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p-Toluic acid(99-94-5)

p-Toluic acid(99-94-5)
Product IdentificationBack to Contents
【Product Name】

p-Toluic acid
【Synonyms】

4-Methylbenzoic acid
Crithminic acid
p-Carboxytoluene
p-Methylbenzoic acid
p-Toluylic acid
p-Tolylcarboxylic acid
【CAS】

99-94-5
【Formula】

C8H8O2
【Molecular Weight】

136.15
【EINECS】

202-803-3
【RTECS】

XU1575000
【RTECS Class】

Other
【Merck】

12,9673
【Beilstein/Gmelin】

507600
【Beilstein Reference】

4-09-00-01724
【EC Class】

harmful, irritant
Physical and Chemical PropertiesBack to Contents
【Appearance】

White powder. Sublimes.
【Solubility in water】

11.6 g/L
【Melting Point】

179 - 180
【Boiling Point】

275
【Vapor Pressure】

0.0025 (25 C)
【Density】

1.06 g/cm3 (20 C)
【pKa/pKb】

4.37 (pKa)
【Partition Coefficient】

2.36
【Heat Of Vaporization】

54.3 kJ/mol
【Usage】

Used in the manufacture of pet.
【Refractive Index】

1.5086 (20 C)
First Aid MeasuresBack to Contents
【Ingestion】

If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
【Inhalation】

Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
【Skin】

Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
【Eyes】

Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Handling and StorageBack to Contents
【Storage】

Store in a cool, dry place. Keep container closed when not in use. Store in a cool, dry, well-ventilated area away from incompatible substances.
【Handling】

Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Do not ingest or inhale.
Hazards IdentificationBack to Contents
【Inhalation】

May cause respiratory tract irritation.
【Skin】

May cause skin irritation.
【Eyes】

May cause eye irritation.
【Ingestion】

May cause irritation of the digestive tract.
【EC Risk Phrase】

R 22 36/37/38
【EC Safety Phrase】

S 26 36/37/39
Exposure Controls/Personal ProtectionBack to Contents
【Personal Protection】

Eyes: Wear safety glasses and chemical goggles if splashing is possible. Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves and clothing to prevent skin exposure. Clothing: Wear appropriate protective clothing to minimize contact with skin.
【Respirators】

Wear a NIOSH/MSHA or European Standard EN 149 approved full-facepiece airline respirator in the positive pressure mode with emergency escape provisions. Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
【Exposure Effects】

Prolonged or repeated skin contact may cause dermatitis.
【Poison Class】

3
Fire Fighting MeasuresBack to Contents
【Autoignition】

570
【Fire Fighting】

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. To extinguish fire, use water, dry chemical, chemical foam, or alcohol-resistant foam.
【Upper exp. limit】

6.8
【Lower exp. limit】

1.2
【Fire Potential】

This material is probably combustible.
Accidental Release MeasuresBack to Contents
【Small spills/leaks】

Clean up spills immediately, using the appropriate protective equipment. Sweep up or absorb material, then place into a suitable clean, dry, closed container for disposal. Avoid generating dusty conditions. Provide ventilation.
Stability and ReactivityBack to Contents
【Disposal Code】

4
【Stability】

Stable under normal temperatures and pressures.
【Incompatibilities】

Strong oxidizing agents, strong bases.
【Decomposition】

Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
Transport InformationBack to Contents
【HS Code】

2916 39 00
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