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Ethyl phosphorodichloridate(1498-51-7)

Ethyl phosphorodichloridate(1498-51-7)
Product IdentificationBack to Contents
【Product Name】

Ethyl phosphorodichloridate
【Synonyms】

Dichloroethoxyphosphine oxide
Ethyl dichlorophosphate
Ethyl phosphoryl dichloride
Ethylphosphoric acid dichloride
Ethylphosphorodichloridate
【CAS】

1498-51-7
【Formula】

C2H5Cl2O2P
【Molecular Weight】

162.94
【EINECS】

216-099-0
【RTECS】

TD4390000
【RTECS Class】

Other
【Beilstein/Gmelin】

506857
【Beilstein Reference】

4-01-00-01345
Physical and Chemical PropertiesBack to Contents
【Appearance】

Colorless liquid.
【Solubility in water】

Slightly soluble
【Melting Point】

-42.5
【Boiling Point】

187
【Vapor Pressure】

0.9 (25 C)
【Density】

1.4362 g/cm3 (20 C)
【Partition Coefficient】

1.24
【Heat Of Vaporization】

40.6 kJ/mol
【Heat Of Combustion】

-1779 kJ/mol
【Usage】

Intermediate in the manufacture of the pesticide ethoprop.
【Vapor Density】

5.62
【Refractive Index】

1.4340 (20 C)
First Aid MeasuresBack to Contents
【Ingestion】

Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
【Inhalation】

Get medical aid immediately. Remove from exposure to fresh air immediately. If breathing is difficult, give oxygen. DO NOT use mouth-to-mouth respiration. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
【Skin】

Get medical aid immediately. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Destroy contaminated shoes.
【Eyes】

Get medical aid immediately. Do NOT allow victim to rub or keep eyes closed. Extensive irrigation is required (at least 30 minutes).
Handling and StorageBack to Contents
【Storage】

Keep container closed when not in use. Store in a cool, dry, well-ventilated area away from incompatible substances. Corrosives area. Store protected from moisture.
【Handling】

Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use only in a well ventilated area. Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Keep container tightly closed. Do not ingest or inhale. Do not allow contact with water. Discard contaminated shoes. Keep from contact with moist air and steam.
Hazards IdentificationBack to Contents
【Inhalation】

May be fatal if inhaled. May cause severe irritation of the respiratory tract with sore throat, coughing, shortness of breath and delayed lung edema. Causes chemical burns to the respiratory tract. Aspiration may lead to pulmonary edema. May cause systemic effects.
【Skin】

Causes skin burns. May cause skin rash (in milder cases), and cold and clammy skin with cyanosis or pale color.
【Eyes】

Causes eye burns. May cause chemical conjunctivitis and corneal damage.
【Ingestion】

Harmful if swallowed. May cause severe and permanent damage to the digestive tract. Causes gastrointestinal tract burns. May cause perforation of the digestive tract. May cause systemic effects.
【Hazards】

Contact with metals may evolve flammable hydrogen gas.
【UN (DOT)】

2927
Exposure Controls/Personal ProtectionBack to Contents
【Personal Protection】

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to minimize contact with skin.
【Respirators】

A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use.
【Exposure Effects】

Effects may be delayed.
Fire Fighting MeasuresBack to Contents
【Flash Point】

28
【Fire Fighting】

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Extinguishing media: Do NOT get water inside containers. Cool containers with flooding quantities of water until well after fire is out. In case of fire, use carbon dioxide, dry chemical powder or appropriate foam.
【Fire Potential】

Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes.
Accidental Release MeasuresBack to Contents
【Small spills/leaks】

Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Clean up spills immediately, using the appropriate protective equipment. Provide ventilation. Do not get water inside containers.
Stability and ReactivityBack to Contents
【Incompatibilities】

Moisture, strong oxidizing agents, strong bases.
【Stability】

Stable under normal temperatures and pressures.
【Decomposition】

Hydrogen chloride, phosphine, carbon monoxide, oxides of phosphorus, irritating and toxic fumes and gases, carbon dioxide.
【Combustion Products】

Irritating fumes of hydrogen chloride and phosphoric acid may be formed.
Transport InformationBack to Contents
【UN Number】

2927
【Hazard Class】

6.1
【Packing Group】

I; II
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