ChemicalBook >>Hexachloroacetone>>Hexachloropropan-2-one(116-16-5)

Hexachloropropan-2-one(116-16-5)

Hexachloropropan-2-one(116-16-5)
Product IdentificationBack to Contents
【Product Name】

Hexachloropropan-2-one
【Synonyms】

Hexachloropropanone
【CAS】

116-16-5
【Formula】

C3Cl6O
【Molecular Weight】

264.75
【EINECS】

204-129-5
【RTECS】

UC2100000
【RTECS Class】

Agricultural Chemical and Pesticide; Mutagen
【Beilstein/Gmelin】

1707475
【Beilstein Reference】

4-01-00-03223
【EC Index Number】

606-032-00-7
【EC Class】

Harmful; Dangerous for the Environment
Physical and Chemical PropertiesBack to Contents
【Appearance】

A yellow-colored liquid.
【Solubility in water】

Slightly soluble
【Melting Point】

-3
【Boiling Point】

204
【Vapor Pressure】

.4
【Density】

1.744 g/cm3 (12 C)
【Partition Coefficient】

3.49
【Usage】

Reagent for n-trichloroacetylation of dipeptides under neutral conditions, herbicide.
【Vapor Density】

9.2
【Refractive Index】

1.5115 (20 C)
First Aid MeasuresBack to Contents
【Ingestion】

Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
【Inhalation】

Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. DO NOT use mouth-to-mouth respiration.
【Skin】

Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
【Eyes】

Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Handling and StorageBack to Contents
【Storage】

Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
【Handling】

Wash thoroughly after handling. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid contact with heat, sparks and flame. Avoid ingestion and inhalation.
Hazards IdentificationBack to Contents
【Ingestion】

Harmful if swallowed. May cause irritation of the digestive tract.
【Inhalation】

May cause respiratory tract irritation. Harmful if inhaled.
【Skin】

May cause skin irritation.
【Eyes】

May cause eye irritation.
【Hazards】

When heated, vapors may form explosive mixtures with air: indoors, outdoors, and sewers explosion hazards. May polymerize explosively when heated or involved in a fire. Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated. Runoff may pollute waterways. Substance may be transported in a molten form.
【EC Risk Phrase】

R 22 51/53
【EC Safety Phrase】

S 24/25 61
【UN (DOT)】

2661
Exposure Controls/Personal ProtectionBack to Contents
【Personal Protection】

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
【Respirators】

Wear a NIOSH/MSHA or European Standard EN 149 approved full-facepiece airline respirator in the positive pressure mode with emergency escape provisions.
【Exposure limit(s)】

OEL-RUSSIA:STEL 0.5 mg/m3
【Poison Class】

4
Fire Fighting MeasuresBack to Contents
【Flash Point】

>110 (99% purity)
【Fire Fighting】

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Containers may explode when heated. Extinguishing media: Use agent most appropriate to extinguish fire. Cool containers with flooding quantities of water until well after fire is out. In case of fire use water spray, dry chemical, carbon dioxide, or appropriate foam.
【Fire Potential】

May burn but does not ignite readily.
Accidental Release MeasuresBack to Contents
【Small spills/leaks】

Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, using the appropriate protective equipment. Remove all sources of ignition. Provide ventilation.
Stability and ReactivityBack to Contents
【Disposal Code】

2
【Incompatibilities】

Oxidizing agents.
【Stability】

Stable under normal temperatures and pressures.
【Decomposition】

Hydrogen chloride, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
【Combustion Products】

Evolves phosgene when heated.
Transport InformationBack to Contents
【UN Number】

2661
【Hazard Class】

6.1
【Packing Group】

III
【HS Code】

2914 70 90
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