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Bismuth(III) trifluoromethanesulfonate

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CAS:88189-03-1
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CAS:88189-03-1
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Bismuth(III) trifluoromethanesulfonate Basic information
Uses
Product Name:Bismuth(III) trifluoromethanesulfonate
Synonyms:BISMUTH(III) TRIFLUOROMETHANESULFONATE;BISMUTH TRIFLUOROMETHANESULFONATE HYDRATE;BISMUTH TRIFLUOROMETHANESULFONATE, ANHY&;Trifluoromethanesulfonicacidbismuthsalt;Bismuth(III)trifluoromethanesulfonate,min.98%(Bismuthtriflate);BISMUTH(III) TRIFLUOROMETHANESULFONATE BISMUTH TRIFLATE;Bismuth(III) trifluoromethanesulfonate,98%;BisMuth(Ⅲ) trifluoroMethanesulfonate
CAS:88189-03-1
MF:3CF3O3S.Bi
MW:656.18
EINECS:
Product Categories:metal triflate compound;triflate;Bismuth;Catalysis and Inorganic Chemistry;Chemical Synthesis
Mol File:88189-03-1.mol
Bismuth(III) trifluoromethanesulfonate Structure
Bismuth(III) trifluoromethanesulfonate Chemical Properties
Melting point 300 °C
storage temp. Inert atmosphere,Room Temperature
solubility Soluble in organics acetonitrile, dioxane, dimethyl formamide and dimethyl sulfoxide.
form Liquid
color Clear colorless
Sensitive Hygroscopic
Hydrolytic Sensitivity5: forms reversible hydrate
Stability:hygroscopic
InChIKeyHIYUMYXSGIKHHE-UHFFFAOYSA-M
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-24/25
WGK Germany 3
Hazard Note Irritant
TSCA No
HazardClass 8
HS Code 29049090
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
ALFA English
Bismuth(III) trifluoromethanesulfonate Usage And Synthesis
UsesBismuth(III) trifluoromethanesulfonate is powerful Lewis acid useful in a number of catalytic reactions. 
Chemical PropertiesWhite powder
UsesCatalyzes direct substitution of allylic, propargylic, and benzylic alcohols with sulfonamides, carbamates, and carboxamides.
UsesBismuth(III) trifluoromethanesulfonate acts as a catalyst in Friedel-Crafts acylation and cycloisomerization of allene-enol ethers. It behaves as a direct substitution catalyst and involved in the substitution of allylic, propargylic, and benzylic alcohols with sulfonamides, carboxamides and carbamates. Further, it is also used in Mukaiyama aldol reactions.
UsesCatalyst for organic syntheses.
Bismuth(III) trifluoromethanesulfonate Preparation Products And Raw materials
Tag:Bismuth(III) trifluoromethanesulfonate(88189-03-1) Related Product Information
BISMUTH 2-ETHYLHEXANOATE Bismuth Bis(tributyltin) oxide Sodium trifluoromethanesulfinate YTTERBIUM(III) TRIFLATE HYDRATE, 99.90% BISMUTH TITANATE Triphenylbismuth Bismuth nitrate pentahydrate Bismuth trioxide BISMUTH SULFIDE BISMUTH NEODECANOATE Bismuth trichloride BISMUTH(III) FLUORIDE BISMUTH ACETATE BISMUTH(III) IODIDE BISMUTH TRIS(2,2,6,6-TETRAMETHYL-3,5-HEPTANEDIONATE) BISMUTH TELLURIDE BISMUTH(III) BROMIDE