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p-Tolualdehyde(104-87-0)

p-Tolualdehyde(104-87-0)
Product IdentificationBack to Contents
【Product Name】

p-Tolualdehyde
【Synonyms】

4-Methylbenzaldehyde
4-Tolualdehyde
p-Formyltoluene
p-Tolualdehyde
【CAS】

104-87-0
【Formula】

C8H8O
【Molecular Weight】

120.15
【EINECS】

203-246-9
【RTECS】

CU7034500
【RTECS Class】

Primary Irritant
【Beilstein/Gmelin】

4112855
【EC Class】

harmful
Physical and Chemical PropertiesBack to Contents
【Appearance】

colorless liquid. Floral odor.
【Solubility in water】

Slightly soluble
【Melting Point】

-6
【Boiling Point】

205
【Vapor Pressure】

2.5 (25 C)
【Density】

1.0194 g/cm3 (17 C)
【Partition Coefficient】

2.1
【Heat Of Vaporization】

44.1 kJ/mol
【Usage】

In perfumes, pharmaceutical & dyestuff intermediate, flavoring agent.
【Vapor Density】

4.1
【Refractive Index】

1.5479 (20 C)
First Aid MeasuresBack to Contents
【Ingestion】

Never give anything by mouth to an unconscious person. Get medical aid immediately. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
【Inhalation】

Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
【Skin】

Get medical aid immediately. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
【Eyes】

Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Handling and StorageBack to Contents
【Storage】

Keep away from heat, sparks, and flame. Keep away from sources of ignition. Keep container closed when not in use. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
【Handling】

Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use only in a well ventilated area. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Avoid contact with heat, sparks and flame. Avoid ingestion and inhalation. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
Hazards IdentificationBack to Contents
【Ingestion】

May cause gastrointestinal irritation with nausea, vomiting and diarrhea. May be harmful if swallowed.
【Inhalation】

Causes respiratory tract irritation with possible burns. May cause irritation of the mucous membranes.
【Skin】

May cause skin irritation.
【Eyes】

May cause eye irritation and possible burns. Lachrymator.
【Hazards】

Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion and poison hazard indoors, outdoors or in sewers.
【EC Risk Phrase】

R 36/38
【EC Safety Phrase】

S 26 36
【UN (DOT)】

1988
Exposure Controls/Personal ProtectionBack to Contents
【Personal Protection】

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to minimize contact with skin.
【Respirators】

Wear a NIOSH/MSHA or European Standard EN 149 approved full-facepiece airline respirator in the positive pressure mode with emergency escape provisions. Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
【Poison Class】

4 (Substances and products that must be considered harmful)
Fire Fighting MeasuresBack to Contents
【Flash Point】

71.5
【Autoignition】

395
【Fire Fighting】

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water spray to keep fire-exposed containers cool. Combustible Liquid. To extinguish fire, use water, dry chemical, chemical foam, or alcohol-resistant foam. Use water spray to cool fire-exposed containers.
【Upper exp. limit】

5.6
【Lower exp. limit】

.9
【Fire Potential】

HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames.
Accidental Release MeasuresBack to Contents
【Small spills/leaks】

Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Clean up spills immediately, using the appropriate protective equipment. Remove all sources of ignition. Use a spark-proof tool. Provide ventilation.
Stability and ReactivityBack to Contents
【Disposal Code】

1
【Incompatibilities】

Oxidizing agents
【Stability】

Stable under normal temperatures and pressures.
【Decomposition】

Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
【Combustion Products】

Fire will produce irritating, corrosive and/or toxic gases.
Transport InformationBack to Contents
【UN Number】

1988
【Hazard Class】

3
【Packing Group】

I; II; III
【HS Code】

2912 29 00
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