| 1,5-Dinitronaphthalene Basic information |
Product Name: | 1,5-Dinitronaphthalene | Synonyms: | 1,5-dinitro-naphthalen;Naphthalene,1,5-dinitro-;1,5-DINITRONAPHTHALENE;LABOTEST-BB LT00436936;1,5-Dinitroaphthalene;1,5-Dinitronaphthalene98%;1,5-Dinitronaphthalene,tech.90%;1,5-DINITRO NAPHTALENE | CAS: | 605-71-0 | MF: | C10H6N2O4 | MW: | 218.17 | EINECS: | 210-095-2 | Product Categories: | Building Blocks;Chemical Synthesis;Nitro Compounds;Nitrogen Compounds;Organic Building Blocks;Nitro Compounds;Nitrogen Compounds;Organic Building Blocks;Intermediates of Dyes and Pigments;Naphthalene derivatives | Mol File: | 605-71-0.mol | |
| 1,5-Dinitronaphthalene Chemical Properties |
| 1,5-Dinitronaphthalene Usage And Synthesis |
Chemical Properties | Yellow to yellow-green needles or fluffy powder | Uses | 1,5-Dinitronaphthalene is an intermediate in the production of naphthazarin (5,8- dihydroxy-1,4-naphthoquinone) and 1,5- naphthalenediamine, which is mainly converted to naphthalene 1,5-diisocyanate. As a sensitizing agent for ammonium nitrate explosives the use of mixed isomers is adequate. | Definition | ChEBI: 1,5-dinitronaphthalene is a dinitronaphthalene carrying nitro groups at positions 1 and 5. It has a role as a genotoxin. | Production Methods | Naphthalene is added slowly to mixed acid (22/58/20) at 40 ℃, and the temperature is raised to 80 ℃ over 4 h to give a mixture of 1,5- and 1,8-dinitronaphthalenes. The isomers are separated by fractional crystallization (e.g., from ethylene dichloride) or, preferably, by solvent extraction. The 1,5-isomer can be extracted with toluene, leaving 99 % pure 1,8- dinitronaphthalene. After evaporation of the toluene, the residue is extracted with a strongly polar solvent (e.g., sulfolane) to leave 99 % pure 1,5-isomer. | General Description | Yellowish white needles or light yellow fluffy solid. | Air & Water Reactions | Insoluble in water. | Reactivity Profile | 1,5-Dinitronaphthalene is incompatible with strong oxidizers and strong bases. Mixtures with sulfur or sulfuric acid may explode if heated to 248° F . | Fire Hazard | Flash point data for 1,5-Dinitronaphthalene are not available; however, 1,5-Dinitronaphthalene is probably combustible. | Safety Profile | A suspected
carcinogen. Mutation data reported.
Mxtures with sulfur or sulfuric acid (used in
commercial reactions) may explode if heated
to 120℃. Initiation temperature depends on
the quality of the dinitronaphthalene. When
heated to decomposition it emits toxic
fumes of NOx. See also NITRO COMPOUNDS of AROMATICHYDROCARBONS |
| 1,5-Dinitronaphthalene Preparation Products And Raw materials |
Preparation Products | Decahydro-1,5-naphthalenediamine-->5-nitronaphthalen-1-amine-->5,8-Dihydroxy-1,4-naphthoquinone-->4-Nitro-1-naphthylamine-->C.I. Sulphur Brown 63-->Copper, cresol-1,5-dinitronaphthalene-sodium polysulfide reaction products complexes, leuco derivs.-->Disperse Blue 20-->5,8-Dihydroxy-1,4-naphthoquinone-->Copper, cresol-1,5-dinitronaphthalene-sodium polysulfide reaction products complexes |
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