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3-Hydroxypropionitrile(109-78-4)

3-Hydroxypropionitrile(109-78-4)
Product IdentificationBack to Contents
【Product Name】

3-Hydroxypropionitrile
【Synonyms】

Ethylene cyanohydrin
Hydracrylonitrile
【CAS】

109-78-4
【Formula】

C3H5NO
【Molecular Weight】

71.08
【EINECS】

203-704-8
【RTECS】

MU5250000
【RTECS Class】

Primary Irritant
【Merck】

13,3828
【Beilstein/Gmelin】

635773
【Beilstein Reference】

4-03-00-00708
Physical and Chemical PropertiesBack to Contents
【Appearance】

Clear, colorless to very slightly yellow liquid with a weak odor.
【Solubility in water】

Miscible
【Melting Point】

-46
【Boiling Point】

228
【Vapor Pressure】

0.08 (25 C)
【Density】

1.0588 g/cm3 (0 C)
【Partition Coefficient】

-.94
【Usage】

Solvent for certain cellulose esters and inorganic salts, organic intermediate for acrylates.
【Vapor Density】

2.45
【Refractive Index】

1.4272 (20 C)
First Aid MeasuresBack to Contents
【Ingestion】

Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
【Inhalation】

Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
【Skin】

Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists. Wash clothing before reuse.
【Eyes】

Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Handling and StorageBack to Contents
【Storage】

Store in a cool, dry place. Keep away from water. Keep containers tightly closed.
【Handling】

Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Keep from contact with moist air and steam.
Hazards IdentificationBack to Contents
【Inhalation】

May cause respiratory tract irritation.
【Skin】

May cause skin irritation.
【Eyes】

May cause eye irritation.
【Ingestion】

May cause gastrointestinal irritation with nausea, vomiting and diarrhea. May cause kidney damage.
【Hazards】

Closed containers may rupture violently when heated. Water Reactive. Material will react with water and may release a flammable and/or toxic gas.
【EC Risk Phrase】

R 36/37/38
【EC Safety Phrase】

S 26 36
Exposure Controls/Personal ProtectionBack to Contents
【Personal Protection】

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to minimize contact with skin.
【Respirators】

Wear a NIOSH/MSHA or European Standard EN 149 approved full-facepiece airline respirator in the positive pressure mode with emergency escape provisions. Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
【Exposure Effects】

Repeated exposure may cause kidney damage and digestive tract abnormalities.
【Poison Class】

4
Fire Fighting MeasuresBack to Contents
【Flash Point】

128
【Autoignition】

494
【Fire Fighting】

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water spray to keep fire-exposed containers cool. Containers may explode in the heat of a fire. Extinguishing media: Water or foam may cause frothing. Do NOT get water inside containers. For large fires, use water spray, fog or alcohol-resistant foam. Cool containers with flooding quantities of water until well after fire is out. For small fires, use dry chemical or carbon dioxide.
【Upper exp. limit】

12.1
【Lower exp. limit】

2.3
【Fire Potential】

Flammable, combustion requires preheating quite flammable.
Accidental Release MeasuresBack to Contents
【Small spills/leaks】

Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Clean up spills immediately, using the appropriate protective equipment. Remove all sources of ignition. Use a spark-proof tool. Provide ventilation. Do not get water on spilled substances or inside containers.
Stability and ReactivityBack to Contents
【Disposal Code】

6
【Incompatibilities】

Acids, bases, strong oxidizing agents, moisture.
【Stability】

Stable under normal temperatures and pressures.
【Decomposition】

Hydrogen cyanide, nitrogen oxides, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, nitrogen.
【Combustion Products】

Toxic gases are generated when heated.
Transport InformationBack to Contents
【HS Code】

2926 90 95
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