ChemicalBook >>N,N-Diisopropylethylamine>>Huenig's base(7087-68-5)

Huenig's base(7087-68-5)

Huenig's base(7087-68-5)
Product IdentificationBack to Contents
【Product Name】

Huenig's base
【Synonyms】

2-Propanamine, N-ethyl-N-(1-methylethyl)-
Bis(1-methylethyl)ethylamine
Hunig's reagent
N,N-Diisopropylethylamine
N-Ethyl-N,N-diisopropylamine
N-Ethyl-N-isopropyl-2-propanamine
【CAS】

7087-68-5
【Formula】

C8H19N
【Molecular Weight】

129.25
【EINECS】

230-392-0
【Beilstein/Gmelin】

605301
【Beilstein Reference】

4-04-00-00511
【EC Class】

highly flammable, harmful, corrosive, dangerous for the environment
Physical and Chemical PropertiesBack to Contents
【Appearance】

Colorless liquid. Ammonia-like odor.
【Solubility in water】

Very soluble
【Melting Point】

-50
【Boiling Point】

127
【Vapor Pressure】

120 (20 C)
【Density】

0.751 g/cm3 (27 C)
【pKa/pKb】

3.02 (pKb)
【Partition Coefficient】

2.35
【Heat Of Vaporization】

36.4 kJ/mol
【Refractive Index】

1.4138 (20 C)
First Aid MeasuresBack to Contents
【Ingestion】

Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
【Inhalation】

Get medical aid immediately. Remove from exposure to fresh air immediately. If breathing is difficult, give oxygen.
【Skin】

Get medical aid immediately. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.
【Eyes】

Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Handling and StorageBack to Contents
【Storage】

Keep away from heat, sparks, and flame. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Flammables-area.
【Handling】

Wash thoroughly after handling. Ground and bond containers when transferring material. Use spark-proof tools and explosion proof equipment. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Avoid ingestion and inhalation. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
Hazards IdentificationBack to Contents
【Ingestion】

May cause irritation of the digestive tract and possible burns.
【Inhalation】

May cause severe respiratory tract irritation and possible burns.
【Skin】

Causes skin irritation and possible burns.
【Eyes】

Causes eye irritation and possible burns.
【Hazards】

Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers.
【EC Risk Phrase】

R 11 20/21/22 34
【EC Safety Phrase】

S 16 26 36/37/39 45
【UN (DOT)】

2733
Exposure Controls/Personal ProtectionBack to Contents
【Personal Protection】

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
【Respirators】

Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
Fire Fighting MeasuresBack to Contents
【Flash Point】

9.5
【Autoignition】

240
【Fire Fighting】

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Water may be ineffective. Material is lighter than water and a fire may be spread by the use of water. Containers may explode in the heat of a fire. Extinguishing media: Use water spray to cool fire-exposed containers. Use foam, dry chemical, or carbon dioxide. Water may be ineffective.
【Upper exp. limit】

6.3
【Lower exp. limit】

.7
【Fire Potential】

Flammable/combustible material. May be ignited by heat, sparks or flames.
Accidental Release MeasuresBack to Contents
【Small spills/leaks】

Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Remove all sources of ignition. Use a spark-proof tool.
Stability and ReactivityBack to Contents
【Disposal Code】

5
【Incompatibilities】

Acids, acid chlorides, acid anhydrides, carbon dioxide, strong oxidizing agents, copper, brass, rubber.
【Stability】

No data.
【Decomposition】

Nitrogen oxides, carbon monoxide, carbon dioxide.
【Combustion Products】

Fire will produce irritating, corrosive and/or toxic gases.
Transport InformationBack to Contents
【UN Number】

2733
【Hazard Class】

3
【Packing Group】

I; II; III
【HS Code】

2921 19 80
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