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4-Fluorobenzenesulfonyl chloride(349-88-2)

4-Fluorobenzenesulfonyl chloride(349-88-2)
Product IdentificationBack to Contents
【Product Name】

4-Fluorobenzenesulfonyl chloride
【Synonyms】

4-Fluorophenylsulfonyl chloride
p-Fluorobenzenesulfonyl chloride
p-Fluorophenylsulfonyl chloride
【CAS】

349-88-2
【Formula】

C6H4ClFO2S
【Molecular Weight】

194.6
【EINECS】

206-493-0
【Beilstein/Gmelin】

2091633
【Beilstein Reference】

4-11-00-00102
Physical and Chemical PropertiesBack to Contents
【Appearance】

White solid.
【Solubility in water】

Insoluble
【Melting Point】

36
【Boiling Point】

263
【Vapor Pressure】

0.02 (25 C)
【Partition Coefficient】

2.3
【Heat Of Vaporization】

48.1 kJ/mol
First Aid MeasuresBack to Contents
【Ingestion】

If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
【Inhalation】

Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
【Skin】

Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
【Eyes】

Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Handling and StorageBack to Contents
【Storage】

Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
【Handling】

Wash thoroughly after handling. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.
Hazards IdentificationBack to Contents
【Ingestion】

May cause gastrointestinal irritation with nausea, vomiting and diarrhea. The toxicological properties of this substance have not been fully investigated.
【Inhalation】

May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
【Skin】

May cause skin irritation and possible burns. The toxicological properties of this material have not been fully investigated.
【Eyes】

May cause eye irritation and possible burns. The toxicological properties of this material have not been fully investigated.
【Hazards】

Contact with metals may evolve flammable hydrogen gas.
【EC Risk Phrase】

R 34
【EC Safety Phrase】

S 26 36/37/39 45
【UN (DOT)】

1759
Exposure Controls/Personal ProtectionBack to Contents
【Personal Protection】

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
【Respirators】

Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
Fire Fighting MeasuresBack to Contents
【Flash Point】

113
【Fire Fighting】

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Extinguishing media: Do NOT use water directly on fire. Use foam, dry chemical, or carbon dioxide. Use agent most appropriate to extinguish fire.
【Fire Potential】

Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes.
Accidental Release MeasuresBack to Contents
【Small spills/leaks】

Clean up spills immediately, using the appropriate protective equipment. Sweep up or absorb material, then place into a suitable clean, dry, closed container for disposal. Provide ventilation.
Stability and ReactivityBack to Contents
【Incompatibilities】

Bases, amines.
【Stability】

Stable under normal temperatures and pressures.
【Decomposition】

Hydrogen chloride, carbon monoxide, oxides of sulfur, irritating and toxic fumes and gases, carbon dioxide, hydrogen fluoride.
【Combustion Products】

Fire may produce irritating, corrosive and/or toxic gases.
Transport InformationBack to Contents
【UN Number】

1759
【Hazard Class】

8
【Packing Group】

I; II; III
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