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Postion:Product Catalog >Organic Chemistry>Organometallic compounds>Organic iron>1,1'-Bis(diphenylphosphino)ferrocene
1,1'-Bis(diphenylphosphino)ferrocene
  • 1,1'-Bis(diphenylphosphino)ferrocene
  • 1,1'-Bis(diphenylphosphino)ferrocene

1,1'-Bis(diphenylphosphino)ferrocene

Price $1
Package 1KG
Min. Order: 1KG
Supply Ability: 1000KG
Update Time: 2019-07-06

Product Details

Product Name: 1,1'-Bis(diphenylphosphino)ferrocene CAS No.: 12150-46-8
EC-No.: 430-420-3 Min. Order: 1KG
Purity: 99% Supply Ability: 1000KG
Release date: 2019/07/06

AD68

1,1'-Bis(diphenylphosphino)ferrocene Basic information
Reaction
Product Name: 1,1'-Bis(diphenylphosphino)ferrocene
Synonyms: DPPF;1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE;1,1'-FERROCENEDIYL-BIS(DIPHENYLPHOSPHINE);1,1'-FERROCENEBIS(DIPHENYLPHOSPHINE);1,1'-bis(diphenyphosphino)ferrocene;1,1'-bis(diphenyphosphino)ferrocene(dppf);1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE, 97 %;1,1'-Bis(diphenylphosphino)ferrocene,99%DPPF
CAS: 12150-46-8
MF: C34H28FeP2 10*
MW: 554.38
EINECS: 430-420-3
Product Categories: Phosphines;Boron, Nitrile, Thio,& TM-Cpds;Miscellaneous;pharmacetical;Ligand;Catalysts-Ligands;Classes of Metal Compounds;Fe (Iron) Compounds;Ferrocenes;Metallocenes;Phosphine Ligands;Synthetic Organic Chemistry;Transition Metal Compounds;Aromatics;Catalyst;Chelating Agents & Ligands;Pharmaceutical intermediates;Achiral Phosphine;Aryl Phosphine
Mol File: 12150-46-8.mol
Article illustration
 
1,1'-Bis(diphenylphosphino)ferrocene Chemical Properties
Melting point  181-182 °C (dec.)(lit.)
storage temp.  2-8°C
form  crystal
color  yellow to orange
Water Solubility  Soluble in chloroform, dichloromethane, alcohol and pentane. Insoluble in water.
Sensitive  Air Sensitive
Stability: Stable. Incompatible with strong oxidizing agents.
CAS DataBase Reference 12150-46-8(CAS DataBase Reference)
NIST Chemistry Reference 1,1'-Bis(diphenylphosphino)ferrocene(12150-46-8)
 
Safety Information
Hazard Codes  T,Xi,Xn
Risk Statements  25-36/37/38-20/21/22
Safety Statements  22-24/25-45-28A-36-26-36/37/39
RIDADR  3467
WGK Germany  3
10-23
TSCA  No
HazardClass  IRRITANT
HS Code  29319090
 
 
1,1'-Bis(diphenylphosphino)ferrocene Usage And Synthesis
Reaction
  1. Ligand for Pd-catalyzed cross-coupling.
  2. Useful ligand for Pd-catalyzed carbon-nitrogen and carbon-oxygen bond forming procedures.
  3. Ligand for Ni-catalyzed amination of aryl chlorides.
  4. Ligand for Pd-catalyzed conversion of aryl halides to aryl nitriles.
  5. Ligand for Ni-catalyzed Suzuki reactions.
  6. Ni-catalyzed hydroamination of 1,3-dienes.
  7. Pd-catalyzed hydrocarbonation and hydroamination of 3,3-dihexylcyclopropene.
  8. Pd-catalyzed γ-arylation of β,γ-unsaturated ketones.
  9. Ligand for Ru-catalyzed reduction of nitriles to primary amines.
  10. Ligand for Rh-catalyzed alkyne head-to-tail dimerization.
  11. Ligand for Rh-catalyzed cross-coupling
  12. Ligand for Rh-catalyzed olefin isomerization
  13. Ligand for Ni or Rh-catalyzed borylation
  14. Ligand for regioselective Pd-catalyzed hydrophosphinylation of terminal alkynes to form branched alkenes.
Article illustration
Article illustration
Article illustration
Chemical Properties deep yellow crystalline powder
Uses suzuki reaction
Uses Commonly used coordination compound in synthesis, readily forms complexes with various metals, i.e. when reacting with the acetonitrile or benzonitrile complexes of PdCl2 it forms (dppf)PdCl2, which i s a popular reagent for palladium-catalyzed coupling reactions.

Company Profile Introduction

Established in 2014,Career Henan Chemical Co. is a manufacturerspecializing in the sale of fine chemicals. Mainly deals in the sales of: Pharmaceutical intermediates OLED intermediates: Pharmaceutical intermediates; OLED intermediates;

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