ChemicalBook >>2-Nitroaniline>>2-Nitroaniline(88-74-4)

2-Nitroaniline(88-74-4)

2-Nitroaniline(88-74-4)
Product IdentificationBack to Contents
【Product Name】

2-Nitroaniline
【Synonyms】

1-Amino-2-nitrobenzene
o-Nitroaniline
【CAS】

88-74-4
【Formula】

C6H6N2O2
【Molecular Weight】

138.13
【EINECS】

201-855-4
【RTECS】

BY6650000
【RTECS Class】

Mutagen
【Merck】

12,6680
【Beilstein/Gmelin】

509275
【Beilstein Reference】

4-12-00-01563
【EC Index Number】

612-012-00-9
【EC Class】

Toxic; Danger of cumulative effects; Dangerous for the Environment
Physical and Chemical PropertiesBack to Contents
【Appearance】

Orange solid with a musty odor.
【Solubility in water】

1.1 g/L
【Melting Point】

68 - 71
【Boiling Point】

284
【Vapor Pressure】

0.003 (25 C)
【Density】

1.446 g/cm3 (20 C)
【pKa/pKb】

-0.26(at 25℃) (pKa)
【Partition Coefficient】

1.83
【Heat Of Vaporization】

52.4 kJ/mol
【Heat Of Combustion】

-3029 kJ/mol
【Usage】

Chemical intermediate for ci pigment yellow 5, orange 2, yellow 7, vat red 15, vat orange 7, ci pigment orange 43, vat red 14, disperse yellow 10.
【Refractive Index】

1.5362 (100 C)
First Aid MeasuresBack to Contents
【Ingestion】

If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
【Inhalation】

Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
【Skin】

Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.
【Eyes】

Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Handling and StorageBack to Contents
【Storage】

Store in a cool, dry, well-ventilated area away from incompatible substances. Poison room locked. Keep containers tightly closed.
【Handling】

Wash thoroughly after handling. Use only in a well ventilated area. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.
Hazards IdentificationBack to Contents
【Inhalation】

Dust is irritating to the respiratory tract.
【Skin】

Causes skin irritation.
【Eyes】

Dust may cause mechanical irritation.
【Ingestion】

May be harmful if swallowed. Causes digestive tract irritation.
【Hazards】

When heated, vapors may form explosive mixtures with air: indoors, outdoors, and sewers explosion hazards.
【EC Risk Phrase】

R 23/24/25 33 52/53
【EC Safety Phrase】

S 28 36/37 45 61
【UN (DOT)】

1661
Exposure Controls/Personal ProtectionBack to Contents
【Personal Protection】

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
【Respirators】

Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
【Exposure Effects】

Acute poisoning may cause rapid heart rate and rapid breathing. Severe headache, CNS disturbances, and tremor may occur. A high incidence of gynecological disorders and excess frequency of spontaneous abortions have been noted. The fetal liver can n-oxygenate aniline to form phenylhydroxylamine. Fetal effects include higher levels of methemoglobin those found in than the mother. Fetal poisoning may occur. <br>No data were available to assess the potential effects of exposure to aniline during lactation. <br>No information about possible male reproductive effects was found in available references at the time of this review
【Exposure limit(s)】

NIOSH: Potential Occupational Carcinogen.
Fire Fighting MeasuresBack to Contents
【Flash Point】

126
【Autoignition】

521
【Fire Fighting】

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. May polymerize explosively when involved in a fire. Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated. Combustible material; may burn but does not ignite readily. Extinguishing media: Cool containers with flooding quantities of water until well after fire is out. In case of fire, use water spray, dry chemical, carbon dioxide, or alcohol-resistant foam.
【Upper exp. limit】

9.8
【Lower exp. limit】

1.5
【Fire Potential】

Slightly flammable. Flammable at elevated temperatures - moderate hazard.
Accidental Release MeasuresBack to Contents
【Small spills/leaks】

Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Avoid runoff into storm sewers and ditches which lead to waterways. Avoid generating dusty conditions. Remove all sources of ignition. Provide ventilation.
Stability and ReactivityBack to Contents
【Disposal Code】

9
【Incompatibilities】

Acids - acid chlorides - acid anhydrides - chloroformates - strong oxidizing agents.
【Stability】

Stable under normal temperatures and pressures.
【Decomposition】

Nitrogen oxides, carbon monoxide, carbon dioxide, nitrogen.
【Combustion Products】

Toxic oxides of nitrogen may form in fire.
Transport InformationBack to Contents
【UN Number】

1661
【Hazard Class】

6.1
【Packing Group】

II
【HS Code】

2921 42 10
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