ChemicalBook >>4,4'-Methylenedianiline>>4,4'-Methylenebisbenzeneamine(101-77-9)

4,4'-Methylenebisbenzeneamine(101-77-9)

4,4'-Methylenebisbenzeneamine(101-77-9)
Product IdentificationBack to Contents
【Product Name】

4,4'-Methylenebisbenzeneamine
【Synonyms】

4,4'-Methylenebisbenzeneamine
4,4'-Methylenedianiline
4-[(4-Aminophenyl)methyl]aniline
Methylenebis(aniline)
【CAS】

101-77-9
【Formula】

C13H14N2
【Molecular Weight】

198.27
【EINECS】

202-974-4
【RTECS】

BY5425000
【RTECS Class】

Tumorigen; Mutagen; Human Data; Primary Irritant
【Merck】

13,3000
【Beilstein/Gmelin】

474706
【Beilstein Reference】

4-13-00-00390
【EC Index Number】

612-051-00-1
【EC Class】

Carcinogenic Category 2; Mutagenic Category 3; Toxic; Harmful; Sensitising; Dangerous for the Environment
Physical and Chemical PropertiesBack to Contents
【Appearance】

A tan flake or lump solid with a faint fishlike odor.
【Solubility in water】

Insoluble
【Melting Point】

91 - 92
【Boiling Point】

398
【Vapor Pressure】

1.5E-6 (25 C)
【Density】

1.15 g/cm3 (20 C)
【pKa/pKb】

8.68 kJ/mol
【Partition Coefficient】

1.59
【Heat Of Vaporization】

64.9 kJ/mol
【Usage】

Determination of tungsten & sulfates, as corrosion inhibitor, prepn of azo dyes.
【Vapor Density】

6.8
First Aid MeasuresBack to Contents
【Ingestion】

Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
【Inhalation】

Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. DO NOT use mouth-to-mouth respiration.
【Skin】

Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
【Eyes】

Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Handling and StorageBack to Contents
【Storage】

Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
【Handling】

Wash thoroughly after handling. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.
Hazards IdentificationBack to Contents
【Inhalation】

May cause respiratory tract irritation. Methemoglobinemia is characterized by dizziness, drowsiness, headache, breath shortness, cyanosis with bluish skin, rapid heart rate and chocolate-brown blood. Inhalation of aniline causes anoxia due to the formation of methemoglobinemia.
【Skin】

May cause skin irritation. May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material.
【Eyes】

May cause eye irritation.
【Ingestion】

May cause irritation of the digestive tract. May cause methemoglobinemia, cyanosis, convulsions, and death. Methemoglobinemia is characterized by dizziness, drowsiness, headache, breath shortness, cyanosis with bluish skin, rapid heart rate and chocolate-brown colored blood. May be harmful if swallowed.
【Hazards】

When heated, vapors may form explosive mixtures with air: indoors, outdoors, and sewers explosion hazards. May polymerize explosively when heated or involved in a fire. Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated. Runoff may pollute waterways. Substance may be transported in a molten form.
【EC Risk Phrase】

R 45 39/23/24/25 43 48/20/21 51/53 68
【EC Safety Phrase】

S 53 45 61
【UN (DOT)】

2651
Exposure Controls/Personal ProtectionBack to Contents
【Personal Protection】

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
【Respirators】

A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use.
【Exposure Effects】

Prolonged exposure may cause anemia and methemoglobinemia, characterized by dizziness, drowsiness, headache, breath shortness, cyanosis, rapid heart rate and chocolate-brown colored blood. Repeated exposure may cause sensitization dermatitis. Effects may be delayed. Potential cancer hazard.
【Exposure limit(s)】

TLV: 0.1 ppm; 0.81 mg/m3 (A2) (skin) (ACGIH 1990-1991). OSHA PEL: 1910.1050 TWA 0.010 ppm ST 0.100 ppm NIOSH REL: Ca See Appendix A NIOSH IDLH: Potential occupational carcinogen
【Poison Class】

1*
Fire Fighting MeasuresBack to Contents
【Flash Point】

221
【Fire Fighting】

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water spray to keep fire-exposed containers cool. May polymerize explosively when involved in a fire. Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated. Combustible material; may burn but does not ignite readily. Extinguishing media: Do NOT get water inside containers. For small fires, use dry chemical, carbon dioxide, or water spray. For large fires, use dry chemical, carbon dioxide, alcohol-resistant foam, or water spray. Cool containers with flooding quantities of water until well after fire is out.
【Fire Potential】

May burn but does not ignite readily.
Accidental Release MeasuresBack to Contents
【Small spills/leaks】

Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, using the appropriate protective equipment. Sweep up, then place into a suitable container for disposal. Avoid generating dusty conditions. Provide ventilation.
Stability and ReactivityBack to Contents
【Incompatibilities】

Oxidizing agents.
【Stability】

Stable under normal temperatures and pressures.
【Decomposition】

Nitrogen oxides, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, nitrogen.
【Combustion Products】

Fire may produce irritating, corrosive and/or toxic gases.
Transport InformationBack to Contents
【UN Number】

2651
【Hazard Class】

6.1
【Packing Group】

III
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