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N-(2-Naphthyl)aniline(135-88-6)

N-(2-Naphthyl)aniline(135-88-6)
Product IdentificationBack to Contents
【Product Name】

N-(2-Naphthyl)aniline
【Synonyms】

2-Anilinonaphthalene
2-Phenylaminonaphthalene
beta-Naphthylphenylamine
N-2-Naphthylaniline
Neozone
Phenyl-beta-Naphthylamine
【CAS】

135-88-6
【Formula】

C16H13N
【Molecular Weight】

219.3
【EINECS】

205-223-9
【RTECS】

QM4550000
【RTECS Class】

Tumorigen; Mutagen
【Beilstein/Gmelin】

2211188
【Beilstein Reference】

4-12-00-03128
【EC Index Number】

612-135-00-8
【EC Class】

Carcinogenic Category 3; Irritant; Sensitising; Dangerous for the Environment
Physical and Chemical PropertiesBack to Contents
【Appearance】

Light gray to gray powder. Solutions show blue fluorescence.
【Solubility in water】

Insoluble
【Melting Point】

105 - 106
【Boiling Point】

395
【Vapor Pressure】

2E-6 (26 C)
【Density】

1.161 g/cm3
【pKa/pKb】

12.17 (pKb)
【Partition Coefficient】

4.38
【Heat Of Vaporization】

64.6 kJ/mol
【Heat Of Combustion】

-8405 kJ/mol
【Usage】

Rubber antioxidant, lubricant, inhibitor (butadiene).
First Aid MeasuresBack to Contents
【Ingestion】

DO NOT INDUCE VOMITING. If the victim is conscious and not convulsing, give 1 or 2 glasses of water to dilute the chemical and IMMEDIATELY call a hospital or poison control center. Be prepared to transport the victim to a hospital if advised by a physician.
【Inhalation】

IMMEDIATELY leave the contaminated area; take deep breaths of fresh air. If symptoms (such as wheezing, coughing, shortness of breath, or burning in the mouth, throat, or chest) develop, call a physician and be prepared to transport the victim to a hospital. Provide proper respiratory protection to rescuers entering an unknown atmosphere. Whenever possible, Self-Contained Breathing Apparatus (SCBA) should be used.
【Skin】

IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing. Gently wash all affected skin areas thoroughly with soap and water. If symptoms such as redness or irritation develop, IMMEDIATELY call a physician and be prepared to transport the victim to a hospital for treatment.
【Eyes】

First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.
Handling and StorageBack to Contents
【Storage】

Materials which are toxic as stored or which.Decomp into toxic components due to contact with heat.Should be stored in cool, well-ventilated place, out of direct rays of sun, away from areas of high fire hazard, and.Periodically inspected and monitored.
【Handling】

All chemicals should be considered hazardous. Avoid direct physical contact. Use appropriate, approved safety equipment. Untrained individuals should not handle this chemical or its container. Handling should occur in a chemical fume hood.
Hazards IdentificationBack to Contents
【Inhalation】

Dyspnea and tachypnea may occur.
【Skin】

Central cyanosis unresponsive to oxygen therapy is classic.
【Eyes】

See Inhalation.
【Ingestion】

Nausea and vomiting may occur.
【Hazards】

Contact with metals may evolve flammable hydrogen gas.
【UN (DOT)】

3259
Exposure Controls/Personal ProtectionBack to Contents
【Personal Protection】

Wear appropriate protective gloves, clothing and goggles.
【Respirators】

Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode. Any supplied-air respirator that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary self-contained breathing apparatus operated in pressure-demand or other positive-pressure mode.
【Exposure Effects】

CNS effects include headache, dizziness, altered mental status, confusion (lethargy progressing coma), seizures, syncope; occur secondary to CNS hypoxia, usually with levels > 20%.
【Exposure limit(s)】

NIOSH REL: Ca* See Appendix A [*Note: Since metabolized to beta-Naphthylamine.]
【Poison Class】

3
Fire Fighting MeasuresBack to Contents
【Flash Point】

209
【Fire Fighting】

Fires involving this compound can be controlled using a dry chemical, carbon dioxide or Halon extinguisher.
【Fire Potential】

Literature sources indicate that this chemical is combustible.
Accidental Release MeasuresBack to Contents
【Small spills/leaks】

If a spill of this chemical occurs, FIRST REMOVE ALL SOURCES OF IGNITION, then you should dampen the solid spill material with acetone and transfer the dampened material to a suitable container. Use absorbent paper dampened with acetone to pick up any remaining material. Seal your contaminated clothing and the absorbent paper in a vapor-tight plastic bag for eventual disposal. Solvent wash all contaminated surfaces with acetone followed by washing with a soap and water solution. Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned.
Stability and ReactivityBack to Contents
【Incompatibilities】

May react with strong oxidizing agents Incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides.
【Stability】

Stable.
【Decomposition】

When heated to decomposition, it emits toxic fumes of nitrogen oxides.
【Combustion Products】

Fire may produce irritating, corrosive and/or toxic gases.
Transport InformationBack to Contents
【UN Number】

3259
【Hazard Class】

8
【Packing Group】

I; II; III
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