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Silver(II) oxide(1301-96-8)

Silver(II) oxide(1301-96-8)
Product IdentificationBack to Contents
【Product Name】

Silver(II) oxide
【Synonyms】

Divasil
Silver monoxide
【CAS】

1301-96-8
【Formula】

AgO
【Molecular Weight】

123.86
【EINECS】

215-098-2
【Merck】

12,8666
【Beilstein/Gmelin】

13605 (G)
Physical and Chemical PropertiesBack to Contents
【Appearance】

gray powder, monoclinic or cubic
【Melting Point】

100
【Density】

7.44 g/cm3
【Usage】

Substance is used in the production of silver oxide-zinc alkali batteries.
First Aid MeasuresBack to Contents
【Ingestion】

If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
【Inhalation】

Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
【Skin】

Get medical aid immediately. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Discard contaminated clothing in a manner which limits further exposure.
【Eyes】

Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. Do NOT allow victim to rub or keep eyes closed.
Handling and StorageBack to Contents
【Storage】

Do not store near combustible materials. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
【Handling】

Wash thoroughly after handling. Use with adequate ventilation. Minimize dust generation and accumulation. Do not get in eyes, on skin, or on clothing. Keep container tightly closed. Avoid contact with clothing and other combustible materials. Do not ingest or inhale. Store protected from light. Do not store near combustible materials.
Hazards IdentificationBack to Contents
【Inhalation】

Causes respiratory tract irritation.
【Skin】

Causes skin burns.
【Eyes】

Causes eye burns. Contact with eyes may cause severe irritation, and possible eye burns.
【Ingestion】

May cause severe gastrointestinal tract irritation with nausea, vomiting and possible burns. Ingestion of soluble silver salts may cause argyria characterized by permanent blue-gray pigmentation of the skin, mucous membranes, and eyes.
【Hazards】

May explode from heat or contamination. May react explosively with hydrocarbons (fuels). May ignite combustibles.
【UN (DOT)】

1479
Exposure Controls/Personal ProtectionBack to Contents
【Personal Protection】

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
【Respirators】

Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
【Exposure Effects】

Chronic inhalation or ingestion may cause argyria characterized by blue-gray discoloration of the eyes, skin and mucous membrances. Chronic skin contact may cause permanent discoloration of the skin.
Fire Fighting MeasuresBack to Contents
【Fire Fighting】

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Strong oxidizer. Contact with combustible materials may cause a fire. Extinguishing media: Use water only! DO NOT use dry chemicals, carbon dioxide, Halon or foams.
【Fire Potential】

These substances will accelerate burning when involved in a fire.
Accidental Release MeasuresBack to Contents
【Small spills/leaks】

Vacuum or sweep up material and place into a suitable disposal container. Avoid generating dusty conditions. Provide ventilation.
Stability and ReactivityBack to Contents
【Incompatibilities】

Reacts dangerously with ammonia. Grinding silver oxide with metal sulfides, selenium, sulfur, or phosphorus can cause ignition. Hydrogen sulfide may ignite when in contact with silver oxide. Incompatible with hydrazines, amines, sulfur, metal sulfides, and carbon monoxide.
【Stability】

Stable under normal shipping and handling conditions. Absorbs carbon dioxide from the air.
【Decomposition】

Oxygen, silver fumes.
【Combustion Products】

Fire may produce irritating, corrosive and/or toxic gases.
Transport InformationBack to Contents
【UN Number】

1479
【Hazard Class】

5.1
【Packing Group】

I; II; III
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