ChemicalBook >>Rhodanine>>2-Thio-2,4-thiazolidinedione(141-84-4)

2-Thio-2,4-thiazolidinedione(141-84-4)

2-Thio-2,4-thiazolidinedione(141-84-4)
Product IdentificationBack to Contents
【Product Name】

2-Thio-2,4-thiazolidinedione
【Synonyms】

2-Sulfanylidene-1,3-thiazolidin-4-one
Rhodanic acid
Rhodanine
Rhodaninic acid
Uranium triiodide
【CAS】

13775-18-3
【CAS】

141-84-4
【Formula】

C3H3NOS2
【Formula】

I3U
【Molecular Weight】

618.74
【Molecular Weight】

133.19
【EINECS】

205-505-1
【EINECS】

237-406-4
【RTECS】

VI7700000
【RTECS Class】

Agricultural Chemical and Pesticide; Drug; Primary Irritant
【Merck】

12,8351
【Beilstein/Gmelin】

110701
【Beilstein/Gmelin】

141844 (G)
【Beilstein Reference】

4-27-00-03188
【EC Class】

harmful
Physical and Chemical PropertiesBack to Contents
【Appearance】

black hygroscopic crystals
【Appearance】

Light yellow crystals.
【Solubility in water】

Slightly soluble
【Melting Point】

766
【Melting Point】

166 - 168
【Boiling Point】

344
【Density】

1.549 g/cm3
【pKa/pKb】

pK (25°) 5.52 (pKa)
【Partition Coefficient】

.26
【Usage】

Fungicide.
First Aid MeasuresBack to Contents
【Ingestion】

Medical problems take priority over radiological concerns. Use first aid treatment according to the nature of the injury. Do not delay care and transport of a seriously injured person.
【Ingestion】

Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
【Inhalation】

Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
【Inhalation】

Minimal risk if packaging remains intact. Package damage can result in a measurable release of radiation but the risk is still low.
【Inhalation】

Apply artificial respiration if victim is not breathing. Administer oxygen if breathing is difficult. See Ingestion.
【Skin】

Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
【Skin】

Immediately flush with running water for at least 20 minutes. See Ingestion.
【Skin】

See Inhalation.
【Eyes】

See Inhalation.
【Eyes】

Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
【Eyes】

Immediately flush with running water for at least 20 minutes. See Ingestion.
Handling and StorageBack to Contents
【Storage】

Keep container closed when not in use. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
【Storage】

Keep in a cool, dry, dark location in a tightly sealed container or cylinder. Keep away from incompatible materials, ignition sources and untrained individuals. Secure and label area. Protect containers/cylinders from physical damage.
【Handling】

Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.
【Handling】

All chemicals should be considered hazardous. Avoid direct physical contact. Use appropriate, approved safety equipment. Untrained individuals should not handle this chemical or its container. Handling should occur in a chemical fume hood.
Hazards IdentificationBack to Contents
【Ingestion】

See Inhalation.
【Inhalation】

May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
【Skin】

May cause skin irritation.
【Eyes】

Causes eye irritation.
【Ingestion】

Harmful if swallowed. May cause irritation of the digestive tract.
【EC Risk Phrase】

R 22 36
【EC Safety Phrase】

S 22 26 36/37/39
【UN (DOT)】

2909
Exposure Controls/Personal ProtectionBack to Contents
【Personal Protection】

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
【Personal Protection】

Wear appropriate protective gloves, clothing and goggles.
【Respirators】

Wear positive pressure self-contained breathing apparatus (SCBA).
【Respirators】

Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
【Exposure Effects】

The toxicological properties of this material have not been investigated.
Fire Fighting MeasuresBack to Contents
【Fire Fighting】

Presence of radioactive material will not influence the fire control processes and should not influence selection of techniques. Small Fires: Dry chemical, carbon dioxide, water spray or regular foam. Large Fires: Water spray, fog (flooding amounts).
【Fire Fighting】

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water spray to keep fire-exposed containers cool. May explode from heat or contamination. Containers may explode when heated. Extinguishing media: Use agent most appropriate to extinguish fire. Cool containers with flooding quantities of water until well after fire is out. In case of fire use water spray, dry chemical, carbon dioxide, or appropriate foam.
【Fire Potential】

May burn but does not ignite readily.
Accidental Release MeasuresBack to Contents
【Small spills/leaks】

Clean up spills immediately, using the appropriate protective equipment. Sweep up, then place into a suitable container for disposal. Avoid generating dusty conditions. Remove all sources of ignition. Provide ventilation.
【Small spills/leaks】

Do not touch damaged packages or spilled material. Cover liquid spill with sand, earth or other noncombustible absorbent material. Cover powder spill with plastic sheet or tarp to minimize spreading. Contact radiation safety officer.
Stability and ReactivityBack to Contents
【Disposal Code】

3
【Stability】

No data.
【Incompatibilities】

Oxidizing agents.
【Stability】

Stable under normal temperatures and pressures.
【Decomposition】

Nitrogen oxides, carbon monoxide, oxides of sulfur, irritating and toxic fumes and gases, carbon dioxide, nitrogen.
Transport InformationBack to Contents
【UN Number】

2909
【Hazard Class】

7
【HS Code】

2934 10 00
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