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2,4,6-Tribromoaniline(147-82-0)

2,4,6-Tribromoaniline(147-82-0)
Product IdentificationBack to Contents
【Product Name】

2,4,6-Tribromoaniline
【Synonyms】

2,4,6-Tribromobenzenamine
sym-Tribromoaniline
【CAS】

147-82-0
【Formula】

C6H4Br3N
【Molecular Weight】

329.82
【EINECS】

205-700-1
【RTECS】

BZ0175000
【RTECS Class】

Other
【Merck】

12,9740
【Beilstein/Gmelin】

2209258
【Beilstein Reference】

4-12-00-01538
Physical and Chemical PropertiesBack to Contents
【Appearance】

Needles from alcohol, benzene.
【Solubility in water】

Insoluble
【Melting Point】

118
【Boiling Point】

300
【Vapor Pressure】

0.0012 (25 C)
【Density】

2.578 g/cm3
【Partition Coefficient】

4.42
【Heat Of Vaporization】

54.0 kJ/mol
【Heat Of Combustion】

-2989 kJ/mol
First Aid MeasuresBack to Contents
【Ingestion】

Emesis: ipecac-induced vomiting is not recommended because of the potential for cns depression and seizures. Activated charcoal: administer charcoal as a slurry (240 ml water/30 g charcoal). Usual dose: 25 to 100 g in adults/adolescents. Consider after ingestion of a potentially life-threatening amount of poison if it can be performed soon after ingestion (generally within 1 hour). Oxygen - administer oxygen to all cyanotic or symptomatic patients. Methemoglobinemia: administer 1 to 2 mg/kg of 1% methylene blue slowly iv in symptomatic patients. Additional doses may be required. Shock and cardiac arrest - treat routinely. Adjunctive therapy - exchange transfusions and hyperbaric oxygen may be useful in severe cases.
【Inhalation】

Move victim to fresh air. Apply artificial respiration if victim is not breathing. Do not use mouth-to-mouth method if victim ingested or inhaled the substance; induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Administer oxygen if breathing is difficult.
【Skin】

Remove and isolate contaminated clothing and shoes. Immediately flush with running water for at least 20 minutes. For minor skin contact, avoid spreading material on unaffected skin.
【Eyes】

Immediately flush with running water for at least 20 minutes.
Handling and StorageBack to Contents
【Storage】

Keep in a cool, dry, dark location in a tightly sealed container or cylinder. Keep away from incompatible materials, ignition sources and untrained individuals. Secure and label area. Protect containers/cylinders from physical damage.
【Handling】

All chemicals should be considered hazardous. Avoid direct physical contact. Use appropriate, approved safety equipment. Untrained individuals should not handle this chemical or its container. Handling should occur in a chemical fume hood.
Hazards IdentificationBack to Contents
【Ingestion】

Nausea and vomiting may occur.
【Inhalation】

Dyspnea and tachypnea may occur.
【Skin】

Central cyanosis unresponsive to oxygen therapy is classic.
【Eyes】

See Inhalation.
【Hazards】

When heated, vapors may form explosive mixtures with air: indoors, outdoors, and sewers explosion hazards.
【EC Risk Phrase】

R 20/21/22 33
【EC Safety Phrase】

S 22 36/37
【UN (DOT)】

2810
Exposure Controls/Personal ProtectionBack to Contents
【Personal Protection】

Wear appropriate protective gloves, clothing and goggles.
【Respirators】

Not available.
Fire Fighting MeasuresBack to Contents
【Flash Point】

133
【Fire Fighting】

Small Fires: Dry chemical, carbon dioxide or water spray. Large Fires: Dry chemical, carbon dioxide, alcohol-resistant foam or water spray.
【Fire Potential】

Combustible material: may burn but does not ignite readily.
Accidental Release MeasuresBack to Contents
【Small spills/leaks】

ELIMINATE all ignition sources. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Stop leak if you can do it without risk. Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers. DO NOT GET WATER INSIDE CONTAINERS.
Stability and ReactivityBack to Contents
【Stability】

No data.
【Combustion Products】

Fire may produce irritating, corrosive and/or toxic gases.
Transport InformationBack to Contents
【UN Number】

2810
【Hazard Class】

6.1
【Packing Group】

I; II; III
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