ChemicalBook >>4-Nitrobiphenyl>>1-Nitro-4-phenylbenzene(92-93-3)

1-Nitro-4-phenylbenzene(92-93-3)

1-Nitro-4-phenylbenzene(92-93-3)
Product IdentificationBack to Contents
【Product Name】

1-Nitro-4-phenylbenzene
【Synonyms】

1-Nitro-4-phenylbenzene
4-Nitrodiphenyl
4-Phenyl-nitrobenzene
p-Nitrobiphenyl
p-Nitrodiphenyl
【CAS】

92-93-3
【Formula】

C12H9NO2
【Molecular Weight】

199.21
【EINECS】

202-204-7
【RTECS】

DV5600000
【RTECS Class】

Tumorigen; Mutagen
【Merck】

12,6690
【Beilstein/Gmelin】

1910956
【Beilstein Reference】

4-05-00-01823
【EC Index Number】

609-039-00-3
【EC Class】

Carcinogenic Category 2; Dangerous for the Environment
Physical and Chemical PropertiesBack to Contents
【Appearance】

White to yellow needle-like crystalline solid with a sweetish odor.
【Solubility in water】

Insoluble
【Melting Point】

114
【Boiling Point】

340
【Vapor Pressure】

0.0002 (25 C)
【Partition Coefficient】

3.77
【Heat Of Vaporization】

56.0 kJ/mol
【Heat Of Combustion】

-6064 kJ/mol
【Usage】

Formerly in prepn of p-biphenylamine.
First Aid MeasuresBack to Contents
【Ingestion】

If victim is conscious and alert, give 2-4 cupfuls of milk or water. Get medical aid immediately.
【Inhalation】

Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
【Skin】

Get medical aid. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.
【Eyes】

Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Handling and StorageBack to Contents
【Storage】

Store in a cool, dry place. Store in a tightly closed container.
【Handling】

Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use only in a well ventilated area. Avoid contact with skin and eyes. Do not ingest or inhale. Use only in a chemical fume hood.
Hazards IdentificationBack to Contents
【Inhalation】

Inhalation of high concentrations may cause central nervous system effects characterized by headache, dizziness, unconsciousness and coma. Causes respiratory tract irritation. May cause pulmonary edema and severe respiratory disturbances.
【Skin】

May cause skin irritation. May be absorbed through the skin in harmful amounts.
【Eyes】

May cause eye irritation.
【Ingestion】

May cause central nervous system depression, kidney damage, and liver damage. Symptoms may include: headache, excitement, fatigue, nausea, vomiting, stupor, and coma. May cause gastrointestinal irritation with nausea, vomiting and diarrhea.
【Hazards】

Contact with metals may evolve flammable hydrogen gas.
【UN (DOT)】

2811
Exposure Controls/Personal ProtectionBack to Contents
【Personal Protection】

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
【Respirators】

Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
【Exposure Effects】

May cause cancer according to animal studies.
【Exposure limit(s)】

NIOSH: Potential Occupational Carcinogen.
【Poison Class】

1*
Fire Fighting MeasuresBack to Contents
【Flash Point】

143
【Fire Fighting】

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. To extinguish fire use water spray, dry chemical, carbon dioxide, or chemical foam.
【Fire Potential】

Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes.
Accidental Release MeasuresBack to Contents
【Small spills/leaks】

Vacuum or sweep up material and place into a suitable disposal container.
Stability and ReactivityBack to Contents
【Stability】

Stable under normal shipping and handling conditions.
【Incompatibilities】

Strong bases - strong oxidizing agents.
【Decomposition】

Nitrogen oxides, carbon monoxide, carbon dioxide.
【Combustion Products】

Fire may produce irritating, corrosive and/or toxic gases.
Transport InformationBack to Contents
【UN Number】

2811
【Hazard Class】

6.1
【Packing Group】

I; II; III
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