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Chlorotris(triphenylphosphine)rhodium(I)(14694-95-2)

Chlorotris(triphenylphosphine)rhodium(I)(14694-95-2)
Product IdentificationBack to Contents
【Product Name】

Chlorotris(triphenylphosphine)rhodium(I)
【Synonyms】

Chlorotris(triphenylphosphine)rhodium
【CAS】

14694-95-2
【Formula】

C54H45ClP3Rh
【Molecular Weight】

925.24
【EINECS】

238-744-5
【Merck】

12,2226
【Beilstein/Gmelin】

4581440
【EC Class】

irritant
Physical and Chemical PropertiesBack to Contents
【Appearance】

Dark rust crystalline powder.
【Solubility in water】

Insoluble
【Melting Point】

157
【Density】

1.363 g/cm3 (20 C)
【Usage】

Homogeneous hydrogenation catalyst.
【Vapor Density】

31.9
First Aid MeasuresBack to Contents
【Ingestion】

Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
【Inhalation】

Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. DO NOT use mouth-to-mouth respiration.
【Skin】

Get medical aid. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Destroy contaminated shoes.
【Eyes】

Get medical aid immediately. Do NOT allow victim to rub or keep eyes closed. Extensive irrigation is required (at least 30 minutes).
Handling and StorageBack to Contents
【Storage】

Keep container closed when not in use. Store in a cool, dry, well-ventilated area away from incompatible substances. Corrosives area. Keep containers tightly closed.
【Handling】

Wash thoroughly after handling. Wash hands before eating. Use only in a well ventilated area. Avoid contact with skin and eyes. Keep container tightly closed. Avoid ingestion and inhalation. Wash clothing before reuse. Discard contaminated shoes.
Hazards IdentificationBack to Contents
【Ingestion】

May cause severe and permanent damage to the digestive tract. Causes gastrointestinal tract burns.
【Inhalation】

May cause severe irritation of the respiratory tract with sore throat, coughing, shortness of breath and delayed lung edema. Causes chemical burns to the respiratory tract.
【Skin】

Causes skin burns.
【Eyes】

Causes eye burns.
【Hazards】

Contact with metals may evolve flammable hydrogen gas.
【EC Risk Phrase】

R 36/38
【EC Safety Phrase】

S 22 26 36
【UN (DOT)】

1759
Exposure Controls/Personal ProtectionBack to Contents
【Personal Protection】

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to minimize contact with skin.
【Respirators】

A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use.
Fire Fighting MeasuresBack to Contents
【Fire Fighting】

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. To extinguish fire use water spray, dry chemical, carbon dioxide, or appropriate foam.
【Fire Potential】

Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes.
Accidental Release MeasuresBack to Contents
【Small spills/leaks】

Clean up spills immediately, using the appropriate protective equipment. Sweep up, then place into a suitable container for disposal. Avoid generating dusty conditions. Provide ventilation.
Stability and ReactivityBack to Contents
【Disposal Code】

27
【Stability】

Stable at room temperature in closed containers under normal storage and handling conditions.
【Incompatibilities】

Strong oxidizing agents.
【Decomposition】

Hydrogen chloride, carbon monoxide, oxides of phosphorus, carbon dioxide.
【Combustion Products】

Fire may produce irritating, corrosive and/or toxic gases.
Transport InformationBack to Contents
【UN Number】

1759
【Hazard Class】

8
【Packing Group】

I; II; III
【HS Code】

2843 90 90
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