ChemicalBook >>1-Hexyne>>1-Hexyne(693-02-7)

1-Hexyne(693-02-7)

1-Hexyne(693-02-7)
Product IdentificationBack to Contents
【Product Name】

1-Hexyne
【Synonyms】

Butylacetylene
Hex-1-yne
n-Butylacetylene
【CAS】

693-02-7
【Formula】

C6H10
【Molecular Weight】

82.15
【EINECS】

211-736-9
【RTECS】

MQ9691000
【RTECS Class】

Other
【Beilstein/Gmelin】

4932296
【Beilstein Reference】

2-27-00-00797
【EC Class】

highly flammable
Physical and Chemical PropertiesBack to Contents
【Appearance】

Colorless liquid.
【Solubility in water】

Slightly soluble
【Melting Point】

-132
【Boiling Point】

71
【Vapor Pressure】

135 (25 C)
【Density】

0.7147 g/cm3 (20C)
【Partition Coefficient】

2.59
【Heat Of Vaporization】

22.5 kJ/mol
【Heat Of Combustion】

-3917 kJ/mol
【Vapor Density】

2.83
【Refractive Index】

1.3988 (20 C)
First Aid MeasuresBack to Contents
【Ingestion】

Never give anything by mouth to an unconscious person. Get medical aid immediately. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
【Inhalation】

Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
【Skin】

Get medical aid immediately. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Discard contaminated clothing in a manner which limits further exposure.
【Eyes】

Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Handling and StorageBack to Contents
【Storage】

Keep away from heat, sparks, and flame. Keep away from sources of ignition. Refrigerator/flammables.
【Handling】

Wash thoroughly after handling. Ground and bond containers when transferring material. Use spark-proof tools and explosion proof equipment. Do not get in eyes, on skin, or on clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Avoid contact with heat, sparks and flame. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames. Do not breathe vapors.
Hazards IdentificationBack to Contents
【Inhalation】

Aspiration may lead to pulmonary edema. Vapors may cause dizziness or suffocation. Causes irritation of the mucous membrane and upper respiratory tract. May cause burning sensation in the chest.
【Skin】

May cause irritation and dermatitis. May cause cyanosis of the extremities.
【Eyes】

Causes eye irritation. May cause conjunctivitis and corneal inflammation.
【Ingestion】

May cause gastrointestinal irritation with nausea, vomiting and diarrhea. Ingestion of large amounts may cause CNS depression.
【Hazards】

Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers.
【EC Risk Phrase】

R 11 36/37/38 65
【EC Safety Phrase】

S 16 26 33 62
【UN (DOT)】

1993
Exposure Controls/Personal ProtectionBack to Contents
【Personal Protection】

Eyes: Wear safety glasses and chemical goggles if splashing is possible. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to minimize contact with skin.
【Respirators】

A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use.
【Exposure Effects】

The toxological properties of this substance have not been fully investigated.
【Poison Class】

3
Fire Fighting MeasuresBack to Contents
【Flash Point】

-21
【Autoignition】

263
【Fire Fighting】

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Will burn if involved in a fire. Use water spray to keep fire-exposed containers cool. Containers may explode in the heat of a fire. Extinguishing media: Use water spray to cool fire-exposed containers. Water may be ineffective. In case of fire, use carbon dioxide, dry chemical powder or appropriate foam.
【Upper exp. limit】

16.6
【Lower exp. limit】

1.3
【Fire Potential】

Flammable Liquid.
Accidental Release MeasuresBack to Contents
【Small spills/leaks】

Cover with an activated carbon adsorbent and place into a closed container for disposal. Remove all sources of ignition. Use a spark-proof tool. A vapor suppressing foam may be used to reduce vapors.
Stability and ReactivityBack to Contents
【Disposal Code】

1
【Incompatibilities】

Oxidizing agents.
【Stability】

Stable under normal temperatures and pressures.
【Decomposition】

Carbon monoxide, carbon dioxide.
【Combustion Products】

Fire may produce irritating, corrosive and/or toxic gases.
Transport InformationBack to Contents
【UN Number】

1993
【Hazard Class】

3
【Packing Group】

I; II; III
【HS Code】

2901 29 80
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