| Product Identification | Back to Contents | 【Product Name】
Bromoacetic acid ethyl ester | 【Synonyms】
(Ethoxycarbonyl)methyl bromide
3-Methylbenzenesulfonic acid
Acetic acid, bromo-, ethyl ester
Antol
Ethyl 2-bromoethanoate
Ethyl bromoethanoate
m-Methylbenzenesulfonic acid
thyl monobromoacetate | 【CAS】
105-36-2 | 【CAS】
617-97-0 | 【Formula】
C4H7BrO2 | 【Formula】
C7H8O3S | 【Molecular Weight】
167.01 | 【Molecular Weight】
172.2 | 【EINECS】
203-290-9 | 【RTECS】
AF6000000 | 【RTECS Class】
Tumorigen | 【Beilstein/Gmelin】
506456 | 【Beilstein/Gmelin】
2208421 | 【Beilstein Reference】
4-02-00-00527 | 【Beilstein Reference】
4-11-00-00237 | 【EC Index Number】
607-069-00-1 | 【EC Class】
Very toxic |
| Physical and Chemical Properties | Back to Contents | 【Appearance】
Clear, colorless liquid, pungent, irritating odor, lachrymator. | 【Solubility in water】
Insoluble | 【Solubility in water】
Very soluble | 【Melting Point】
-38 | 【Boiling Point】
159 | 【Boiling Point】
160 - 170 (0.1 torr) | 【Vapor Pressure】
2.6 | 【Density】
1.5282 g/cm3 (4 C) | 【Partition Coefficient】
.93 | 【Partition Coefficient】
1.12 | 【Heat Of Vaporization】
| 【Usage】
Has been employed as tear gas. | 【Vapor Density】
5.8 | 【Saturation Concentration】
3422 ppm (0.34%) at 25 C (calculated) | 【Refractive Index】
1.4516 (13 C) | 【Refractive Index】
1.53 (20 C) |
| First Aid Measures | Back to Contents | 【Ingestion】
If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately. | 【Ingestion】
Seek medical assistance. | 【Inhalation】
TOXIC; inhalation, ingestion, or skin contact with material may cause severe injury or death. Effects of contact or inhalation may be delayed. | 【Inhalation】
Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. | 【Inhalation】
Move victim to fresh air. Apply artificial respiration if victim is not breathing. Do not use mouth-to-mouth method if victim ingested or inhaled the substance; induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Administer oxygen if breathing is difficult. | 【Skin】
Get medical aid immediately. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. | 【Skin】
Remove and isolate contaminated clothing and shoes. Immediately flush with running water for at least 20 minutes. For minor skin contact, avoid spreading material on unaffected skin. | 【Skin】
Contact with molten substance may cause severe burns to skin and eyes. See Inhalation. | 【Eyes】
Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. | 【Eyes】
See Inhalation. | 【Eyes】
Immediately flush with running water for at least 20 minutes. |
| Handling and Storage | Back to Contents | 【Storage】
Keep away from heat, sparks, and flame. Keep away from sources of ignition. Keep container closed when not in use. Store in a cool, dry, well-ventilated area away from incompatible substances. Flammables-area. | 【Handling】
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use only in a well ventilated area. Ground and bond containers when transferring material. Use spark-proof tools and explosion proof equipment. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Avoid ingestion and inhalation. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames. |
| Hazards Identification | Back to Contents | 【Ingestion】
See Inhalation. | 【Inhalation】
May cause respiratory tract irritation. Vapors may cause dizziness or suffocation. | 【Skin】
Causes severe skin irritation. May be absorbed through the skin. | 【Eyes】
Causes severe eye irritation. May cause opacity and scarring. Lachrymator. | 【Ingestion】
Causes gastrointestinal irritation with nausea, vomiting and diarrhea. | 【Hazards】
Vapors form explosive mixtures with air: indoors, outdoors, and sewers explosion hazards. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapors may travel to source of ignition and flash back. Substance will react with water (some violently) releasing flammable, toxic or corrosive gases and runoff. Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated or if contaminated with water. | 【Hazards】
When heated, vapors may form explosive mixtures with air: indoors, outdoors, and sewers explosion hazards. | 【EC Risk Phrase】
R 26/27/28 | 【EC Risk Phrase】
R 34 | 【EC Safety Phrase】
S 26 36/37/39 45 | 【EC Safety Phrase】
S 7/9 26 45 | 【UN (DOT)】
1603 | 【UN (DOT)】
2586 |
| Exposure Controls/Personal Protection | Back to Contents | 【Personal Protection】
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. | 【Personal Protection】
Wear appropriate protective gloves, clothing and goggles. | 【Respirators】
Wear positive pressure self-contained breathing apparatus (SCBA). | 【Respirators】
Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary. | 【Exposure Effects】
Agitation and syncope, both attributed to panic, have been reported. | 【Poison Class】
1 |
| Fire Fighting Measures | Back to Contents | 【Flash Point】
50 | 【Fire Fighting】
Small Fires: Dry chemical, carbon dioxide or water spray. Large Fires: Dry chemical, carbon dioxide, alcohol-resistant foam or water spray. | 【Fire Fighting】
Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. To extinguish fire use water fog, dry chemical, carbon dioxide or alcohol type foam. | 【Fire Potential】
Combustible material: may burn but does not ignite readily. | 【Fire Potential】
HIGHLY FLAMMABLE. |
| Accidental Release Measures | Back to Contents | 【Small spills/leaks】
Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Remove all sources of ignition. Use a spark-proof tool. Provide ventilation. | 【Small spills/leaks】
ELIMINATE all ignition sources. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Stop leak if you can do it without risk. Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers. DO NOT GET WATER INSIDE CONTAINERS. |
| Stability and Reactivity | Back to Contents | 【Disposal Code】
9 | 【Incompatibilities】
Oxidizing agents, reducing agents, acids, bases. | 【Stability】
Stable under normal temperatures and pressures. | 【Decomposition】
Carbon monoxide, carbon dioxide, hydrogen bromide. | 【Combustion Products】
Fire may produce irritating, corrosive and/or toxic gases. | 【Combustion Products】
Fire will produce irritating, corrosive and/or toxic gases. |
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