ChemicalBook >>N-Methylhomopiperazine>>Hexahydro-1-methyl-1H-1,4-diazepine(4318-37-0)

Hexahydro-1-methyl-1H-1,4-diazepine(4318-37-0)

Hexahydro-1-methyl-1H-1,4-diazepine(4318-37-0)
Product IdentificationBack to Contents
【Product Name】

Hexahydro-1-methyl-1H-1,4-diazepine
【Synonyms】

1-Methyl-[1,4]diazepan
1-Methyl-2,3,4,5,6,7-hexahydro-1H-1,4-diazepine
1-Methylperhydro-1,4-diazepine
Hexahydro-1-methyl-1,4-diazepine
N-Methyl-1,4-diazacycloheptane
N-Methylhomopiperazine
【CAS】

4318-37-0
【Formula】

C6H14N2
【Molecular Weight】

114.19
【Beilstein Reference】

5-23-03-00241
Physical and Chemical PropertiesBack to Contents
【Appearance】

Clear, colorless liquid.
【Solubility in water】

77 g/L (25 C)
【Melting Point】

33
【Boiling Point】

164
【Vapor Pressure】

2.8 (25 C)
【Density】

0.918 g/cm3 (25 C)
【pKa/pKb】

3.17 (pKb)
【Partition Coefficient】

.21
【Heat Of Vaporization】

39.41 kJ/mol
【Refractive Index】

1.477 (20 C)
First Aid MeasuresBack to Contents
【Ingestion】

If swallowed, wash out mouth with water provided person is conscious. Call a physician.
【Inhalation】

If inhaled, remove to fresh air. If not breathing give artificial respiration. If breathing is difficult, give oxygen.
【Skin】

In case of contact, immediately wash skin with soap and copious amounts of water. Remove contaminated clothing and shoes. Call a physician.
【Eyes】

In case of contact with eyes, flush with copious amounts of water for at least 15 minutes. Assure adequate flushing by separating the eyelids with fingers. Call a physician.
Handling and StorageBack to Contents
【Storage】

Keep container tightly closed.
Hazards IdentificationBack to Contents
【Inhalation】

Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. May be harmful if inhaled.
【Skin】

Causes burns. May be harmful if absorbed through the skin.
【Eyes】

Causes burns.
【Ingestion】

Harmful if swallowed.
【Hazards】

Emits toxic fumes under fire conditions.
【EC Risk Phrase】

10 22 34
【EC Safety Phrase】

16 26 27 36/37/39 45
【UN (DOT)】

2920
Exposure Controls/Personal ProtectionBack to Contents
【Personal Protection】

Compatible chemical-resistant gloves. Chemical safety goggles. Protective clothing. Faceshield (8 inch minimum).
【Respirators】

Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator.
【Exposure Effects】

Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Inhalation may result in spasm, inflammation and edema of the larynx and bronchi, chemical pneumonitis, and pulmonary edema. Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin.
Fire Fighting MeasuresBack to Contents
【Flash Point】

45
【Fire Fighting】

Extinguish with water spray, carbon dioxide, dry chemical powder or appropriate foam. Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes.
【Fire Potential】

Combustible liquid.
Accidental Release MeasuresBack to Contents
【Small spills/leaks】

Cover with dry lime or soda ash, pick up, keep in a closed container, and hold for waste disposal. Ventilate area and wash spill site after material pickup is complete.
Stability and ReactivityBack to Contents
【Stability】

Stable at normal temperatures and pressures.
【Incompatibilities】

Strong oxidizing agents.
【Decomposition】

Oxides of carbon, oxides of nitrogen.
Transport InformationBack to Contents
【UN Number】

2920
【Hazard Class】

8
【Packing Group】

II
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