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2-Bromobenzoyl chloride(7154-66-7)

2-Bromobenzoyl chloride(7154-66-7)
Product IdentificationBack to Contents
【Product Name】

2-Bromobenzoyl chloride
【Synonyms】

2-Bromobenzoic acid chloride
o-Bromobenzoyl chloride
【CAS】

7154-66-7
【Formula】

C7H4BrClO
【Molecular Weight】

219.46
【EINECS】

230-507-4
【RTECS】

DM6635000
【RTECS Class】

Other
【Beilstein/Gmelin】

508506
【Beilstein Reference】

4-09-00-01013
Physical and Chemical PropertiesBack to Contents
【Appearance】

Clear, colorless liquid.
【Solubility in water】

Insoluble
【Melting Point】

11
【Boiling Point】

245
【Vapor Pressure】

0.03 (25 C)
【Density】

1.67 g/cm3
【Partition Coefficient】

2.56
【Heat Of Vaporization】

48.3 kJ/mol
【Vapor Density】

7.57
【Refractive Index】

1.5965 (20 C)
First Aid MeasuresBack to Contents
【Ingestion】

Never give anything by mouth to an unconscious person. Get medical aid immediately. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
【Inhalation】

Get medical aid immediately. Remove from exposure to fresh air immediately. If breathing is difficult, give oxygen. Do not use mouth-to-mouth respiration if victim ingested or inhaled the substance; induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device.
【Skin】

Get medical aid immediately. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Destroy contaminated shoes.
【Eyes】

Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. Do NOT allow victim to rub or keep eyes closed. Extensive irrigation is required (at least 30 minutes).
Handling and StorageBack to Contents
【Storage】

Refrigerator (approx 4 C). Keep containers tightly closed. Store protected from moisture.
【Handling】

Keep container tightly closed. Do not get on skin or in eyes. Do not ingest or inhale. Use with adequate ventilation. Do not allow contact with water. Use only in a chemical fume hood. Discard contaminated shoes. Keep from contact with moist air and steam.
Hazards IdentificationBack to Contents
【Inhalation】

May cause severe irritation of the respiratory tract with sore throat, coughing, shortness of breath and delayed lung edema. Causes chemical burns to the respiratory tract. Inhalation may be fatal as a result of spasm, inflammation, edema of the larynx and bronchi, chemical pneumonitis and pulmonary edema. May cause systemic effects. May cause burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting.
【Skin】

Causes skin burns. May cause skin rash (in milder cases), and cold and clammy skin with cyanosis or pale color.
【Eyes】

Causes eye burns. Lachrymator. May cause chemical conjunctivitis and corneal damage.
【Ingestion】

May cause severe and permanent damage to the digestive tract. Causes gastrointestinal tract burns. May cause perforation of the digestive tract. May cause systemic effects.
【Hazards】

When heated, vapors may form explosive mixtures with air: indoors, outdoors, and sewers explosion hazards.
【EC Risk Phrase】

R 34
【EC Safety Phrase】

S 26 36/37/39 45
【UN (DOT)】

3265
Exposure Controls/Personal ProtectionBack to Contents
【Personal Protection】

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to minimize contact with skin.
【Respirators】

A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use.
【Exposure Effects】

Effects may be delayed.
Fire Fighting MeasuresBack to Contents
【Flash Point】

102
【Fire Fighting】

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Water hydrolyzes material liberating acidic gas which in contact with metal surfaces can generate flammable and/or explosive hydrogen gas. Extinguishing media: Do NOT use water directly on fire. Use foam, dry chemical, or carbon dioxide. Do NOT get water inside containers.
【Fire Potential】

Combustible material: may burn but does not ignite readily.
Accidental Release MeasuresBack to Contents
【Small spills/leaks】

Clean up spills immediately, using the appropriate protective equipment. Cover with sand, dry lime or soda ash and place in a closed container for disposal. Provide ventilation. Do not get water inside containers.
Stability and ReactivityBack to Contents
【Incompatibilities】

Oxidizing agents, strong bases, alcohols, moisture, water.
【Stability】

Stable under normal temperatures and pressures. Moisture sensitive.
【Decomposition】

Hydrogen chloride, phosgene, carbon monoxide, carbon dioxide, hydrogen bromide.
【Combustion Products】

Fire may produce irritating, corrosive and/or toxic gases.
Transport InformationBack to Contents
【UN Number】

3265
【Hazard Class】

8
【Packing Group】

I; II; III
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