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4-Chlorobenzotrichloride(5216-25-1)

4-Chlorobenzotrichloride(5216-25-1)
Product IdentificationBack to Contents
【Product Name】

4-Chlorobenzotrichloride
【Synonyms】

alpha,alpha,alpha,4-Tetrachlorotoluene
【CAS】

5216-25-1
【Formula】

C7H4Cl4
【Molecular Weight】

229.91
【EINECS】

226-009-1
【RTECS】

XT8580000
【RTECS Class】

Other
【Beilstein/Gmelin】

1866549
【Beilstein Reference】

4-05-00-00823
【EC Index Number】

602-093-00-9
Physical and Chemical PropertiesBack to Contents
【Appearance】

Clear colorless liquid.
【Solubility in water】

Insoluble
【Melting Point】

5.8
【Boiling Point】

245
【Vapor Pressure】

0.05 (25 C)
【Density】

1.5036 g/cm3 (20 C)
【Partition Coefficient】

3.94
【Heat Of Vaporization】

46.3 kJ/mol
【Vapor Density】

7.9
【Refractive Index】

1.5733 (16 C)
First Aid MeasuresBack to Contents
【Ingestion】

Never give anything by mouth to an unconscious person. Get medical aid immediately. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
【Inhalation】

Get medical aid immediately. Remove from exposure to fresh air immediately. If breathing is difficult, give oxygen. DO NOT use mouth-to-mouth respiration. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
【Skin】

Get medical aid immediately. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Destroy contaminated shoes.
【Eyes】

Get medical aid immediately. Do NOT allow victim to rub or keep eyes closed. Extensive irrigation is required (at least 30 minutes).
Handling and StorageBack to Contents
【Storage】

Keep container closed when not in use. Corrosives area. Store protected from moisture.
【Handling】

Use only in a well ventilated area. Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Keep container tightly closed. Do not ingest or inhale. Do not allow contact with water. Discard contaminated shoes. Keep from contact with moist air and steam.
Hazards IdentificationBack to Contents
【Inhalation】

Causes chemical burns to the respiratory tract. Aspiration may lead to pulmonary edema. May cause cardiac abnormalities. May cause systemic effects.
【Skin】

Causes skin burns. May cause skin rash (in milder cases), and cold and clammy skin with cyanosis or pale color.
【Eyes】

Causes eye burns. Produces irritation, characterized by a burning sensation, redness, tearing, inflammation, and possible corneal injury. Lachrymator. May cause chemical conjunctivitis and corneal damage.
【Ingestion】

Causes gastrointestinal tract burns. May cause perforation of the digestive tract. May cause cardiac disturbances. May cause central nervous system effects. May cause systemic effects.
【Hazards】

Contact with metals may evolve flammable hydrogen gas.
【EC Risk Phrase】

R 20/22 34
【EC Safety Phrase】

S 26 36/37/39 45
【UN (DOT)】

1760
Exposure Controls/Personal ProtectionBack to Contents
【Personal Protection】

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
【Respirators】

Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
【Exposure Effects】

Effects may be delayed.
Fire Fighting MeasuresBack to Contents
【Flash Point】

109
【Autoignition】

505
【Fire Fighting】

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated. Contact with water forms corrosive vapors. Runoff from fire control or dilution water may cause pollution. Extinguishing media: Do NOT get water inside containers. For small fires, use dry chemical, carbon dioxide, or water spray. For large fires, use dry chemical, carbon dioxide, alcohol-resistant foam, or water spray. Cool containers with flooding quantities of water until well after fire is out.
【Fire Potential】

Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes.
Accidental Release MeasuresBack to Contents
【Small spills/leaks】

Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, using the appropriate protective equipment. Provide ventilation. Do not get water inside containers.
Stability and ReactivityBack to Contents
【Incompatibilities】

Oxidizing agents, moisture.
【Stability】

Stable under normal temperatures and pressures.
【Decomposition】

Hydrogen chloride, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
【Combustion Products】

Fire may produce irritating, corrosive and/or toxic gases.
Transport InformationBack to Contents
【UN Number】

1760
【Hazard Class】

8
【Packing Group】

I; II; III
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