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Acetylenedicarboxylic acid(142-45-0)

Acetylenedicarboxylic acid(142-45-0)
Product IdentificationBack to Contents
【Product Name】

Acetylenedicarboxylic acid
【Synonyms】

2-Butyne-1,4-dioic acid
2-Butynedioic acid
Acetylenedicarboxylic acid
But-2-ynedioic acid
【CAS】

142-45-0
【Formula】

C4H2O4
【Molecular Weight】

114.06
【EINECS】

205-536-0
【Beilstein/Gmelin】

878357
【Beilstein Reference】

4-02-00-02290
Physical and Chemical PropertiesBack to Contents
【Appearance】

Light beige solid.
【Solubility in water】

Very soluble
【Melting Point】

180 - 185
【Boiling Point】

292
【pKa/pKb】

0.67 (pKa)
【Partition Coefficient】

-.26
First Aid MeasuresBack to Contents
【Ingestion】

Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
【Inhalation】

Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
【Skin】

Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.
【Eyes】

Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Handling and StorageBack to Contents
【Storage】

Store in a cool, dry place. Store in a tightly closed container. Refrigerator (approx 4 C).
【Handling】

Wash thoroughly after handling. Wash hands before eating. Use only in a well ventilated area. Minimize dust generation and accumulation. Do not get on skin or in eyes. Do not ingest or inhale.
Hazards IdentificationBack to Contents
【Ingestion】

Causes gastrointestinal irritation with nausea, vomiting and diarrhea.
【Inhalation】

May cause severe irritation of the respiratory tract with sore throat, coughing, shortness of breath and delayed lung edema.
【Skin】

May cause severe irritation and possible burns.
【Eyes】

Contact with eyes may cause severe irritation, and possible eye burns.
【Hazards】

Contact with metals may evolve flammable hydrogen gas.
【EC Risk Phrase】

R 23/24/25 36/38
【EC Safety Phrase】

S 26 36/37/39 45
【UN (DOT)】

3261
Exposure Controls/Personal ProtectionBack to Contents
【Personal Protection】

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves and clothing to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
【Respirators】

Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
Fire Fighting MeasuresBack to Contents
【Flash Point】

131
【Fire Fighting】

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. To extinguish fire, use water, dry chemical, chemical foam, or alcohol-resistant foam.
【Fire Potential】

Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes.
Accidental Release MeasuresBack to Contents
【Small spills/leaks】

Clean up spills immediately, using the appropriate protective equipment. Sweep up, then place into a suitable container for disposal.
Stability and ReactivityBack to Contents
【Disposal Code】

4
【Incompatibilities】

Bases; reducing agents; and oxidizing agents.
【Stability】

Stable under normal temperatures and pressures.
【Decomposition】

Carbon monoxide, carbon dioxide.
【Combustion Products】

Fire may produce irritating, corrosive and/or toxic gases.
Transport InformationBack to Contents
【UN Number】

3261
【Hazard Class】

8
【Packing Group】

I; II; III
【HS Code】

2917 19 90
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