ChemicalBook >>3,4-Dichlorophenol>>3,4-Dichlorophenol(95-77-2)

3,4-Dichlorophenol(95-77-2)

3,4-Dichlorophenol(95-77-2)
Product IdentificationBack to Contents
【Product Name】

3,4-Dichlorophenol
【Synonyms】

4,5-Dichlorophenol
Phenol, 3,4-dichloro-
【CAS】

95-77-2
【Formula】

C6H4Cl2O
【Molecular Weight】

163
【EINECS】

202-450-5
【RTECS】

SK8800000
【RTECS Class】

Other
【Beilstein/Gmelin】

1907693
【Beilstein Reference】

4-06-00-00952
【EC Class】

irritant
Physical and Chemical PropertiesBack to Contents
【Appearance】

Needles (from benzene, petroleum ether) or light brown and yellow crystals.
【Solubility in water】

Insoluble
【Melting Point】

66 - 68
【Boiling Point】

247
【Vapor Pressure】

0.017 (25 C)
【Density】

1.6 g/cm3
【pKa/pKb】

8.55 (pKa)
【Partition Coefficient】

3.33
【Heat Of Vaporization】

50.4 kJ/mol
【Heat Of Combustion】

-2749 kJ/mol
【Usage】

Chemical intermediate for 2-chloro-1,4-dihydroxyanthraquinone & 2,3,4-trichlorophenol.
【Vapor Density】

5.6
【Odor threshold】

100 ug/L in water
First Aid MeasuresBack to Contents
【Ingestion】

Get medical aid. Wash mouth out with water.
【Inhalation】

Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
【Skin】

Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.
【Eyes】

Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Handling and StorageBack to Contents
【Storage】

Store in a cool, dry place. Store in a tightly closed container.
【Handling】

Wash thoroughly after handling. Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Use only in a chemical fume hood.
Hazards IdentificationBack to Contents
【Inhalation】

May cause respiratory tract irritation. Exposure produces central nervous system depression. May be harmful if inhaled. May cause liver damage.
【Skin】

Causes skin irritation. May be harmful if absorbed through the skin.
【Eyes】

Causes eye irritation.
【Ingestion】

Harmful if swallowed. May cause irritation of the digestive tract. May cause burning sensations, coughing, wheezing, laryngitis, shortness of breath and headache.
【Hazards】

When heated, vapors may form explosive mixtures with air: indoors, outdoors, and sewers explosion hazards.
【EC Risk Phrase】

R 21/22 36/37/38
【EC Safety Phrase】

S 24 26 36/37/39
【UN (DOT)】

2020
Exposure Controls/Personal ProtectionBack to Contents
【Personal Protection】

Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
【Respirators】

Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
【Exposure Effects】

Prolonged exposure can cause damage to the eyes, severe irritation or burns.
Fire Fighting MeasuresBack to Contents
【Flash Point】

109
【Fire Fighting】

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. To extinguish fire use water spray, dry chemical, carbon dioxide, or chemical foam.
【Fire Potential】

This material is probably combustible.
Accidental Release MeasuresBack to Contents
【Small spills/leaks】

Vacuum or sweep up material and place into a suitable disposal container.
Stability and ReactivityBack to Contents
【Disposal Code】

3
【Incompatibilities】

Oxidizing agents, acid chlorides, acid anhydrides.
【Stability】

Stable under normal temperatures and pressures.
【Decomposition】

Hydrogen chloride, carbon monoxide, carbon dioxide.
【Combustion Products】

Fire may produce irritating, corrosive and/or toxic gases.
Transport InformationBack to Contents
【UN Number】

2020
【Hazard Class】

6.1
【Packing Group】

III
【HS Code】

2908 10 00
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