes, nose, and throat. Contact of the liquid with the skin may lead, in addition to local vasoconstriction and numbness, to rapid absorption and distribution through the body. If remedial measures are not taken promptly, such contact may result in burns and internal injuries. Inhalation may cause headache, dizziness, and in htgh concentration, loss of consciousness; however, even in low concentration, its odor in most cases is irritating enough to give warning of its presence. Concentration of the vapors high enough to cause serious effects, includlng damage to the lungs, especially on repeated exposure, may not be intolerable. Consequently, the warning characteristics should never be disregarded. In general, precautions should be taken AT ALL TIMES to avoid splllage and accumulation of noticeable concentration of the vapors in the atmosphere. Acute exposure in experimental animals has resulted in marked inflammation of lungs, irritation of skin, and swelling of the hdneys. Chronically exposed animals have shown degenerative changes in the liver and kidneys. Reported human exposures have been principally cases of irritation of the eyes, skin, and respiratory tract, sometimes accompanied by aches and pains in the bones. Liver and hdney injury is possible. Dangerous fire and explosion hazard when exposed to heat, flame, or oxidlzers. Vigorous or explosive reaction above -7O℃ with alkyl aluminum chlorides (e.g., trichlorotriethyl dialuminum, ethyl aluminum dichloride, or diethyl aluminum chloride) + aromatic hydrocarbons (e.g., benzene or toluene). Violently exothermic polymerization reaction with Lewis acids (e.g., aluminum chloride, boron trifluoride, or sulfuric acid) and metals (e.g., aluminum, magnesium, zinc, or galvanized metals). Incompatible with HNO3, ethylene imine, ethylenedlamine, chlorosulfonic acid, oleum, NaOH. To fight fire, use CO2, alcohol foam, dry chemical. See also CHLORINATED HYDROCARBONS; ALIPHATIC; ALLYL COMPOUNDS; and CHLORIDES. Storage and Handling: Keep cool, away from heat sources. Maintain good vendation. Work in a fume hood or with closed system if possible; otherwise, use adequate vendation so that the odor of allyl chloride does not persist. If it should be necessary to enter an area in which the odor of allyl chloride is at all noticeable, use a gas mask equipped with an “organic vapor” canister. Do not dlsregard the warning odor or eye irritation of allyl chloride
Potential ExposureAllyl chloride is used as a chemical intermediate and in making allyl compounds, epichlorohydrin, and glycerol.
CarcinogenicityThe IARC found that it could not classify AC as a human carcinogen on the basis of available data. In contrast, EPA considers AC to be a possible human carcinogen and has ranked it in EPA’s Group C. This classification was based on a low incidence of forestomach tumors in female mice and positive results in a variety of genetic toxicity tests. However, the forestomach tumor data were not used for quantitative cancer risk assessment. AC is a strong alkylating agent and is structurally similar to other forestomach carcinogens, such as propylene oxide and epichlorohydrin, which cause tumors at the site of exposure.
Olsen reported on a cohort of 1064 men employed at a Texas plant in epoxy resin, glycerin, andAC/epichlorohydrin production between 1957 and 1986 and followed up through 1989. There were 66 total deaths [standardized mortality ratio (SMR)=0.8; 95% CI 0.6–1.0] and 10 cancers (SMR=0.5; CI 0.2–0.9).However, the authors noted that the cohort was limited due to sample size, duration of follow-up, small numbers of deaths both expected and found, and the limited exposure potential.
Environmental fateBiological. Bridié et al. (1979) reported BOD and COD values of 0.23 and 0.86 g/g using filtered effluent from a biological sanitary waste treatment plant. These values were determined using a standard dilution method at 20 °C and stirred for a period of 5 d. When a sewage seed was used in a separate screening test, a BOD value of 0.42 g/g was obtained. The ThOD for allyl chloride is 1.67 g/g.
Photolytic. Anticipated products from the reaction of allyl chloride with ozone or OH radicals in the atmosphere are formaldehyde, formic acid, chloroacetaldehyde, chloroacetic acid, and chlorinated hydroxy carbonyls (Cupitt, 1980).
Chemical/Physical. Hydrolysis under alkaline conditions will yield allyl alcohol (Hawley, 1981). The estimated hydrolysis half-life in water at 25 °C and pH 7 is 2.0 yr (Mabey and Mill, 1978).
ShippingUN1100 Allyl chloride, Hazard Class: 3; Labels: 3-Flammable liquid, 6.1-Poisonous materials
Purification MethodsLikely impurities include 2-chloropropene, propyl chloride, iso-propyl chloride, 3,3-dichloropropane, 1,2-dichloropropane and 1,3-dichloropropane. Purify it by washing with conc HCl, then with Na2CO3 solution, dry it with CaCl2, and distil it through an efficient column [Oae & Vanderwerf J Am Chem Soc 75 2724 1953]. [Beilstein 1 IV 738.] LACHRYMATORY, TOXIC.
IncompatibilitiesContact with water forms hydrochloric acid. Keep away from strong oxidizers, acids, aluminum, amines, peroxides, chlorides of iron and aluminum; magnesium, zinc.
Waste DisposalConsult with environmental regulatory agencies for guidance on acceptable disposal practices. Generators of waste containing this contaminant (≥100 kg/mo) must conform with EPA regulations governing storage, transportation, treatment, and waste disposal. Controlled incineration at a temperature of 982 C for 2 seconds minimum.
Tag:Allyl chloride(107-05-1) Related Product Information
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