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Ethanesulfonic acid

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CAS:594-45-6
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Ethanesulfonic acid manufacturers

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  • 2024-01-22
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Ethanesulfonic acid Basic information
Description Uses structure and hydrogen bonding Preparation
Product Name:Ethanesulfonic acid
Synonyms:ETHYLSULFONATE, POLYMER-BOUND;ETHYLSULFONIC ACID;ETHANESULFONIC ACID;ETHANSULFONIC ACID;Ethanesulfonicacid,90%;ETHANESULFONIC ACID, 70 WT. % SOLUTION I N WATER;ETHANESULFONIC ACID 95%;ethanesulfonate
CAS:594-45-6
MF:C2H6O3S
MW:110.13
EINECS:209-843-0
Product Categories:Organic Building Blocks;Sulfonic/Sulfinic Acids;Sulfur Compounds;Others;Supported Reagents;Supported Synthesis;Pharmaceutical Intermediates
Mol File:594-45-6.mol
Ethanesulfonic acid Structure
Ethanesulfonic acid Chemical Properties
Melting point -17 °C (lit.)
Boiling point 123 °C/0.01 mmHg (lit.)
density 1.35 g/mL at 25 °C (lit.)
refractive index n20/D 1.434(lit.)
Fp >230 °F
storage temp. Store below +30°C.
solubility water: soluble
form Liquid
pka1.83±0.50(Predicted)
Specific Gravity1.357
color Colorless to yellow
Water Solubility soluble
BRN 1743071
InChIKeyCCIVGXIOQKPBKL-UHFFFAOYSA-N
LogP-1.577 (est)
CAS DataBase Reference594-45-6(CAS DataBase Reference)
EPA Substance Registry SystemEthanesulfonic acid (594-45-6)
Safety Information
Hazard Codes C
Risk Statements 34-35
Safety Statements 26-36/37/39-45
RIDADR UN 2586 8/PG 3
WGK Germany 3
TSCA Yes
HazardClass 8
PackingGroup II
HS Code 29041000
MSDS Information
ProviderLanguage
Ethanesulfonic acid English
SigmaAldrich English
ACROS English
ALFA English
Ethanesulfonic acid Usage And Synthesis
DescriptionEthanesulfonic acid (esylic acid) is a sulfonic acid with the chemical formula CH3CH2SO3H. The conjugate base is known as ethanesulfonate or, when used in pharmaceutical formulations, as esilate. It is a colorless liquid.
Ethanesulfonic acid
UsesEthanesulfonic acid is an alkanesulfonic acid in which the alkyl group directly linked to the sulfo functionality is ethyl, and it is a conjugate acid of an ethanesulfonate. employed in the electrolytic reduction of perrhenate solutions. Ethanesulfonic acid is used as pharmaceutical intermediates, catalyst of polymerization and alkylation. It participates in the electrolytic reduction of perrhenate solutions.

structure and hydrogen bondingThis compound belongs to the class of organic compounds known as organosulfonic acids. These are compounds containing the sulfonic acid group, which has the general structure RS(=O)2OH (R is not a hydrogen atom).
Preparation(1) To a glass reactor equipped with a reflux condenser, sample inlet, internal cooler, stirring device and solvent was distilled off with an opening and closing cock was charged with 60weight % of hydrogen peroxide solution 295 g (5.20 mol) prepared and 154 g (1.00 mol) of bis(2-hydroxyethyl)disulfide was uniformly added from the sample inlet over 150 minutes and the liquid was stirred. During this time, the temperature of reaction liquid was held at 45 °C by flowing 19 °C cooling water at the flow rate of 140mL/minutes into the condenser. After completion of the addition, the reaction solution temperature was maintained at 50 °C for 2 hours and heated under reflux for 4 hours.

594-45-6 synthesis

During heating under reflux, the nitrogen gas was blown and the portion of steam was evaporated from the reaction system. 55 weight% aqueous solution of isethionic acid was obtained as a product. Purity of the generated isethionic acid was 244g (1.94 mol) and the yield was 97%. (2) Similarly, there is another synthesis route as shown in scheme 3. The product was obtained in the same manner as above route (1), instead of bis(2-hydroxyethyl)disulfide 154 g (1.00 mol), diethyl disulfide 122 g(1.00 mol) was added, the temperature was maintained at 45 °C by flowing 19 °C cooling water at the flow rate of 140mL/minute into the condenser and the temperature was maintained at 75 °C for 2 hours. 52 weight% aqueous solution of ethanesulfonic acid was obtained as a product. The purity of the generated ethanesulfonic acid was 213 g (1.94 mol) and the yield was 97%.

Chemical Propertiesclear yellow to brown liquid
UsesEthanesulfonic acid is employed in the electrolytic reduction of perrhenate solutions. It is also used as a catalyst for alkylation, polymerization and other reactions. Further, it reacts with triethoxymethane to prepare ethanesulfonic acid ethyl ester.
DefinitionChEBI: An alkanesulfonic acid in which the alkyl group directly linked to the sulfo functionality is ethyl.
General DescriptionEthanesulfonic acid participates in electrolytic reduction of perrhenate solutions.
Ethanesulfonic acid Preparation Products And Raw materials
Preparation ProductsMethyl ethanesulfonate
Tag:Ethanesulfonic acid(594-45-6) Related Product Information
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