| Product Identification | Back to Contents | 【Product Name】
1,1,2-Trichloroethane | 【Synonyms】
beta-Trichloroethane
Emulgen - 913
Ethane trichloride
Neutronyx 600
Peg-9 nonyl phenyl ether
Polyethylene glycol 450 nonyl phenyl ether
Polyoxyethylene (9) nonyl phenyl ether
Vinyl trichloride | 【CAS】
79-00-5 | 【CAS】
9016-45-9 | 【Formula】
C2H3Cl3 | 【Formula】
(C2H4O)nC15H24O | 【Molecular Weight】
133.4 | 【EINECS】
201-166-9 | 【EINECS】
500-024-6 | 【RTECS】
KJ3150000 | 【RTECS】
WZ4750000 | 【RTECS Class】
Primary Irritant | 【RTECS Class】
Agricultural Chemical and Pesticide; Tumorigen; Drug; Mutagen; Primary Irritant | 【Merck】
12,9767 | 【Beilstein/Gmelin】
1731726 | 【Beilstein/Gmelin】
8402221 | 【Beilstein Reference】
4-01-00-00139 | 【EC Index Number】
602-014-00-8 | 【EC Class】
Harmful |
| Physical and Chemical Properties | Back to Contents | 【Appearance】
Clear, almost colorless liquid with a sweetish odor. | 【Appearance】
Slightly hazy, light amber liquid. | 【Solubility in water】
Insoluble | 【Solubility in water】
4.4 g/L (20 C) | 【Melting Point】
-35.5 | 【Boiling Point】
113.8 | 【Boiling Point】
94 | 【Vapor Pressure】
17 (20 C) | 【Density】
1.06 g/cm3 (20 C) | 【Density】
1.42234 g/cm3 (0 C) | 【Partition Coefficient】
2.17 | 【Heat Of Vaporization】
40.23 kJ/mol | 【Heat Of Combustion】
-1099 kJ/mol | 【Usage】
Fungicide, adjuvant, soap/surfactant. | 【Usage】
Used in adhesives, production of teflon tubing, in lacquer, and coating formulations. | 【Vapor Density】
4.63 | 【Refractive Index】
1.466 (30 C) |
| First Aid Measures | Back to Contents | 【Ingestion】
DO NOT INDUCE VOMITING. If the victim is conscious and not convulsing, give 1 or 2 glasses of water to dilute the chemical and IMMEDIATELY call a hospital or poison control center. Be prepared to transport the victim to a hospital if advised by a physician. | 【Ingestion】
If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately. | 【Inhalation】
IMMEDIATELY leave the contaminated area; take deep breaths of fresh air. If symptoms (such as wheezing, coughing, shortness of breath, or burning in the mouth, throat, or chest) develop, call a physician and be prepared to transport the victim to a hospital. Provide proper respiratory protection to rescuers entering an unknown atmosphere. Whenever possible, Self-Contained Breathing Apparatus (SCBA) should be used. | 【Inhalation】
Occupational asthma has been reported. Aspiration may result in upper airway edema and significant respiratory distress. Difficulty in breathing has been described in animals inhaling high concentrations of anionic surfactants. | 【Inhalation】
Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. | 【Skin】
Skin irritation has been reported after prolonged occupational dermal contact. Skin dryness, irritation, and contact dermatitis have been reported following varying degrees of exposure to detergents. | 【Skin】
Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. | 【Skin】
IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing. Gently wash all affected skin areas thoroughly with soap and water. If symptoms such as redness or irritation develop, IMMEDIATELY call a physician and be prepared to transport the victim to a hospital for treatment. | 【Eyes】
First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop. | 【Eyes】
Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. | 【Eyes】
Can cause permanent eye injury. Symptoms include stinging, tearing, redness, and swelling of eyes. Can injure the cornea and cause blindness. |
| Handling and Storage | Back to Contents | 【Storage】
Keep away from heat, sparks, and flame. Store in a cool, dry place. Keep from contact with oxidizing materials. Do not store in metal containers. Keep containers tightly closed. | 【Storage】
Keep tightly closed in a cool place in a tightly closed container. | 【Handling】
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Do not reuse this container. | 【Handling】
Containers of this material may be hazardous when emptied. Since emptied containers retain product residues (vapor, liquid, and/or solid), all hazard precautions given in the data sheet must be observed. |
| Hazards Identification | Back to Contents | 【Ingestion】
Nausea, vomiting, and diarrhea are common. Oral, pharyngeal and esophageal burns may occur following ingestion of low phosphate detergents which are generally more alkaline. Colitis, esophageal stricture, and irritation of mucous membranes have also been reported. | 【Inhalation】
Inhalation of high concentrations may cause central nervous system effects characterized by nausea, headache, dizziness, unconsciousness and coma. Causes respiratory tract irritation. Long-term vapor exposure to 1,1,2-trichloroethane causes chronic gastric symptoms, fat deposition in the kidneys, and damage to the lungs. | 【Skin】
May be absorbed through the skin in harmful amounts. Exposure may cause irritation characterized by redness, dryness, and inflammation. | 【Eyes】
May cause eye irritation. May cause eye injury. | 【Ingestion】
May cause gastrointestinal irritation with nausea, vomiting and diarrhea. May cause central nervous system depression, characterized by excitement, followed by headache, dizziness, drowsiness, and nausea. Advanced stages may cause collapse, unconsciousness, coma and possible death due to respiratory failure. May be harmful if swallowed. | 【Hazards】
Air/vapor mixtures may explode when ignited. Container may explode in heat of fire. | 【UN (DOT)】
2831 |
| Exposure Controls/Personal Protection | Back to Contents | 【Personal Protection】
Eye Protection Chemical splash goggles in compliance with OSHA regulations are advised; however, OSHA regulations also permit other type safety glasses. Consult your safety representative. Wear resistant gloves such as: neoprene, To prevent repeated or prolonged skin contact, wear impervious clothing and boots. | 【Personal Protection】
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. | 【Respirators】
Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary. | 【Respirators】
Not required under normal conditions of use. | 【Exposure Effects】
May cause liver and kidney damage. | 【Exposure limit(s)】
OSHA PEL: TWA 10 ppm (45 mg/m3) skin NIOSH REL: Ca TWA 10 ppm (45 mg/m3) skin See Appendix A See Appendix C (Chloroethanes) NIOSH IDLH: Potential occupational carcinogen 100 ppm | 【Poison Class】
3 | 【Poison Class】
4 |
| Fire Fighting Measures | Back to Contents | 【Flash Point】
260 | 【Flash Point】
32 | 【Autoignition】
460 | 【Fire Fighting】
Fire Extinguishing Agents Not to Be Used: Water may be ineffective on fire.Fire Extinguishing Agents: Dry chemicals, foam, carbon dioxide | 【Fire Fighting】
Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing media: For small fires, use dry chemical, carbon dioxide, halon, or water spray. For large fires, use water spray, fog or regular foam. Cool containers with flooding quantities of water until well after fire is out. | 【Upper exp. limit】
15.5 | 【Lower exp. limit】
6 | 【Fire Potential】
No statement of flammability in national fire codes. |
| Accidental Release Measures | Back to Contents | 【Small spills/leaks】
Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Clean up spills immediately, using the appropriate protective equipment. Flush spill area with water. A vapor suppressing foam may be used to reduce vapors. | 【Small spills/leaks】
Dampen the solid spill material with water, then transfer the dampened material to a suitable container. Use absorbent paper dampened with water to pick up any remaining material. Seal your contaminated clothing and the absorbent paper in a vapor-tight plastic bag for eventual disposal. Wash all contaminated surfaces with a soap and water solution. Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned. |
| Stability and Reactivity | Back to Contents | 【Stability】
Stable under normal temperatures and pressures. | 【Stability】
Stable. | 【Incompatibilities】
Strong mineral acids, strong oxidizing agents. | 【Incompatibilities】
Strong oxidizing agents, strong bases, ammonia, Active metals (such as potassium and magnesium). | 【Decomposition】
Hydrogen chloride, phosgene, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide. | 【Decomposition】
Oxides of carbon. | 【Combustion Products】
Toxic gases including hydrogen chloride and very small amounts of phosgene and chlorine are produced. |
|
| Company Name: |
Energy Chemical |
| Tel: |
021-021-58432009 400-005-6266 |
| Fax: |
021-58436166 |
| WebSite: |
http://www.energy-chemical.com |
| Company Name: |
Adamas Reagent, Ltd. |
| Tel: |
400-6009262 16621234537 |
| Fax: |
021-64823266 |
| WebSite: |
www.tansoole.com |
| Company Name: |
BEST-REAGENT |
| Tel: |
400-1166-196 18981987031 |
| Fax: |
028-84555506 800101999 |
| WebSite: |
http://www.hx-r.com/ |
|