| Product Identification | Back to Contents | 【Product Name】
3-Nitrobenzyl chloride | 【Synonyms】
3-Nitrobenzyl chloride
alpha-Chloro-3-nitrotoluene
m-Nitrobenzyl chloride | 【CAS】
619-23-8 | 【Formula】
C7H6ClNO2 | 【Molecular Weight】
171.58 | 【EINECS】
210-586-1 | 【RTECS】
XS9090000 | 【RTECS Class】
Mutagen | 【Beilstein/Gmelin】
742794 | 【Beilstein Reference】
4-05-00-00855 |
| Physical and Chemical Properties | Back to Contents | 【Appearance】
Yellow to brown solid. | 【Solubility in water】
Insoluble | 【Melting Point】
43-46 | 【Boiling Point】
289 | 【Vapor Pressure】
0.004 (25 C) | 【Partition Coefficient】
2.22 | 【Heat Of Vaporization】
50.7 kJ/mol | 【Refractive Index】
1.5577 (62 C) |
| First Aid Measures | Back to Contents | 【Ingestion】
Never give anything by mouth to an unconscious person. Get medical aid immediately. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. | 【Inhalation】
Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. | 【Skin】
Get medical aid immediately. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. | 【Eyes】
Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. Do NOT allow victim to rub or keep eyes closed. |
| Handling and Storage | Back to Contents | 【Storage】
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Keep away from water. | 【Handling】
Keep container tightly closed. Do not get on skin or in eyes. Do not ingest or inhale. Use with adequate ventilation. Wash clothing before reuse. |
| Hazards Identification | Back to Contents | 【Inhalation】
Causes respiratory tract irritation. May cause burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Can produce delayed pulmonary edema. | 【Skin】
Causes skin irritation. | 【Eyes】
Causes eye irritation. Lachrymator. May cause chemical conjunctivitis. | 【Ingestion】
May cause gastrointestinal irritation with nausea, vomiting and diarrhea. | 【Hazards】
Contact with metals may evolve flammable hydrogen gas. | 【EC Risk Phrase】
R 20/21/22 34 | 【EC Safety Phrase】
S 26 36/37/39 45 | 【UN (DOT)】
2811 |
| Exposure Controls/Personal Protection | Back to Contents | 【Personal Protection】
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. | 【Respirators】
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use. | 【Exposure Effects】
Effects may be delayed. |
| Fire Fighting Measures | Back to Contents | 【Flash Point】
129 | 【Fire Fighting】
Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Water runoff can cause environmental damage. Dike and collect water used to fight fire. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Containers may explode when heated. Combustible material; may burn but does not ignite readily. Water hydrolyzes material liberating acidic gas which in contact with metal surfaces can generate flammable and/or explosive hydrogen gas. Extinguishing media: DO NOT USE WATER! In case of fire use water spray, dry chemical, carbon dioxide, or appropriate foam. In case of fire, use carbon dioxide, dry chemical powder or appropriate foam. | 【Fire Potential】
Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. |
| Accidental Release Measures | Back to Contents | 【Small spills/leaks】
Cover with sand, dry lime or soda ash and place in a closed container for disposal. Provide ventilation. Do not get water inside containers. Cover with plastic sheet to prevent spreading. |
| Stability and Reactivity | Back to Contents | 【Stability】
May decompose on exposure to moist air or water. Stable, however may violently decompose at temperatures above 125 C. | 【Incompatibilities】
Oxidizing agents, bases, alcohols, amines, steel, moisture. | 【Decomposition】
Hydrogen chloride, nitrogen oxides, carbon monoxide, carbon dioxide, chloride fumes. | 【Combustion Products】
Fire may produce irritating, corrosive and/or toxic gases. |
|
|