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Postion:Product Catalog >Organic Chemistry>Hydrocarbons and derivatives>Aromatic hydrocarbons>4-Phenylphenol
4-Phenylphenol
  • 4-Phenylphenol

4-Phenylphenol

Price $1
Package 1kg
Min. Order: 1kg
Supply Ability: 100KG
Update Time: 2019-07-06

Product Details

Product Name: 4-Phenylphenol CAS No.: 92-69-3
Min. Order: 1kg Purity: 99%
Supply Ability: 100KG Release date: 2019/07/06
Number:: AD68
 
4-Phenylphenol Basic information
Chemical properties Uses Uses Preparative Methods
Product Name: 4-Phenylphenol
Synonyms: (1,1’-Biphenyl)-4-ol;[1,1’-biphenyl]-4-ol;[1,1'-Biphenyl]-4-ol;1-Hydroxy-4-phenylbenzene;4-Diphenylol;4-Hydroxy-1,1'-biphenyl;4-hydroxy-bipheny;l,l-biphenyl,hydroxyderivs
CAS: 92-69-3
MF: C12H10O
MW: 170.21
EINECS: 202-179-2
Product Categories: Industrial/Fine Chemicals;Organics;Phenoles and thiophenoles;Color Former & Related Compounds;Developer;Functional Materials;Bioactive Small Molecules;Building Blocks;C9 to C20+;Cell Biology;Chemical Synthesis;Organic Building Blocks;Oxygen Compounds;P;Phenols
Mol File: 92-69-3.mol
Article illustration
 
4-Phenylphenol Chemical Properties
Melting point  164-166 °C(lit.)
Boiling point  321 °C(lit.)
density  1.0149 (rough estimate)
refractive index  1.6188 (estimate)
Fp  330 °F
storage temp.  0-6°C
solubility  methanol: soluble50mg/mL, clear, colorless
form  Flakes
pka 9.55(at 25℃)
color  White to slightly yellow
PH 7 (0.7g/l, H2O, 20℃)
Water Solubility  0.7 g/L (20 ºC)
Merck  14,7305
BRN  1907452
Stability: Stable. Incompatible with strong oxidizing agents, strong bases, halogens. Combustible.
CAS DataBase Reference 92-69-3(CAS DataBase Reference)
NIST Chemistry Reference p-Hydroxybiphenyl(92-69-3)
 
Safety Information
Hazard Codes  Xi,N
Risk Statements  36/37/38-51/53-38
Safety Statements  26-36/37-61-36
RIDADR  UN3077
WGK Germany  2
RTECS  DV5850000
TSCA  Yes
HazardClass  9
PackingGroup  III
HS Code  29071900
Hazardous Substances Data 92-69-3(Hazardous Substances Data)
MSDS Information
Provider Language
4-Hydroxybiphenyl English
ACROS English
SigmaAldrich English
ALFA English
 
4-Phenylphenol Usage And Synthesis
Chemical properties P-phenyl phenol appears as a white flake solid; being tasteless; mp:159 ~ 160 ℃; pure product has a mp of 166 ℃, a bp of 323 ℃, a relative density of 1.24. It is almost insoluble in water, but easily soluble in organic solvents such as alcohol, ketone and ether and alkaline solution.
Uses Biphenol, also known as p-phenyl phenol, is the intermediates of the fungicide bitertanol.It is used in the synthesis of oil-soluble resin and emulsifier; used as a component of corrosion-resistant paint, printing and dyeing carrier.
Uses It can be used as an intermediate for dyes, resins and rubbers. The red light sensitization and green sensitizing dye manufactured by this product is one of the main raw materials of color film; it can also be used as analytical reagents.
Preparative Methods
  • Separation of the byproducts of phenol produced by sulfonation method
The byproduct during phenol production by sulfonation is subject to distillation with the residue containing p-phenyl phenol and o-phenyl phenol. The residue is heated by the vacuum distillation with the vacuum degree being controlled at 53.3 to 66.7 kPa. The temperature is gradually increased from 65 to 75 DEG C to over 100 DEG C, but not higher than 135 ° C. Then apply separation based on the different solubility of p-phenyl o-phenol in trichlorethylene, that is, the mixed phenyl phenol was heated to be dissolved in trichlorethylene; then after cooling, it undergoes precipitation to generate p-phenyl phenol with filtering and drying to get the final product.
  • Biphenyl sulfonated alkali melting method
The biphenyl dissolved in acetic acid, subjecting to sulfur trioxide sulfonation; after the separation of the sulfonation products, it is reacted with the 20% NaOH aqueous solution to form salt, followed by alkali melting with solid NaOH at 100 ~ 350 ℃, then further being acidified to obtain the product.
Chemical Properties light tan solid (odour threshold detection limit 0.7 ppm)
Definition ChEBI: A member of the class of hydroxybiphenyls that is biphenyl carrying a hydroxy group at position 4.
Uses As intermediate in the manufacture of resins; also in the rubber industry.
Purification Methods Crystallise the phenol from aqueous EtOH, *C6H6, and dry it in a vacuum over CaCl2 [Buchanan et al. J Am Chem Soc 108 7703 1986]. [Beilstein 6 IV 4600.]

Company Profile Introduction

Established in 2014,Career Henan Chemical Co. is a manufacturerspecializing in the sale of fine chemicals. Mainly deals in the sales of: Pharmaceutical intermediates OLED intermediates: Pharmaceutical intermediates; OLED intermediates;

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