ChemicalBook >>Acetonylacetone>>2,5-Hexanedione(110-13-4)

2,5-Hexanedione(110-13-4)

2,5-Hexanedione(110-13-4)
Product IdentificationBack to Contents
【Product Name】

2,5-Hexanedione
【Synonyms】

1,2-Diacetylethane
2,5-Diketohexane
2,5-Dioxohexane
2,5-Hexanedione
Diacetonyl
【CAS】

110-13-4
【Formula】

C6H10O2
【Molecular Weight】

114.15
【EINECS】

203-738-3
【RTECS】

MO3150000
【RTECS Class】

Mutagen; Reproductive Effector; Primary Irritant
【Merck】

13,72
【Beilstein/Gmelin】

506525
【Beilstein Reference】

4-01-00-03688
【EC Class】

irritant
Physical and Chemical PropertiesBack to Contents
【Appearance】

Clear colorless to amber liquid with a sweet aromatic odor.
【Solubility in water】

Very soluble
【Melting Point】

-5.4
【Boiling Point】

191
【Vapor Pressure】

0.6 (25 C)
【Density】

0.971 g/cm3 (20 C)
【Partition Coefficient】

-.27
【Heat Of Vaporization】

42.5 kJ/mol
【Vapor Density】

3.94
【Refractive Index】

1.42167 (17 C)
First Aid MeasuresBack to Contents
【Ingestion】

Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid.
【Inhalation】

Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
【Skin】

Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
【Eyes】

Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Handling and StorageBack to Contents
【Storage】

Keep away from heat, sparks, and flame. Store in a cool, dry place. Keep container closed when not in use. Flammables-area.
【Handling】

Wash thoroughly after handling. Wash hands before eating. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Avoid ingestion and inhalation. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
Hazards IdentificationBack to Contents
【Inhalation】

Causes respiratory tract irritation.
【Skin】

Causes skin irritation.
【Eyes】

Causes eye irritation.
【Ingestion】

Causes gastrointestinal irritation with nausea, vomiting and diarrhea. May cause central nervous system effects.
【Hazards】

Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers.
【EC Risk Phrase】

R 36/38 48/20/21/22
【EC Safety Phrase】

S 23 26 36/37
【UN (DOT)】

1224
Exposure Controls/Personal ProtectionBack to Contents
【Personal Protection】

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
【Respirators】

Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
【Exposure Effects】

The toxological properties of this substance have not been fully investigated.
【Poison Class】

3
Fire Fighting MeasuresBack to Contents
【Flash Point】

79
【Autoignition】

400
【Fire Fighting】

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water spray to keep fire-exposed containers cool. Combustible Liquid. Containers may explode if exposed to fire. To extinguish fire, use water, dry chemical, chemical foam, or alcohol-resistant foam. Use agent most appropriate to extinguish fire. Cool containers with flooding quantities of water until well after fire is out.
【Lower exp. limit】

1.5
【Fire Potential】

This chemical is combustible.
Accidental Release MeasuresBack to Contents
【Small spills/leaks】

Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Clean up spills immediately, using the appropriate protective equipment. Remove all sources of ignition. Use a spark-proof tool. Provide ventilation.
Stability and ReactivityBack to Contents
【Disposal Code】

1
【Stability】

Stable under normal temperatures and pressures.
【Incompatibilities】

Strong oxidants.
【Decomposition】

Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
【Combustion Products】

Fire may produce irritating, corrosive and/or toxic gases.
Transport InformationBack to Contents
【UN Number】

1224
【Hazard Class】

3
【Packing Group】

I; II; III
【HS Code】

2914 19 90
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