ChemicalBook >>Acetaldoxime>>Acetaldehyde oxime(107-29-9)

Acetaldehyde oxime(107-29-9)

Acetaldehyde oxime(107-29-9)
Product IdentificationBack to Contents
【Product Name】

Acetaldehyde oxime
【Synonyms】

Acetaldoxime
【CAS】

107-29-9
【Formula】

C2H5NO
【Molecular Weight】

59.07
【EINECS】

203-479-6
【RTECS】

AB2975000
【RTECS Class】

Mutagen
【Merck】

13,43
【Beilstein/Gmelin】

1209252
【Beilstein Reference】

4-01-00-03121
【EC Class】

flammable
Physical and Chemical PropertiesBack to Contents
【Appearance】

A colorless liquid with a pungent odor.
【Solubility in water】

Soluble
【Melting Point】

47
【Boiling Point】

115
【Vapor Pressure】

13
【Density】

0.969 g/cm3 (17 C)
【pKa/pKb】

11.82 (pKa)
【Partition Coefficient】

-.13
【Heat Of Vaporization】

38.9 kJ/mol
【Usage】

Aldoximes, such as acetaldehyde oxime, are used as intermediates in chemical synthesis.
【Refractive Index】

1.424 (20 C)
First Aid MeasuresBack to Contents
【Ingestion】

Get medical aid immediately. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
【Inhalation】

Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
【Skin】

Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.
【Eyes】

Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Handling and StorageBack to Contents
【Storage】

Keep away from heat, sparks, and flame. Refrigerator/flammables.
【Handling】

Wash thoroughly after handling. Wash hands before eating. Use only in a well ventilated area. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Avoid contact with heat, sparks and flame. Avoid ingestion and inhalation. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
Hazards IdentificationBack to Contents
【Ingestion】

Harmful if swallowed. May cause gastrointestinal irritation with nausea, vomiting and diarrhea.
【Inhalation】

Harmful if inhaled. May cause respiratory tract irritation.
【Skin】

May cause skin irritation. Harmful if absorbed through the skin.
【Eyes】

May cause eye irritation.
【Hazards】

Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. May polymerize explosively when heated or involved in a fire. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water.
【EC Risk Phrase】

R 10 22 36/38
【EC Safety Phrase】

S 26 36
【UN (DOT)】

2332
Exposure Controls/Personal ProtectionBack to Contents
【Personal Protection】

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
【Respirators】

Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
【Poison Class】

3
Fire Fighting MeasuresBack to Contents
【Flash Point】

40
【Fire Fighting】

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. To extinguish fire, use water, dry chemical, chemical foam, or alcohol-resistant foam. Use agent most appropriate to extinguish fire.
【Upper exp. limit】

50
【Lower exp. limit】

4.2
【Fire Potential】

HIGHLY FLAMMABLE.
Accidental Release MeasuresBack to Contents
【Small spills/leaks】

Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Clean up spills immediately, using the appropriate protective equipment.
Stability and ReactivityBack to Contents
【Stability】

Stable under normal temperatures and pressures.
【Incompatibilities】

Strong oxidizing agents; strong acids.
【Decomposition】

Nitrogen oxides, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, nitrogen.
【Combustion Products】

When heated to decomposition it emits toxic fumes of oxides of nitrogen.
Transport InformationBack to Contents
【UN Number】

2332
【Hazard Class】

3
【Packing Group】

III
【HS Code】

2928 00 90
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